Journal of Inorganic Materials ›› 2022, Vol. 37 ›› Issue (7): 710-716.DOI: 10.15541/jim20210653
• RESEARCH ARTICLE • Previous Articles Next Articles
JIANG Yiyi1(), SHEN Min1, SONG Banxia1, LI Nan1, DING Xianghuan1, GUO Leyi2, MA Guoqiang1,2(
)
Received:
2021-10-22
Revised:
2022-01-19
Published:
2022-07-20
Online:
2022-03-18
Contact:
MA Guoqiang, senior engineer. E-mail: erguo87@163.com; maguoqiang@sinochem.comAbout author:
JIANG Yiyi(1988-), female, Master. E-mail: jiangyiyi@sinochem.com
Supported by:
CLC Number:
JIANG Yiyi, SHEN Min, SONG Banxia, LI Nan, DING Xianghuan, GUO Leyi, MA Guoqiang. Effect of Dual-functional Electrolyte Additive on High Temperature and High Voltage Performance of Li-ion Battery[J]. Journal of Inorganic Materials, 2022, 37(7): 710-716.
Fig. 3 (a) Gas swelling rates and ACR change rates, (b) K values and capacity recovery rates, (c) charge and discharge curves of pouch cells with and without TVS in electrolytes after storage at 60 ℃ for 14 d
Sample | Ni/(×10-4, %) | Co/(×10-4, %) | Mn/(×10-4, %) |
---|---|---|---|
Base | 90 | 21 | 130 |
TVS | 35 | 4 | 69 |
Table 1 Uess fractions of Ni, Co and Mn ions deposited on anodes from pouch cell with and without TVS in electrolyte stored at cutoff potential of 4.4 V and temperature of 60 ℃ for 14 d
Sample | Ni/(×10-4, %) | Co/(×10-4, %) | Mn/(×10-4, %) |
---|---|---|---|
Base | 90 | 21 | 130 |
TVS | 35 | 4 | 69 |
Sample | CO/µL | CH4/µL | CO2/µL | C2H4/µL | H2/µL |
---|---|---|---|---|---|
Base | 393.3 | 253.2 | 209.3 | 67.0 | 17.6 |
TVS | 9.2 | 4.8 | 2.2 | 1.1 | 0.2 |
Table S1 Gas composition and contents of pouch cells with and without TVS in electrolytes stored at cutoff potential of 4.4 V and temperature of 60 ℃ for 14 d
Sample | CO/µL | CH4/µL | CO2/µL | C2H4/µL | H2/µL |
---|---|---|---|---|---|
Base | 393.3 | 253.2 | 209.3 | 67.0 | 17.6 |
TVS | 9.2 | 4.8 | 2.2 | 1.1 | 0.2 |
Fig. 4 Cycling performance of pouch cells with and without TVS in electrolytes at 45 ℃ (a) Discharge capacity and (b) ΔV vs cycle number; EIS plots of (c) pouch full cells, (d) graphite/graphite symmetric cells and (e) NCM622/NCM622 symmetric cells before and after 100 cycles
Fig. S2 Cycling performance of pouch cells with and without TVS in electrolytes at 45 ℃ (a) Differential capacity (dQ/dV) versus potential of Base; (b) Differential capacity (dQ/dV) versus potential of TVS
Sample | Full cell | Anode symmetric cell | Cathode symmetric cell | ||||||
---|---|---|---|---|---|---|---|---|---|
Rs/mΩ | Rsei/mΩ | Rct/mΩ | Rs/mΩ | Rsei/mΩ | Rct/mΩ | Rs/mΩ | Rsei/mΩ | Rct/mΩ | |
Base-before cycle | 16.2 | 7.5 | 14.2 | 3.4 | 4.7 | 23.2 | 2.6 | 116.1 | 21.2 |
Base-after cycle | 46.7 | 9.1 | 19.3 | 4.2 | 17.1 | 26.5 | 2.7 | 144.3 | 26.7 |
TVS-before cycle | 16.4 | 8.9 | 25.8 | 4.5 | 20.5 | 43.3 | 2.1 | 86.1 | 18.2 |
TVS-after cycle | 38.5 | 10.2 | 25.4 | 4.8 | 22.6 | 43.8 | 2.2 | 100.4 | 18.1 |
Table S2 Fitted EIS results before and after 100 cycles of pouch full cells and corresponding symmetric cells with and without TVS in electrolytes
Sample | Full cell | Anode symmetric cell | Cathode symmetric cell | ||||||
---|---|---|---|---|---|---|---|---|---|
Rs/mΩ | Rsei/mΩ | Rct/mΩ | Rs/mΩ | Rsei/mΩ | Rct/mΩ | Rs/mΩ | Rsei/mΩ | Rct/mΩ | |
Base-before cycle | 16.2 | 7.5 | 14.2 | 3.4 | 4.7 | 23.2 | 2.6 | 116.1 | 21.2 |
Base-after cycle | 46.7 | 9.1 | 19.3 | 4.2 | 17.1 | 26.5 | 2.7 | 144.3 | 26.7 |
TVS-before cycle | 16.4 | 8.9 | 25.8 | 4.5 | 20.5 | 43.3 | 2.1 | 86.1 | 18.2 |
TVS-after cycle | 38.5 | 10.2 | 25.4 | 4.8 | 22.6 | 43.8 | 2.2 | 100.4 | 18.1 |
Fig. 5 SEM images of cathodes from pouch cells (a) without and (b) with TVS in electrolytes after 100 cycles; (c) XPS spectra of cathodes from pouch cells without and with TVS in electrolytes after 10 cycles
Fig. S3 SEM images of anodes from pouch cells (a) without and (b) with TVS in electrolytes after 100 cycles; (c) Si2p XPS spectra of anode from pouch cell with TVS in electrolyte after 10 cycles
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