Synthesis and Characterizations of Lithium Vanadium Oxide Nanotubes

doi:10.3724/SP.J.1077.2009.00787

Abstract

Abstract: Lithium vanadium oxide nanotubes as cathode materials for rechargeable lithium batteries were prepared via a sol-gel reaction followed by hydrothermal treatment, in which V₂O₅ and LiOH·H₂O were used as raw materials and C₁₆H₃₃NH₂ as structure-directing template. Structure and morphology of the nanotubes were investigated by SEM, TEM, XRD, FT-IR and XPS.Meantime, electrochemical behavior of the materials was researched by cyclic voltammetry. The results show that the inner and the outer diameters of the obtained nanotubes are of about 30nm and 70nm with length between 1μm to 3μm, respectively. It is also confirmed by XPS that the elements of the products are made up of various chemical states. The electrochemical performance indicates that the obtained nanotubes as cathode materials for rechargeable lithium batteries have good lithium-ion insertion/deinsertion reversibility.

Key words: lithium vanadium oxide, nanotubes, hydrothermal synthesis, cathode material

CLC Number:

O611

CUI Chao-Jun,WU Guang-Ming,ZHANG Ming-Xia,SUN Juan-Ping,YANG Hui-Yu,SHEN Jun. Synthesis and Characterizations of Lithium Vanadium Oxide Nanotubes[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2009.00787.

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