Journal of Inorganic Materials

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Phase Transition and Dielectric Properties of MgO-Al2O3-SiO2-TiO2
Glass-ceramics Adding CeO2

DONG Ji-Peng, HE Fei, LUO Lan, CHEN Wei   

  1. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
  • Received:2006-02-17 Revised:2006-03-31 Published:2007-01-20 Online:2007-01-20

Abstract: The glass-forming, the crystallization process and microwave dielectric properties of MgO-Al2O3-SiO2-TiO2 system glasses adding CeO2 were investigated by means of DTA, XRD, SEM. Results show that spontaneous
crystallization of the MgO-Al2O3-SiO2-TiO2 system glasses is obviously prevented with the increass of CeO2 content. After heat treatment (nucleation at 770℃ for 4h and cryatal growth at 1200℃ for 1.5h) the crystallized volume fraction of rutile and cordierite decrease and that of perrierite increases. The glass-ceramics obtained by crystallization of the glasses have dielectric constant of 7.5--10.5, and microwave loss less than 5.5×10-4.

Key words: glass-ceramics, microwave materials, MgO-Al2O3-SiO2-TiO2-CeO2 system glass

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