Journal of Inorganic Materials ›› 2021, Vol. 36 ›› Issue (11): 1137-1144.DOI: 10.15541/jim20210105
• RESEARCH ARTICLE • Previous Articles Next Articles
ZENG Fanxin(), LIU Chuang, CAO Yuliang(
)
Received:
2021-02-21
Revised:
2021-04-05
Published:
2021-11-20
Online:
2021-04-25
Contact:
CAO Yuliang, professor. E-mail: ylcao@whu.edu.cn
About author:
ZENG fanxin(1995-), male, Master candidate. E-mail: fxzeng1117@126.com
Supported by:
CLC Number:
ZENG Fanxin, LIU Chuang, CAO Yuliang. Sodium Storage Behavior of Nanoporous Sb/MCNT Anode Material with High Cycle Stability by Dealloying Route[J]. Journal of Inorganic Materials, 2021, 36(11): 1137-1144.
Fig. 3 (a) TEM image, (b) HRTEM image, (c) SAED pattern, (d) SEM image and the corresponding (e) Sb, (f) C, and (g) O elemental mapping images of De-Sb/MCNT
Fig. 4 XRD patterns of (a) AlSb, (b) Raw-Sb, De-Sb, Raw-Sb/MCNT and De-Sb/MCNT, (c) Raman spectra of MCNT, De-Sb and De-Sb/MCNT, and (d) XPS spectrum of De-Sb/MCNT Colorful figures are available on website
Fig. 5 (a) N2 adsorption-desorption isotherms of Raw-Sb, De-Sb, Raw-Sb/MCNT and De-Sb/MCNT, and (b) pore size distributions of Raw-Sb and De-Sb Colorful figures are available on website
Fig. 6 (a) Cyclic voltammogram and (b) Galvanostatic charge/discharge voltage profile at 200 mA·g-1 of De-Sb/MCNT, (c) long-term cycling performance of Raw-Sb/MCNT and De-Sb/MCNT at 800 mA·g-1, and (d) rate performance of De-Sb/MCNT Colorful figures are available on website
Fig. 7 EIS plots of Raw-Sb/MCNT and De-Sb/MCNT after 1 and 50 cycles with inset showing the corresponding equivalent circuit Colorful figures are available on website
Sample | Cycle number | RS/Ω | RSEI/Ω | RCT/Ω |
---|---|---|---|---|
Raw-Sb/MCNT | 1 | 2.89 | 37.62 | 23.70 |
50 | 4.38 | 43.29 | 142.90 | |
De-Sb/MCNT | 1 | 1.32 | 21.44 | 44.84 |
50 | 2.68 | 24.44 | 51.25 |
Table 1 Fitting results of the EIS plots of Raw-Sb/MCNT and De-Sb/MCNT
Sample | Cycle number | RS/Ω | RSEI/Ω | RCT/Ω |
---|---|---|---|---|
Raw-Sb/MCNT | 1 | 2.89 | 37.62 | 23.70 |
50 | 4.38 | 43.29 | 142.90 | |
De-Sb/MCNT | 1 | 1.32 | 21.44 | 44.84 |
50 | 2.68 | 24.44 | 51.25 |
Material | Capacity/(mAh·g-1) | Cycling stability | Ref. |
---|---|---|---|
Sb/Super P | 610 (0.1 A·g-1) | 94% after 100 cycles | [1] |
Sb/MCNT | 502 (0.1 A·g-1) | 76.1% after 120 cycles | [2] |
SbOx/RGO | 427 (0.1 A·g-1) | 95% after 100 cycles | [3] |
Sb-AlC0.75-C | 295 (0.1 A·g-1) | 83% after 100 cycles | [4] |
Dealloyed Sb | 620 (0.1 A·g-1) | 90.2 % after 100 cycles | [5] |
Sb nanoparticles/RGO | 476 (0.1 A·g-1) | 81% after 45 cycles | [6] |
Sb2S3/C | 598 (0.2 A·g-1) | 93.1% after 100 cycles | [7] |
Nanoporous Sb/C | 436 (0.05 A·g-1) | No fading after 200 cycles | [8] |
Antimony nanocrystals/C | 520 (0.1 A·g-1) | 88% after 500 cycles | [9] |
SiC-Sb-Cu-C | 542 (0.02 A·g-1) | No fading after 100 cycles | [10] |
De-Sb/MCNT | 408.6 (0.2 A·g-1) | 97% after 200 cycles, 88% after 330 cycles | This work |
Table S1 Electrochemical performance of different Sb-based materials as Na ion battery electrodes
Material | Capacity/(mAh·g-1) | Cycling stability | Ref. |
---|---|---|---|
Sb/Super P | 610 (0.1 A·g-1) | 94% after 100 cycles | [1] |
Sb/MCNT | 502 (0.1 A·g-1) | 76.1% after 120 cycles | [2] |
SbOx/RGO | 427 (0.1 A·g-1) | 95% after 100 cycles | [3] |
Sb-AlC0.75-C | 295 (0.1 A·g-1) | 83% after 100 cycles | [4] |
Dealloyed Sb | 620 (0.1 A·g-1) | 90.2 % after 100 cycles | [5] |
Sb nanoparticles/RGO | 476 (0.1 A·g-1) | 81% after 45 cycles | [6] |
Sb2S3/C | 598 (0.2 A·g-1) | 93.1% after 100 cycles | [7] |
Nanoporous Sb/C | 436 (0.05 A·g-1) | No fading after 200 cycles | [8] |
Antimony nanocrystals/C | 520 (0.1 A·g-1) | 88% after 500 cycles | [9] |
SiC-Sb-Cu-C | 542 (0.02 A·g-1) | No fading after 100 cycles | [10] |
De-Sb/MCNT | 408.6 (0.2 A·g-1) | 97% after 200 cycles, 88% after 330 cycles | This work |
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