Chemistry and Physics of Point Defects in Advanced Ceramics

doi:10.3724/sp.j.1077.2009.00417

Abstract

Abstract: he structure and behavior of defects, especial point defects are the key to understand the structural imperfection of structuresensitive advanced ceramics and related devices. A conception of chemistry and physics, especially for electronics on the point defect in the advanced ceramics is briefly reviewed in the present work. Several achieved examples of defect engineering and microscopic control technology for improving some ceramics/devices of electric, magnetic, optical, mechanical and/or biological behavior by defect improve/rebuild are discussed. The knowledge of how defects influence the ceramics/device performance is revealed and point defects provide very useful tools for understanding their basic characteristics and to open up their potentiality of the new advanced ceramics/devices in the near future.

Key words: point defect, oxygen vacancies, Brouwer-Kroger-Vink diagram, defect engineering, chemical bound, advanced ceramics

CLC Number:

TQ174

ZHOU Zhi-Gang,TANG Zi-Long. Chemistry and Physics of Point Defects in Advanced Ceramics[J]. Journal of Inorganic Materials, DOI: 10.3724/sp.j.1077.2009.00417.

References

1］Jost W. Diffusion und Chemische Reaktion in Festen Stoffen. Steinkopff, Dresden: Leipzing, 1937.
［2］Schmalzried H. Solid State Reactions. Weinheim: Verlag Chemie, 2^nd ed., 1981.
［3］Schmalzried H. Chemical Kinetics of Solids. Weinheim: VCH, 1995.
［4］West A R. Basic Solid State Chemistry. 2^nd ed., Chichester: Wiley, 1999.
［5］Kroger F A. Chemistry of Imperfect Crystals. Amsterdam: North Holland, 1964.
［6］Kroger F A, Vink V J. Solid State Physics. Seitz F, Turnbull D. NY: Academic Press, 1976,(3):307.
［7］Lidiard Alan B. Phys. Chem. Chem. Phys., 2003，5：2161-2163.
［8］Zhou Zhi-Gang, Tang Zi-Long. Defects in Chemical Sensors, in Encyclopedia of Sensors, C.A. Grimes et all Eds., USA: American Scientific Publishers, 2006, (2):305-331.
［9］Balian R, Kleman M, Poirier J-P. Physics of Defects, Oxford: NorthHolland Publishing Com., 1981.
［10］Smyth D M. The Defect Chemistry of Metal Oxides, Oxford: Oxford University Press, NY, 2000:61-91.
［11］Stoneham A M. Theory of Defects in Solids, Electronic Structure of Defects in Insulators and Semiconductors. Oxford: Clarendon Press, 1985.
［12］Tilley R J D. Defect Crystal Chemistry and its Applications, NY: Blackie, 1987:143, 155.
［13］Krger F A. The Chemistry of Imperfect Crystals, 2^nd ed., Amsterdam: NorthHolland, 1974, Chapter 7, 9, 13.
［14］Chiang Y M, Birnie Ⅲ D P, Kingery W D. Physical Ceramics, New York: Wiley, 1997.
［15］Lewis G V, Catlow C R A. Radiat. Eff.,1983,73(1-4):307-314.
［16］Sorensen O Toft. Nonstoichiometric Oxides, O. Toft Sorensen Ed., New York: Academic Press, 1981:1-22.
［17］Watts R K. Point Defects in Crystals. New York: John Wiley & Sons, 1977:109, 120
［18］Lax M. Symmetry Principles in Solid State and Molecular Physics, New York: John Wiley & Sons, 1974.
［19］Kelly A, Groves G W. Crystallography and Crystal Defects. London: Longman, 1970.
［20］Larson I, Milling A J. Surface Characterization Methods, Principles, Techniques, and Applications. New York: Marcel Dekker, Inc. 1999:143.
［21］Seiyama T. Chemical Sensor Technology. Tokyo: Kodansha, 1988, (1):1-5.
［22］Yamazoe N. Chemical Sensor Technology. S. Yamauchi.Kodansha, Tokyo,1990, (4):19-26.
［23］ZHOU ZhiGang, ZHAO Gang, WEI Ming, et al. Sensors and Actuators, 1989,19:71.
［24］Zhou ZhiGang, Tang ZiLong, Zhang ZhongTai. Sensors and Actuators B: Chemical, 2003, 93:356.
［25］Brouwer G. Philips. Res. Reports, 1954, 9: 366.
［26］Brouwer G. Philips. Res. Reports, 1957,12: 415.
［27］Waser R. J. Am. Ceram. Soc., 1991,74(8): 1934-1940.
［28］Raymond M V, Smyth D M. J. Phy. Chem.Solids,1996,57(10):1507-1511.
［29］Chan NH, Sharma R K, Smyth D M. J. Am. Ceram. Soc.,1981,64(9):556-562.
［30］Chan NH, Sharma R K, Smyth D M. J. Am. Ceram. Soc.,1982,65(3):167-170.
［31］周志刚，李从周.铁电原理，（电介质物理学，殷之文主编），北京: 科学出版社，1989.
［32］Wouters DJ, Maes H E. Microelectrics & Reliability, 1996,36(1112):1763-1766.
［33］Lupascu Doru C, Genenko Yuri A, Balke Nina. J. Am. Ceram. Soc., 2006, 89(1): 224-229.
［34］Warren W L, Dimos D, Pike G E, et al. Appl. Phys. Lett., 1995, 67(6):866-868.
［35］Wang Junling, TrolierMcKinstryb Susan. Appl. Phy. Lett., 2006, 89(17): 172906-1-3.
［36］Schloss Lawrence F, McIntyre Paul C, Hendrix Bryan C, et al. Appl. Phy. Lett., 2002，81(17):3218-3220.
［37］Whlecke M, Corradi G, Betzler K. Appl. Phys. B:Lasers and Optics, 1996,63: 323-330.
［38］Abdi F, Fontana M D, Aillerie M, et al. Appl. Phys. A: Materials Science & Processing, 2006,83(10):427-434.
［39］Sobolev N A. Physica B:Condensed Matter，2007, 401402: 10-15.
［40］Ledentsov N N, Bimberg D. Journal of Crystal Growth, 2003, 255(1-2):68-80.
［41］Prokes Sharka M, Gole Janes L, Chen Xiaobo, et al. Adv. Funct. Mater., 2005,15(1):161-167.
［42］Funk S, Burghaus U. Phys. Chem. Chem. Phys., 2006, 8: 4805-4813.
［43］Kossoy Anna, Feldman Yishay, Wachtel Ellen, et al. Adv. Funct. Mater., 2007, 17(14):2393-2398.
［44］Shahid P, Lundgrena Rylan J, Lachlan M D, et al. Journal of Solid State Chemistry, 2007,180(12): 3333-3340.
［45］Sudakara C, Kharel P, Suryanarayanan R, et al. Journal of Magnetism and Magnetic Materials, 2008, 320(15): L31-L36.
［46］Debernardi A, Fanciulli M. Physica B, 2007,401-402: 451-453.
［47］Yang KC, Shen P, Gan D. Journal of Solid State Chemistry, 2006,179(11): 3478-3483 .
［48］Kuwabara Akihide. Science and Technology of Advanced Materials, 2007, 8(16): 519-523.
［49］Cormack A N, Freeman C M, Catlow C R A, et al. Defect Structures and Energetics in Nonstoichiometric Rutile, Advances in Ceramics. Westerville, OH: American Ceramic Society, 1987,(23): 283-291.
［50］Kofstad P, Hed AZ. J. Am. Ceram. Soc.,1967,50(12): 681-682.
［51］Shannon R D. Acta Crystallogr. A, 1976,32: 751-767.
［52］Sobolev M M, Cirlin G E,Tonkikh A A. Physica B,2007,401-402:576-579.
［53］Karen Pavel. Journal of Solid State Chemistry, 2006,79(10): 3167-3183. ［54］Roth E G, Holland O W, Venezia V C, et al. Journal of Electronic Materials, 1997,26(11):1349-1354.
［55］Kuhnke M, Fretwurst E, Lindstroem G. Nuclear Instruments and Methods in Physics Research B, 2002, 186(1-4):144-151.
［56］Mac Evoy B C. Solid State Phenomena,1997, 57-58:221.
［57］Mac Evoy B C, Santocchia A, Hall G. Physica B, 1999, 273-274:1045-1049.
［58］Tuller Harry L. Electrochimica Acta, 2003,48(20-22): 2879-2887.
［59］Waser R. Nanoelectronics and Information Technology. Weinheim: WileyVCH, 2003.
［60］Yan Qingfeng, Wang Likui, Zhao X S. Adv. Funct. Mater., 2007,17(18): 3695-3706.
［61］Estreicher Stefan k. Materials Today, 2003,6(6):26-35.
［62］PardoYissar V,Katz E, Wasserman J, et al. J. Am. Chem. Soc., 2003, 125(3): 622-623.
［63］Eglitis RI, Kotomin E A, Borstel G. Computational Materials Science, 2004, 30(3-4): 376-382.
［64］Duque Carlos, Stashans Arvids. Physica B, 2003,336(3-4): 227-235.
［65］Spaeth JM, Overhof H. Point Defect in Semiconductors and Insulators, Determination of Atomic and Electronic Structure from Paramagnetic Hyperfine Interactions. BerlinHeidelberg: SpringerVerlag, 2003.
［66］Dierolf V. Electronic Defects States in Alkali Halides, BerlinHeidelberg: SpringerVerlag, 2003.
［67］Newnham R E. Properties of Materials, Anisotropy, Symmetry, Structure, Oxford: Oxford University Press, 2005. ［68］Catlow C R A. Defect and Disorder in Crystalline and Amorphous Solids, Dordrecht, The Netherlands: Kluwer Academic Publisher, 1994. ［69］Lam Robert, Langet Thomas, Greedan John E. Journal of Solid State Chemistry, 2003,171(1-2):317-323.
［70］Mueller R, Gross D, Lupascu D C. Computational Materials Science, 2006,35(1):42-52.
［71］Moritani Kimikazu, Takagi Ikuji, Moriyama Hirotake. Journal of Nuclear Materials, 2004, 326(2-3):106-113.
［72］Grundy A Nicholas, Povoden E, Ivas T, et al. Calphad, 2006, 30(1):33-41.
［73］Shankar N G, Zhong Z W. Microelectronics Journal, 2005, 36(8):718-724.
［74］Allan N L, Barrera G D, Lavrentiev M Yu, et al. Computational Materials Science, 2006, 36(1-2):42-48.

[1]	JIANG Lili, XU Shuaishuai, XIA Baokai, CHEN Sheng, ZHU Junwu. Defect Engineering of Graphene Hybrid Catalysts for Oxygen Reduction Reactions [J]. Journal of Inorganic Materials, 2022, 37(2): 215-222.
[2]	ZHANG Wenjin, SHEN Qianqian, XUE Jinbo, LI Qi, LIU Xuguang, JIA Husheng. Preparation and Photoelectrochemical Water Oxidation of Hematite Nanobelts Containing Highly Ordered Oxygen Vacancies [J]. Journal of Inorganic Materials, 2021, 36(12): 1290-1296.
[3]	ZHANG Xiuyu,CHEN Xiaofei,WANG Hao,GUO Xun,XUE Jianming. Molecular Dynamics Analysis of Chemical Disorders Induced by Irradiated Point Defects in 6H-SiC [J]. Journal of Inorganic Materials, 2020, 35(8): 889-894.
[4]	WU Fan, ZHAO Ziyan, LI Bangxin, DONG Fan, ZHOU Ying. Interfacial Oxygen Vacancy of Bi₂O₂CO₃/PPy and its Visible-light Photocatalytic NO Oxidation Mechanism [J]. Journal of Inorganic Materials, 2020, 35(5): 541-548.
[5]	LU Qing, HUA Luo-Guang, CHEN Yi-Lin, GAO Bi-Fen, LIN Bi-Zhou. Preparation and Property of Oxygen-deficient Bi₂WO_6-_x Photocatalyst Active in Visible Light [J]. Journal of Inorganic Materials, 2015, 30(4): 413-419.
[6]	ZHAO Qian, WU Ping. Ferromagnetism Induced by Defects in Cr-doped TiO₂ Nanopowders [J]. Journal of Inorganic Materials, 2013, 28(10): 1098-1102.
[7]	ZHOU Zhi-Gang,TANG Zi-Long. Point Defects and Applications of Chemical Sensors Ceramics [J]. Journal of Inorganic Materials, 2009, 24(4): 650-660.
[8]	LI Bao-Shan,ZHU Zhi-Gang,LI Guo-Rong,YIN Qing-Rui,DING Ai-Li. Sintering Behavior of PMnN-PZT Ceramics [J]. Journal of Inorganic Materials, 2005, 20(4): 993-999.
[9]	FENG Shao-Xin,LI Bao-Hui,YANG Zhi,JIN Qing-Hua,GUO Zhen-Ya,DING Da-Tong. Empirical Calculations of the Formation Energies of Point Defects in Lithium Niobate [J]. Journal of Inorganic Materials, 2003, 18(2): 283-288.