Stable Zirconium Carbide Fibers Fabricated by Centrifugal Spinning Technique

doi:10.15541/jim20200031

Journal of Inorganic Materials ›› 2020, Vol. 35 ›› Issue (12): 1385-1390.DOI: 10.15541/jim20200031

Special Issue: 结构陶瓷论文精选(2020)

• RESEARCH LETTERS • Previous Articles Next Articles

Stable Zirconium Carbide Fibers Fabricated by Centrifugal Spinning Technique

CHEN Bowen^1,^2,³(),WANG Jingxiao^1,²,JIANG Youlin^1,^2,³,ZHOU Haijun^1,²,LIAO Chunjing^1,²,ZHANG Xiangyu^1,²,KAN Yanmei^1,²,NI Dewei^1,²(), DONG Shaoming^1,3

1. State Key Laboratory of High Performance Ceramics and Super?ne Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
2. Structural Ceramics and Composites Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
3. University of Chinese Academy of Sciences, Beijing 100049, China

Received:2020-01-13 Published:2020-12-20 Online:2020-06-09
About author:CHEN Bowen(1994–), male, PhD candidate. E-mail: chenbowen@student.sic.ac.cn
Supported by:
The National Key Research and Development Program of China(2016YFB0700202);National Natural Science Foundation of China(51702341);Chinese Academy of Sciences Innovative Funding(CXJJ-17-M169);The Key Deployment Project of Chinese Academy of Sciences(Y71YZ7171G);“CAS Pioneer Hundred Talents Program”

Abstract

Abstract:

In this work, an efficient approach was presented to produce stable zirconium carbide (ZrC) fibers by centrifugal spinning technique. Zirconium acetate and sucrose were used as the zirconium source and carbon source respectively. And polyvinyl pyrrolidone (PVP) was used as the spinning aid. After pyrolysis and carbothermal reduction at 1600 ℃, the as-spun green fibers can be converted to homogeneous ZrC fibers composed of uniform nano-sized ZrC crystals. Moreover, it is revealed that the as-fabricated ZrC fibers can sustain superior microstructure stability at an ultra-high temperature up to 2000 ℃, benefiting from a limited amount of residual carbon. The reaction mechanisms and the resulted ZrC fibers were also investigated.

Key words: zirconium carbide fiber, centrifugal spinning, ultra-high temperature stability

CLC Number:

TQ174

CHEN Bowen, WANG Jingxiao, JIANG Youlin, ZHOU Haijun, LIAO Chunjing, ZHANG Xiangyu, KAN Yanmei, NI Dewei, DONG Shaoming. Stable Zirconium Carbide Fibers Fabricated by Centrifugal Spinning Technique[J]. Journal of Inorganic Materials, 2020, 35(12): 1385-1390.

Figures/Tables 6

References 16

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Stable Zirconium Carbide Fibers Fabricated by Centrifugal Spinning Technique

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