Cs2Ag0.1Na0.9BiCl6:Tm3+ Double Perovskite: Coprecipitation Preparation and Near-infrared Emission

doi:10.15541/jim20230005

Abstract

Abstract:

Cs₂NaBiCl₆ double perovskite with indirect band demonstrates near-infrared (NIR) wide-band emission, but its low efficacy limits its potential applications in the field of NIR. In this work, micron-sized Cs₂Ag_0.1Na_0.9BiCl₆:Tm³⁺ double perovskites were synthesized via the coprecipitation method, which shows enhanced NIR emission. Their optical absorption, photoluminescence emission (PL) and excitation (PLE), time-resolved photoluminescence, and photoluminescence quantum yield (PLQY) were investigated. The Cs₂Ag_0.1Na_0.9BiCl₆:Tm³⁺ shows optical bandgap of 3.06 eV and NIR broad emission peaking at 680 nm under 350 nm excitation due to recombination of self-trapped excitons (STEs). Meanwhile, a new emission peak could be observed at 810 nm due to Tm³⁺ doping. The PLQY in the band range of 780-830 nm can be increased by 6.05 times from 1.67% to 11.77% and in the band range of 650-900 nm can reach 25.22%. This study proves the feasibility of Cs₂Ag_0.1Na_0.9BiCl₆:Tm³⁺ double perovskite as new NIR emission material.

Key words: near-infrared emission, self-trapped excitons, coprecipitation, double perovskite, Cs₂Ag_0.1Na_0.9BiCl₆

CLC Number:

TQ422

WANG Machao, TANG Yangmin, DENG Mingxue, ZHOU Zhenzhen, LIU Xiaofeng, WANG Jiacheng, LIU Qian. Cs₂Ag_0.1Na_0.9BiCl₆:Tm³⁺ Double Perovskite: Coprecipitation Preparation and Near-infrared Emission[J]. Journal of Inorganic Materials, 2023, 38(9): 1083-1088.

Figures/Tables 5

Fig. 1 Microstructure of crystals (a) Crystal structure and (b) XRD patterns of Cs2NaBiCl6, Cs2Ag0.1Na0.9BiCl6, and Cs2Ag0.1Na0.9BiCl6:Tm3+; (c) SEM image (left) and EDS elemental mappings (right) of Cs2Ag0.1Na0.9BiCl6:Tm3+

Fig. 2 Band gaps of Cs2NaBiCl6, Cs2Ag0.1Na0.9BiCl6 and Cs2Ag0.1Na0.9BiCl6:Tm3+ crystals (a) Optical absorption; (b) Tauc plots. Colorful figures are available on the website

Fig. 3 XPS and Raman characterizations of crystals (a) Total XPS spectra, and (b) Ag3d, (c) Na1s, (d) Bi4f, and (e) Cl2p high-resolution XPS spectra of Cs2NaBiCl6, Cs2Ag0.1Na0.9BiCl6 and Cs2Ag0.1Na0.9BiCl6:Tm3+; (f) Raman spectra of Cs2Ag0.1Na0.9BiCl6 and Cs2NaBiCl6

Fig. 4 Optical properties of crystals (a) Photoluminescence emission (PL) spectra, (c) integrated NIR emission intensity and (d) photoluminescence quantum yield (PLQY) of Cs2NaBiCl6, Cs2Ag0.1Na0.9BiCl6 and Cs2Ag0.1Na0.9BiCl6:Tm3+; (b) excitation (PLE) spectra and (e) PL decay curves (λem = 680 nm) of Cs2Ag0.1Na0.9BiCl6 and Cs2Ag0.1Na0.9BiCl6:Tm3+; Colorful figures are available on website

Fig. 5 Schematic diagram of simplified energy levels for Cs2Ag0.1Na0.9BiCl6:Tm3+

References 22

[1]	HAN G, LI G, HUANG J, et al. Two-photon-absorbing ruthenium complexes enable near infrared light-driven photocatalysis. Nature Communications, 2022, 13: 2288. DOI PMID
[2]	MARQUES E J, DE FREITAS S T, PIMENTEL M F, et al. Rapid and non-destructive determination of quality parameters in the ‘Tommy Atkins’ mango using a novel handheld near infrared spectrometer. Food Chemistry, 2016, 197: 1207. DOI URL
[3]	HAYASHI D, VAN DONGEN A M, BOEREKAMP J, et al. A broadband LED source in visible to short-wave-infrared wavelengths for spectral tumor diagnostics. Applied Physics Letters, 2017, 110(23): 233701. DOI URL
[4]	LIU D, LI G, DANG P, et al. Simultaneous broadening and enhancement of Cr³⁺ photoluminescence in LiIn₂SbO₆ by chemical unit cosubstitution: night-vision and near-infrared spectroscopy detection applications. Angewandte Chemie International Edition, 2021, 60(26): 14644. DOI URL
[5]	ZHAO H, JI T, SUN T, et al. Comparative study on photobiomodulation between 630 nm and 810 nm LED in diabetic wound healing both in vitro and in vivo. Journal of Innovative Optical Health Sciences, 2022, 15(2): 2250010. DOI URL
[6]	SHI L, REN X, WANG Q, et al. Tridecaboron diphosphide: a new infrared light active photocatalyst for efficient CO₂ photoreduction under mild reaction conditions. Journal of Materials Chemistry A, 2021, 9(4): 2421. DOI URL
[7]	FRIBERG T R, KARATZA E C. The treatment of macular disease using a micropulsed and continuous wave 810-nm diode laser. Ophthalmology, 1997, 104(12): 2030. DOI PMID
[8]	RAJENDRAN V, FANG M H, GUZMAN G N D, et al. Super broadband near-infrared phosphors with high radiant flux as future light sources for spectroscopy applications. ACS Energy Letters, 2018, 3(11): 2679. DOI URL
[9]	DE WOLF S, HOLOVSKY J, MOON S J, et al. Organometallic halide perovskites: sharp optical absorption edge and its relation to photovoltaic performance. The Journal of Physical Chemistry Letters, 2014, 5(6): 1035. DOI URL
[10]	BRENNER T M, EGGER D A, KRONIK L, et al. Hybrid organic- inorganic perovskites: low-cost semiconductors with intriguing charge- transport properties. Nature Reviews Materials, 2016, 1: 15007. DOI
[11]	GUO B, LAI R, JIANG S, et al. Ultrastable near-infrared perovskite light-emitting diodes. Nature Photonics, 2022, 16(9): 637. DOI
[12]	VASILOPOULOU M, FAKHARUDDIN A, GARCÍA DE ARQUER F P, et al. Advances in solution-processed near-infrared light-emitting diodes. Nature Photonics, 2021, 15(9): 656. DOI
[13]	ZHAO X, TAN Z K. Large-area near-infrared perovskite light- emitting diodes. Nature Photonics, 2020, 14(4): 215. DOI
[14]	YUAN M, QUAN L N, COMIN R, et al. Perovskite energy funnels for efficient light-emitting diodes. Nature Nanotechnology, 2016, 11(10): 872. DOI PMID
[15]	STROYUK O, RAIEVSKA O, HAUCH J, et al. Doping/alloying pathways to lead-free halide perovskites with ultimate photoluminescence quantum yields. Angewandte Chemie International Edition, 2022, 62(3): e202212668.
[16]	LUO J, WANG X, LI S, et al. Efficient and stable emission of warm-white light from lead-free halide double perovskites. Nature, 2018, 563(7732): 541. DOI
[17]	ZHANG G, WANG D, LOU B, et al. Efficient broadband near-infrared emission from lead-free halide double perovskite single crystal. Angewandte Chemie International Edition, 2022, 61(33): e202207454.
[18]	YAO M, WANG L, YAO J, et al. Improving lead-free double perovskite Cs₂NaBiCl₆ nanocrystal optical properties via ion doping. Advanced Optical Materials, 2020, 8(8): 1901919. DOI URL
[19]	HU Y, LI Z, WANG Z, et al. Suppressing local dendrites hotspot via current density redistribution using a superlithiophilic membrane for stable lithium metal anode. Advanced Science, 2023, doi: 10.1002/advs.202206995. DOI
[20]	ZHENG Z, LIANG W, LIN R, et al. Facile synthesis of zinc indium oxide nanofibers distributed with low content of silver for superior antibacterial activity. Small Structures, 2023, 4(4): 2200291. DOI URL
[21]	CHENG X, XIE Z, ZHENG W, et al. Boosting the self-trapped exciton emission in alloyed Cs₂(Ag/Na)InCl₆ double perovskite via Cu⁺ doping. Advanced Science, 2022, 9(7): 2103724. DOI URL
[22]	ZHENG W, SUN R, LIU Y, et al. Excitation management of lead-free perovskite nanocrystals through doping. ACS Applied Materials & Interfaces, 2021, 13(5): 6404.

Cs₂Ag_0.1Na_0.9BiCl₆:Tm³⁺ Double Perovskite: Coprecipitation Preparation and Near-infrared Emission

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