Heavy-Fermion YbAl3 Materials: One-step Synthesis and Enhanced Thermoelectric Performance

doi:10.15541/jim20220318

Abstract

Abstract:

Microstructure plays a key role in tuning physical properties of materials. Here YbAl₃ materials with high figure of merit ZT of 0.35 at 300 K was directly synthesized with Yb and Al pure powders through one-step spark plasma sintering process in 10 min. The excellent thermoelectric performance is attributed to the simultaneous reduction in the lattice thermal conductivity by 47% and electronic thermal conductivity by 27% at 300 K. The remarkable decrease in the electronic thermal conductivity is ascribed to the enhanced scattering of electrons by nanocrystals with 5-20 nm in diameter, strip-like non-crystal with several nanometers in width and various atomic-scale distortions. The substantial decline in the lattice thermal conductivity originates from the enhanced scattering of phonons due to multi-scale microstructures spanning from nanoscale to mesoscale. This work demonstrates that one-step spark plasma sintering process is an efficient strategy to rapidly synthesize YbAl₃ materials with multi-scale microstructures and enhanced thermoelectric performance.

Key words: YbAl₃thermoelectric materials, one-step synthesis, microstructure, thermoelectric performance

CLC Number:

TQ174

HE Danqi, WEI Mingxu, LIU Ruizhi, TANG Zhixin, ZHAI Pengcheng, ZHAO Wenyu. Heavy-Fermion YbAl₃ Materials: One-step Synthesis and Enhanced Thermoelectric Performance[J]. Journal of Inorganic Materials, 2023, 38(5): 577-582.

Figures/Tables 5

Fig. 1 XRD patterns of SPS1, SPS2 and MQA-SPS samples

Fig. 2 Microstructures of SPS1, SPS2 and MQA-SPS samples (a-c) FESEM images of (a) MQA-SPS, (b) SPS1, and (c) SPS2; (d) Enlarged FESEM image of the rectangular region in (c)

Fig. 3 Multi-scale microstructures in SPS1 (a) HRTEM image of YbAl3 nanocrystals with 5-20 nm in diameter; (b) HRTEM image of nanoscale strip-like noncrystal in YbAl3 crystals; (c, d) HRTEM images of high-density distortions in YbAl3 crystals with insets showing IFFT images of the marked regions

Fig. 4 Temperature dependence of (a) electrical conductivity and (b) Seebeck coefficient for SPS1, SPS2 and MQA-SPS with inset showing the temperature dependence of power factor

Fig. 5 Temperature dependences of (a) thermal conductivity, (b) carrier thermal conductivity, (c) lattice thermal conductivity, and (d) ZT values for the samples for SPS1, SPS2 and MQA-SPS

References 29

[1]	BELL L E. Cooling,heating, generating power, and recovering waste heat with thermoelectric systems. Science, 2008, 321(5895): 1457. DOI URL
[2]	KIM H S, LIU W S, REN Z F. Bridge between materials and devices of thermoelectric power generators. Energy Environment Science, 2017, 10(1): 69. DOI URL
[3]	BISWAS K, HE J Q, BLUM I D, et al. High-performance bulk thermoelectrics with all-scale hierarchical architectures. Nature, 2012, 489(7416): 414. DOI
[4]	YU J, ZHAO W Y, WEI P, et al. Enhanced thermoelectric performance of (Ba,In) double-filled skutterudites via randomly arranged micropores. Applied Physics Letters, 2014, 104: 142104.
[5]	XU Z J, WU H J, ZHU T J, et al. Attaining high mid-temperature performance in (Bi,Sb)₂Te₃ thermoelectric materials via synergistic optimization. NPG Asia Materials, 2016, 8: e302. DOI
[6]	WU D, ZHAO L D, HAO S Q, et al. Origin of the high performance in GeTe-based thermoelectric materials upon Bi₂Te₃ doping. Journal of the American Chemical Society, 2014, 136(32): 11412. DOI URL
[7]	MAO J, KIM H, SHUAI S J, et al. Thermoelectric properties of materials near the band crossing line in Mg₂Sn-Mg₂Ge-Mg₂Si system. Acta Materials, 2016, 103: 633. DOI URL
[8]	ZHANG J, SONG L R, PEDERSEN S H, et al. Discovery of high-performance low-cost n-type Mg₃Sb₂-based thermoelectric materials with multi-valley conduction bands. Nature Communications, 2017, 8: 13901. DOI
[9]	STEWART G R, FISK Z, WIRE M S. New Ce heavy-Fermion system: CeCu₆. Physical Review B, 1984, 30(1): 482. DOI URL
[10]	STRANGE P, SVANE A, TEMMERMAN W M, et al. Understanding the valency of rare earths from first-principles theory. Nature, 1999, 399(6738): 756. DOI URL
[11]	ROWE D M, MIN G, KUZNESTSOV V L. Thermoelectric properties of not-pressed YbAl₃ compound over temperature range150-800 K. 16th International Conference on Thermoelectrics, Dresden, 1997: 528.
[12]	ROWE D M, MIN G, KUZNESTSOV V L. Electrical resistivity and Seebeck coefficient of hot-pressed YbAl₃ over the temperature range 150-700 K. Philosophical Magazine Letters, 1998, 77(2): 105. DOI URL
[13]	ROWE D M, KUZNETSOV V L, KUZNETSOVA L A, et al. Electrical and thermal transport properties of intermediate-valence YbAl₃. Journal of Applied Physics, 2002, 35(17): 2183.
[14]	HE T, CALVARESE T G, CHEN J Z, et al. Origin of low thermal conductivity in α-Mn: enhancing the ZT of YbAl₃ and CoSb₃ through Mn addition. 24th International Conference on Thermoelectrics, Clemson, 2005: 437.
[15]	CHRISTIANSON A D, FANELLI V R, LAWRENCE J M, et al. Localized excitation in the hybridization gap in YbAl₃. Physical Review Letters, 2006, 96(11): 117206. DOI URL
[16]	ROJAS D P, FERNÁNDEZ BARQUÍN L, ESPESO J I, et al. Reduction of the Yb valence in YbAl₃ nanoparticles. Physical Review B, 2008, 78(9): 094412. DOI URL
[17]	ZHOU J, SUN Z M, CHENG X, et al. Phase stability and electronic structures of YbAl_3-_xM_x (M=Mg, Cu, Zn, In and Sn) studied by first-principles calculations. Intermetallics, 2009, 17(12): 995. DOI URL
[18]	CHEN C K, SANG X H, CUI W J, et al. Atomic-resolution fine structure and chemical reaction mechanism of Gd/YbAl₃ thermoelectric-magnetocaloric heterointerface. Journal of Alloys and Compounds, 2020, 831: 154722. DOI URL
[19]	OČKO M, ŽONJA S, AVIANI I, et al. Transport properties of the YbAl₃ compound: on the energy scales of YbAl₃ from thermopower data. Journal of Alloys and Compounds, 2011, 509: 6999. DOI URL
[20]	KATSUYAMA S, SUZUKI M, TANAKA T. Effect of addition of B or C on thermoelectric properties of heavy fermion intermetallic compound YbAl₃. Journal of Alloys and Compounds, 2012, 513: 189. DOI URL
[21]	LEHR G J, MORELLI D T. Synthesis, crystal structure, and thermoelectric properties of the YbAl₃-ScAl₃ solid solution. Intermetallics, 2013, 32: 225. DOI URL
[22]	LEHR G J, MORELLI D T. Thermoelectric properties of Yb_1-_x(Er,Lu)_xAl₃ solid solutions. Journal of Electronic Materials, 2013, 42(7): 1697. DOI URL
[23]	LI J Q, LIU X Y, LI Y, et al. Influence of Sn substitution on the thermoelectric properties in YbAl₃. Journal of Alloys and Compounds, 2014, 600: 8. DOI URL
[24]	LI J Q, LIU X Y, LI Y, et al. Effects of second phase Yb₅Sb₃ on the thermoelectric properties of YbAl₃. Journal of Electronic Materials, 2014, 43(4): 1289. DOI URL
[25]	HE D Q, ZHAO W Y, MU X, et al. Preparation and thermoelectric properties of YbAl₃ thermoelectric materials with excessive Al. Journal of Electronic Materials, 2015, 44(6): 1919. DOI URL
[26]	ZHAO W Y, WEI P, ZHANG Q J, et al. Enhanced thermoelectric performance in barium and indium double-filled skutterudite bulk materials via orbital hybridization induced by Indium filler. Journal of the American Chemical Society, 2009, 131(10): 3713. DOI URL
[27]	LIANG J H, FAN D D, JIANG P H, et al. First-principles study of the thermoelectric properties of intermetallic compound YbAl₃. Intermetallics, 2017, 87: 27. DOI URL
[28]	HE D Q, ZHAO W Y, MU X, et al. Enhanced thermoelectric performance of heavy-fermion YbAl₃ via multi-scale microstructures. Journal of Alloys and Compounds, 2017, 725: 1297. DOI URL
[29]	HU L P, GAO H L, LIU X H, et al. Enhancement in thermoelectric performance of bismuth telluride based alloys by multi-scale microstructural effects. Journal of Materials Chemistry, 2012, 22(32): 16484. DOI URL

Heavy-Fermion YbAl₃ Materials: One-step Synthesis and Enhanced Thermoelectric Performance

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