Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Preparation and Electrochemical Properties of High-performance LiFePO4

LU Jun-Biao; TANG Zi-Long; ZHANG Zhong-Tai; SHEN Wan-Ci   

  1. Department of Materials Sciences and Engineering; State Key Laboratory of New Ceramics and Fine Processing; Tsinghua University; Beijing 100084; China
  • Received:2004-04-19 Revised:2004-07-12 Published:2005-05-20 Online:2005-05-20

Abstract: Carbon covered LiFePO4 powders with the microstructure of submicro-particles aggregated 5.01wt% carbon content,
and the diameter of aggregated particle of 10μm were synthesized by solid state sintering processing. The capacity and cycle performance were studied
at the charge and discharge rate of C/10, C/5, C/2 and 1C. The results show that below the rate of C/2, the voltage platform and capacity is not sensitive to the rate.
When the rate is increased to 1C, the capacity is decreased and the voltage platform is increased in charge processing and decreased in discharge
processing. Along with the increasing of cycle number, the capacity is increased to its saturate value. After 30 cycles, the capacities are
131.7, 129.1, 123.5 and 114.4 mAh/g, respectively.

Key words: lithium ion battery, cathode material, LiFePO4, granulated

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