Journal of Inorganic Materials ›› 2023, Vol. 38 ›› Issue (6): 656-662.DOI: 10.15541/jim20220511
• RESEARCH ARTICLE • Previous Articles Next Articles
KONG Guoqiang1(), LENG Mingzhe2(
), ZHOU Zhanrong2(
), XIA Chi1, SHEN Xiaofang2
Received:
2022-09-01
Revised:
2022-11-14
Published:
2022-12-09
Online:
2022-12-09
Contact:
LENG Mingzhe, lecturer. E-mail: lmz_198810@163.com;About author:
KONG Guoqiang (1986-), male, PhD, senior engineer. E-mail: kongguoqiang2010@163.com
Supported by:
CLC Number:
KONG Guoqiang, LENG Mingzhe, ZHOU Zhanrong, XIA Chi, SHEN Xiaofang. Sb Doped O3 Type Na0.9Ni0.5Mn0.3Ti0.2O2 Cathode Material for Na-ion Battery[J]. Journal of Inorganic Materials, 2023, 38(6): 656-662.
Fig. 6 Performance of Na-ion batteries with NMTSbx as electrodes (a) Charging and discharging curves of Na-ion batteries with samples as electrodes for the first cycle at 1C; (b) Cycling performance of Na-ion batteries with samples as electrodes at 1C for 200 cycles; (c, d) Charging and discharging curves of Na-ion batteries with samples as electrodes for initial 3 cycles at 5C; (e) Coulombic efficiencies of Na-ion batteries with NMTSbx as electrodes for 200 cycles at 1C Colorful figures are available on website
Na | Ni | Mn | Ti | Sb | |
---|---|---|---|---|---|
NMTSb0 | 0.913 | 0.486 | 0.288 | 0.181 | 0 |
NMTSb0.02 | 0.924 | 0.471 | 0.284 | 0.186 | 0.023 |
NMTSb0.04 | 0.920 | 0.452 | 0.287 | 0.184 | 0.039 |
NMTSb0.06 | 0.929 | 0.435 | 0.279 | 0.184 | 0.061 |
Table S1 ICP-AES results of O3-NMTSbx (x=0, 0.02, 0.04, 0.06) (Stoichiometric ratio)
Na | Ni | Mn | Ti | Sb | |
---|---|---|---|---|---|
NMTSb0 | 0.913 | 0.486 | 0.288 | 0.181 | 0 |
NMTSb0.02 | 0.924 | 0.471 | 0.284 | 0.186 | 0.023 |
NMTSb0.04 | 0.920 | 0.452 | 0.287 | 0.184 | 0.039 |
NMTSb0.06 | 0.929 | 0.435 | 0.279 | 0.184 | 0.061 |
a/nm | b/nm | c/nm | V/nm3 | Rwp/% | Rp/% | |
---|---|---|---|---|---|---|
NMTSb0 | 0.29812 | 0.29812 | 1.600487 | 0.1232 | 4.92 | 5.53 |
NMTSb0.04 | 0.29790 | 0.29790 | 1.608391 | 0.1236 | 5.65 | 6.32 |
Table S2 Lattice parameters of materials with NMTSb0and NMTSb0.04
a/nm | b/nm | c/nm | V/nm3 | Rwp/% | Rp/% | |
---|---|---|---|---|---|---|
NMTSb0 | 0.29812 | 0.29812 | 1.600487 | 0.1232 | 4.92 | 5.53 |
NMTSb0.04 | 0.29790 | 0.29790 | 1.608391 | 0.1236 | 5.65 | 6.32 |
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