Preparation of Anatase TiO2 Nanorods Sol by the Hydrothermal Treatment of Peroxotitanium Acid

doi:10.3724/SP.J.1077.2009.00675

Abstract

Abstract:

Transparent anatase titanium dioxide sol was prepared by the hydrothermal treatment of the peroxotitanium acid (PTA) as precursor, PTA was synthesized by the reaction of hydrogen peroxide with the wellwashed wet titania precipitates. The TiO₂ nanoparticles were characterized by XRD, UV-Vis, PL, FT-Raman and TEM. It is confirmed the nanoparticles are shuttlelike and in the anatase phase with average diameter less than 10nm, most of which grow along the c-axis. The TiO₂ sol shows a band-gap emission at the wavelength of 368nm. Prolonging the hydrothermal time makes TiO₂ nanoparticles align and form the longer nanorods with aspect ratio more than 10 via the oriented attachment mechanism. Moreover, more stronger emission is observed in the sol prepared for a prolonged hydrothermal duration due to the formation of more longer nanorods.

Key words: hydrothermal method, peroxotitauium acid, titania, oriented attachment

CLC Number:

TB44

LI Shuang,ZHANG Qing-Hong,LI Yao-Gang,WANG Hong-Zhi. Preparation of Anatase TiO₂ Nanorods Sol by the Hydrothermal Treatment of Peroxotitanium Acid[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2009.00675.

References

［1］Wilson G J, Will G D, Frost R L, et al. J. Mater. Chem., 2002, 12(6): 1787-1791.
［2］Liu Y J, Claus R O. J. Am. Chem. Soc., 1997, 119(22): 5273-5274.
［3］Jiu J, Isoda S, Wang F, et al. J. Phys. Chem. B, 2006, 110(5): 2087-2092.
［4］Chen X B, Mao S S. Chem. Rev., 2007, 107(7): 2891-2959.
［5］Lee J H, Kang M, Choung S J, et al. Water Res., 2004, 38(3): 713-719.
［6］Xie Y B, Yuan C W. Appl. Catal. B, 2003, 46(2): 251-259.
［7］熊国兴, 张玉红, 姚楠, 等. 一种由四氯化钛制备二氧化钛溶胶的方法, 中国发明专利: CN1323743, 2001.11.28.
［8］高濂, 张青红, 孙静, 等. 一种制备二氧化钛溶胶的简便方法, 中国发明专利: CN1295977, 2001.05.23.
［9］黄冬根, 廖世军, 党志. 化学学报, 2006, 64(17): 1805-1811.
［10］Zeng T Y, Qiu Y, Chen L S, et al. Mater. Chem. Phys., 1998, 56(2): 163-170.
［11］孙静, 高濂 (SUN Jing, et al). 无机材料学报(Journal of Inorganic Materials), 2003, 18(2): 505-508.
［12］Zhang R B, Gao L. Mater. Res. Bull., 2001, 36(11): 1957-1965.
［13］Wang C C, Ying J Y. J. Chem. Mater., 1999, 11(11): 3113-3120.
［14］Vargas S, Arroyo R, Haro E, et al. J. Mater. Res., 1997, 12(2): 439-442.
［15］Seok S I, Kim M S, Suh T S. J. Am. Ceram. Soc., 2002, 85(7):1888-1890.
［16］Zhang Y, Wu L Z, Zeng Q H, et al. J. Phys. Chem.C, 2008, 112(42): 16457-16462.
［17］Ichinose H, Terasaki M, Katsuki H. J. Ceram. Soc. Jpn., 1996, 104(8):715-718.
［18］Ichinose H, Terasaki M, Katsuki H. J. SolGel Sci. Technol., 2001, 22(1/2): 33-40.
［19］Gao Y F, Masuda Y, Peng Z F, et al. J. Mater. Chem., 2003, 13(3): 608-613.
［20］Bao X W, Yan S S, Chen F, et al. Mater.Lett., 2005, 59(4): 412-415.
［21］Ge L, Xu M X, Sun M, et al. J. Sol-Gel Sci. Technol.,2006, 38(1): 47-53.
［22］戈磊, 徐明霞, 方海波, 等. 硅酸盐学报, 2005, 33(3): 330-334.
［23］Bersani D, Lottici P P, Ding X Z. Appl. Phys. Lett., 1998, 72(1): 72-75.
［24］Monticone S, Tufeu R, Kanaev A V, et al. Appl. Surf. Sci., 2000, 162-163: 565-570.
［25］Serpone N, Lawless D, Khairutdinov R. J. Phys. Chem., 1995, 99(45): 16646-16654.
［26］Cozzoli P D, Kornowski A,Weller H. J. Am. Chem. Soc., 2003, 125(47): 14539-14548.
［27］郑燕青, 施尔畏, 李汶军, 等. 中国科学(E辑), 2001, 31(3): 204-212.

[1]	YAO Yishuai, GUO Ruihua, AN Shengli, ZHANG Jieyu, CHOU Kuochih, ZHANG Guofang, HUANG Yarong, PAN Gaofei. In-situ Loaded Pt-Co High Index Facets Catalysts: Preparation and Electrocatalytic Performance [J]. Journal of Inorganic Materials, 2023, 38(1): 71-78.
[2]	MA Hui, TAO Jianghui, WANG Yanni, HAN Yu, WANG Yabin, DING Xiuping. Gold Nanoparticles Supported on Silica & Titania Hybrid Mesoporous Spheres and Their Catalytic Performance Regulation [J]. Journal of Inorganic Materials, 2022, 37(4): 404-412.
[3]	ZHANG Xian, ZHANG Ce, JIANG Wenjun, FENG Deqiang, YAO Wei. Synthesis, Electronic Structure and Visible Light Photocatalytic Performance of Quaternary BiMnVO₅ [J]. Journal of Inorganic Materials, 2022, 37(1): 58-64.
[4]	XIAO Yumin, Li Bin, QIN Lizhao, LIN Hua, LI Qing, LIAO Bin. Efficient Preparation of CuGeO₃ with Controllable Morphology Using CuCl₂ as Copper Source [J]. Journal of Inorganic Materials, 2021, 36(1): 69-74.
[5]	WANG Juhan,WEN Xiong,LIU Chengchao,ZHANG Yuhua,ZHAO Yanxi,LI Jinlin. Preparation and Fischer-Tropsch Synthesis Performance of Hierarchical Co/Al-SiO₂ Catalyst [J]. Journal of Inorganic Materials, 2020, 35(9): 999-1004.
[6]	XU Yun-Qing,WANG Hai-Zeng. Sodium Magnesium Fluoride Particles of Different Morphologies: Prepared by EDTA-assisted Hydrothermal Method [J]. Journal of Inorganic Materials, 2019, 34(9): 933-937.
[7]	GOU Sheng-Lian, NAI Xue-Ying, XIAO Jian-Fei, YE Jun-Wei, DONG Ya-Ping, LI Wu. Preparation and Thermal Decomposition of Basic Magnesium Chloride Whiskers [J]. Journal of Inorganic Materials, 2019, 34(7): 781-785.
[8]	Wei LIU, Kai ZHENG, Dong-Hong WANG, Yi-San LEI, Huai-Lin FAN. Co₃O₄ Nanowire Arrays@Activated Carbon Fiber Composite Materials: Facile Hydrothermal Synthesis and Its Electrochemical Application [J]. Journal of Inorganic Materials, 2019, 34(5): 487-492.
[9]	WANG Wei, LUO Shi-Jie, XIAN Cong, XIAO Qun, YANG Yang, OU Yun, LIU Yun-Ya, XIE Shu-Hong. Enhanced Thermoelectric Properties of Hydrothermal Synthesized BiCl₃/Bi₂S₃ Composites [J]. Journal of Inorganic Materials, 2019, 34(3): 328-334.
[10]	SHENG Peng, ZHAO Guang-Yao, XU Li, LIU Shuang-Yu, WANG Bo, LIU Hai-Zhen, MA Guang, HAN Yu, CHEN Xin. Reductive Preparation of Blue TiO₂ via Deposition of Aluminum [J]. Journal of Inorganic Materials, 2018, 33(9): 942-948.
[11]	JIANG Hai-Yan, XIA Yun-Sheng, LI Yu-Zhen. Preparation and Visible-light-driven Photocatalytic Performance of Porous Rod-like FeVO₄ [J]. Journal of Inorganic Materials, 2018, 33(9): 949-955.
[12]	ZENG Yan-Fei, XIN Guo-Xiang, BULIN Chao-Ke, ZHANG Bang-Wen. One-step Preparation and Electrochemical Performance of 3D Reduced Graphene Oxide/NiO as Supercapacitor Electrodes Materials [J]. Journal of Inorganic Materials, 2018, 33(10): 1070-1076.
[13]	LV Yu-Zhen, SUN Qian, LI Chao, SHAN Bing-Liang, QI Bo, LI Cheng-Rong. Solvothermal Synthesis and Morphological Control of TiO₂ Nanorods Modified with Oleic Acid [J]. Journal of Inorganic Materials, 2017, 32(7): 719-724.
[14]	YU Yang, TONG Ming-Xing, HE Yu-Lan, CHEN Hui, GAO Jing, LI Guo-Hua. Preparation and Visible-light Photocatalytic Performance of Mesoporous Hollow TiO₂/WO₃ Spheres [J]. Journal of Inorganic Materials, 2017, 32(4): 365-371.
[15]	LI Guo-Chang, WANG Ping, LIU Chang-Bo. Hydrothermal Synthesis of Whitlockite [J]. Journal of Inorganic Materials, 2017, 32(11): 1128-1132.

Preparation of Anatase TiO₂ Nanorods Sol by the Hydrothermal Treatment of Peroxotitanium Acid

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments