Synthesis and Photocatalytic Activity of Vanadium Doped Titania Hollow Microspheres

doi:10.3724/SP.J.1077.2009.00671

Abstract

Abstract:

Vanadium doped titania hollow microspheres were successfully prepared using polystyrene latex particles as template and using organmetallic Ti (Ⅳ) as precursor. The resulting samples were characterized by FT-IR,SEM,TEM, XRD and UV-Vis DRS. The results show that the morphology of titania hollow microspheres do not exhibit remarkable change when adding low concentration of vanadium. The wall thickness of these hollow microspheres is in the range from 20nm to 30nm. The vanadium promotes the phase transformation of TiO₂ hollow microsphere from anatase to rutile phase. With increasing concentration of vanadium, the adsorption edge of as-prepared titania hollow microspheres show stronger absorbance of light with longer wavelength. The moderately vanadium doped titania hollow microspheres（1.0%）exhibit better photocatalytic activity for the decomposition of methyl orange in aqueous solution.

Key words: titanium dioxide, vanadium doped, hollow microsphere, photocatalytic activity

CLC Number:

O612

JIA Jin-Yi,LIU Jing-Bing,ZHANG Wen-Xiong,CHANG Lin,JING Qi. Synthesis and Photocatalytic Activity of Vanadium Doped Titania Hollow Microspheres[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2009.00671.

References

［1］Byrne J A, Eggins B R, Brown M. Appl. Catal. B:Environment, 1998, 17（1/2）：25-36.
［2］Carp O, Huisman C L, Reller A. Prog. Solid State Chem., 2004, 32（1/2）：33-177.
［3］Hoffmann M R, Martin S T, Choi W, et al. Chem.Rev., 1995, 95（1）：69-96.
［4］Linsebigler A L, Lu G, Yates J T. Chem.Rev., 1995, 95（3）：735-758.
［5］Asahi R, Morikawa T, Ohwaki T, et al. Science, 2001, 293（23）：269-271.
［6］Fotou P G.Chem. Eng. Comm., 1996, 133（15）：251-259.
［7］刘守新, 孙承林. 东北林业大学学报, 2003, 31（1）：53-56.
［8］林志东, 刘黎明, 郭云. 材料导报, 2003, 11（1）：64-67.
［9］KamatpV. Mater. Sci., 1987, 22（12）： 4307-4312.
［10］Arslan I. Wat. Res., 1993, 27（12）：1743-1748.
［11］Dvoranová D, Brezová V, Mazúr M, et al . Appl. Catal. B: Environ., 2002, 37（2）：91-105.
［12］于向阳, 程继建（YU Xiang-Yang, et al）. 无机材料学报（Journal of Inorganic Materials）, 2001, 16（4）：742-746.
［13］Shyue J, de Guire M R. J. Am. Chem. Soc., 2005, 127（36）：12736-12742.
［14］Yu J C, Lin J, Kwok R W M. Journal of Photochemistry and Photobiology A: Chemistry, 1997, 111（1）：199-203.
［15］管晶，梁文懂. 应用化工, 2006, 35（2）：117-119.
［16］于书平, 古国榜, 李新军. 化学通报, 2004, 11（9）：835-840.
［17］王俊刚, 李新军, 郑少健.化学学报, 2005, 63（7）：592-596.
［18］吴树新, 马智, 秦永宁. 物理化学学报, 2004, 20（2）：138-143.
［19］Yu J C, Lin J, Kwok R W M. J. Phys.Chem.B, 1998, 102（26）：5094-5098.
［20］Lin J, Yu J C, Lo D, et al. J. Catal., 1999, 183（2）：368-372.
［21］Huang Y, Zheng Z, Ai Z, et al. J.Phys.Chem.B, 2006, 110（39）：19323-19328.
［22］Yu J G,Liu S W,Zhou M H . J.Phys.Chem.B, 2008, 112（6）：2050-2057.

[1]	XUE Hongyun, WANG Congyu, MAHMOOD Asad, YU Jiajun, WANG Yan, XIE Xiaofeng, SUN Jing. Two-dimensional g-C₃N₄ Compositing with Ag-TiO₂ as Deactivation Resistant Photocatalyst for Degradation of Gaseous Acetaldehyde [J]. Journal of Inorganic Materials, 2022, 37(8): 865-872.
[2]	CHI Congcong, QU Panpan, REN Chaonan, XU Xin, BAI Feifei, ZHANG Danjie. Preparation of SiO₂@Ag@SiO₂@TiO₂ Core-shell Structure and Its Photocatalytic Degradation Property [J]. Journal of Inorganic Materials, 2022, 37(7): 750-756.
[3]	PAN Bichen,REN Penghe,ZHOU Tejun,CAI Zhenyang,ZHAO Xiaojun,ZHOU Hongming,XIAO Lairong. Microstructure and Property of Thermal Insulation Coating on the Carbon Fiber Reinforced Epoxy Resin Composites [J]. Journal of Inorganic Materials, 2020, 35(8): 947-952.
[4]	ZHU Ben-Bi,ZHANG Wang,ZHANG Zhi-Jian,ZHANG Jian-Zhong,IMRAN Zada,ZHANG Di. Photothermal Enhanced Photocatalytic Properties of Titanium Dioxide (B)/Glass Fiber Cloth [J]. Journal of Inorganic Materials, 2019, 34(9): 961-966.
[5]	LI Yuan-Yang, JIANG Bo. λ/4-λ/2 Double-layer Broadband Antireflective Coatings with Superhydrophilicity and Photocatalysis [J]. Journal of Inorganic Materials, 2019, 34(2): 159-163.
[6]	SUI Li-Li, WANG Run, ZHAO Dan, SHEN Shu-Chang, SUN Li, XU Ying-Ming, CHENG Xiao-Li, HUO Li-Hua. Construction of Hierarchical α-MoO₃ Hollow Microspheres and Its High Adsorption Performance towards Organic Dyes [J]. Journal of Inorganic Materials, 2019, 34(2): 193-200.
[7]	SU Kun, ZHANG Ya-Ru, LU Fei, ZHANG Jun, WANG Xi. Platinum Decorated Titanium Dioxide Nanosheets for Efficient Photoelectrocatalytic Hydrogeu Evolution Reaction [J]. Journal of Inorganic Materials, 2019, 34(11): 1200-1204.
[8]	LI Bo, HAO Wen, WEN Xiao-Gang. Semi-hollow/Solid ZnMn₂O₄ Microspheres: Synthesis and Performance in Li Ion Battery [J]. Journal of Inorganic Materials, 2018, 33(3): 307-312.
[9]	FAN Wen, WU Li-Min. Controllable Preparation of Nano-TiO₂ Lens by Silicon Oil Two-step Dehydration Method [J]. Journal of Inorganic Materials, 2018, 33(12): 1337-1342.
[10]	LIN Jing-Cheng, TANG Xiao, CHU Wan-Yi. Synthesis and Photocatalysis Property of Ultra-small TiO₂ Nanoclusters in Aqueous Media [J]. Journal of Inorganic Materials, 2017, 32(8): 863-869.
[11]	LI Cui-Xia, JIN Hai-Ze, YANG Zhi-Zhong, YANG Xuan, DONG Qi-Zheng, LI Ting-Ting. Preparation and Photocatalytic Properties of Mesoporous RGO/TiO₂ Composites [J]. Journal of Inorganic Materials, 2017, 32(4): 357-364.
[12]	CAI Wei-Wei, LI Jiao, HE Jing, WANG Wei-Wei. Controlled Synthesis and Photocatalytic Activity Evaluation of Nanostructured Ag₃PO₄ [J]. Journal of Inorganic Materials, 2017, 32(3): 263-268.
[13]	SONG Jia, XU Ying, MO Yan-Ping, LI Yong-An. Enhanced Photocatalytic Activity of Bi₂WO₆ by the Synergistic Action of Ti(IV) and Graphene Bi-cocatalysts [J]. Journal of Inorganic Materials, 2017, 32(3): 269-274.
[14]	MA Ya-Ting, LI Qiao-Ling. Preparation and Characterization of TiO₂/Co₃O₄ Nanocomposites and Their Photocatalytic Activity for Hydrogen Evolution [J]. Journal of Inorganic Materials, 2016, 31(8): 841-844.
[15]	ZOU Jian-Peng, YANG Hong-Zhi, XIAO Ping, PAN Yi-Feng. Controllable Fabrication of Calcium Carbonate Hollow Microspheres with Micro-nano Hierarchical Structure [J]. Journal of Inorganic Materials, 2016, 31(7): 711-718.