Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Surface Modification of Nanosized TiO2 with Silane Coupling Reagent

YAO Chao1,2, GAO Guo-Sheng2, LIN Xi-Ping2, YANG Xu-Jie1, LU Lu-De1, WANG Xin1   

  1. 1. School of Chemical Engineering,Nanjing University of Science \& Technology,
    Nanjing 210094, China;
    2. Jiangsu Polytechnic University, Changzhou 213016, China
  • Received:2005-03-28 Revised:2005-06-07 Published:2006-03-20 Online:2006-03-20

Abstract: The surface modification with silane coupling reagent KH-570 of nanosized TiO2 in the rutile phase pre-coated with silica, was studied. The prepared samples were characterized by FT-IR, XPS,TEM, TG and DTA techniques. According to the spectra of FT-IR and XPS, it can be inferred that the KH-570 is bound on the surface of nanosized TiO2 particles and an organic coating layer is formed. The mass fraction of KH-570 coated on the surface of nanosized TiO2 measured is about 7.42%~8.59%.The wetting experiments show that the hydrophobicity of nanosized TiO2 modified with KH-570 is improved. Mechanical tests reveal that the strength and toughness of the nanosized TiO2 modified with KH-570 are improved simultaneously.

Key words: TiO2, KH-570, surface modification

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