MOF/Poly(Ethylene Oxide) Composite Polymer Electrolyte for Solid-state Lithium Battery

doi:10.15541/jim20200206

Journal of Inorganic Materials ›› 2021, Vol. 36 ›› Issue (3): 332-336.DOI: 10.15541/jim20200206

Special Issue: 能源材料论文精选(2021)；【虚拟专辑】锂离子电池(2020~2021)；【能源环境】金属有机框架材料

• RESEARCH LETTERS • Previous Articles

MOF/Poly(Ethylene Oxide) Composite Polymer Electrolyte for Solid-state Lithium Battery

LIANG Fengqing¹^,²(), WEN Zhaoyin¹^,²()

1. CAS Key Laboratory of Materials for Energy Conversion, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2020-04-20 Revised:2020-05-05 Published:2021-03-20 Online:2020-05-20
Contact: WEN Zhaoyin, professor. E-mail: zywen@mail.sic.ac.cn
About author:LIANG Fengqing(1994-), female, Master candidate. E-mail: liangfengqing@student.sic.ac.cn
Supported by:
National Key R&D Program of China(2018YFB0905400);National Natural Science Foundation of China(51772315);Science and Technology Commission of Shanghai Municipality(18DZ2280800)

Abstract

Abstract:

Solid polymer electrolytes (SPEs) with high flexibility and processability enable the fabrication of leak-free solid-state batteries with varied geometries. However, SPEs usually suffer from low ionic conductivity and poor stability with lithium metal anodes. Here, we propose nano-sized metal-organic framework (MOF) material(UiO-66) as filler for poly(ethylene oxide) (PEO) polymer electrolyte. The coordination of UiO-66 with oxygen in PEO chain and the interaction between UiO-66 and lithium salt significantly improve the ionic conductivity (3.0×10 ^-5 S/cm at 25 ℃, 5.8×10 ^-4 S/cm at 60 ℃) and transference number of Li ⁺ (0.36), widen the electrochemical window to 4.9 V (vs Li ⁺/Li), enhance the stability with lithium metal anode. As a result, the as-prepared Li symmetrical cells can continuously operate for 1000 h at 0.15 mA?cm ^-2, 60 ℃. The results show that UiO-66 filler is effective to improve the electrochemical performance of polymer electrolyte.

Key words: composite electrolyte, poly(ethylene oxide), metal-organic framework material, lithium metal battery

CLC Number:

TQ174

LIANG Fengqing, WEN Zhaoyin. MOF/Poly(Ethylene Oxide) Composite Polymer Electrolyte for Solid-state Lithium Battery[J]. Journal of Inorganic Materials, 2021, 36(3): 332-336.

Figures/Tables 3

References 19

[1]	CROCE F, APPETECCHI G B, PERSI L, et al. Nanocomposite polymer electrolytes for lithium batteries. Nature, 1998,394(6692):456-458. DOI URL
[2]	CLERICUZIO M, PARKER W O, SOPRANI M, et al. Ionic diffusivity and conductivity of plasticized polymer electrolytes: PMFG-NMR and complex impedance studies. Solid State Ionics, 1995,82(3/4):179-192.
[3]	GORECKI W, ANDREANI C, BERTHIER C. NMR, DSC, conductivity study of a poly(ethylene oxide) complex electrolyte: PEO(LiClO₄)_x. Solid State Ionics, 1986,18(19):295-299.
[4]	PUTHIRATH A B, PATRA S, PAL S, et al. Transparent flexible lithium ion conducting solid polymer electrolyte. Journal of Materials Chemistry A, 2017,5(22):11152-11162.
[5]	ZHANG D, ZHANG L, YANG K, et al. Superior blends solid polymer electrolyte with integrated hierarchical architectures for all-solid-state lithium-ion batteries. ACS Appl. Mater. Inter., 2017,9(42):36886-36896. DOI URL
[6]	ZHANG J, ZANG X, WEN H, et al. High-voltage and free-standing poly(propylene carbonate)/Li_6.75La₃Zr_1.75Ta_0.25O₁₂ composite solid electrolyte for wide temperature range and flexible solid lithium ion battery. Journal of Materials Chemistry A, 2017,5(10):4940-4948.
[7]	XU D, SU J, JIN J, et al. In situ generated fireproof gel polymer electrolyte with Li_6.4Ga_0.2La₃Zr₂O₁₂ as initiator and ion-conductive filler. Advanced Energy Materials, 2019,9(25):1-12.
[8]	LI W W, ZHANG S P, WANG B R, et al. Nanoporous adsorption effect on alteration of the Li⁺ diffusion pathway by a highly ordered porous electrolyte additive for high-rate all-solid-state lithium metal batteries. ACS Appl. Mater. Inter., 2018,10(28):23874-23882. DOI URL
[9]	LIU Y, LEE J Y, HONG L. In situ preparation of poly(ethylene oxide)-SiO₂ composite polymer electrolytes. Journal of Power Sources, 2004,129(2):303-311.
[10]	ZHU P, YAN C, DIRICAN M, et al. Li_0.33La_0.557TiO₃ ceramic nanofiber-enhanced polyethylene oxide-based composite polymer electrolytes for all-solid-state lithium batteries. Journal of Materials Chemistry A, 2018,6(10):4279-4285. DOI URL
[11]	ZHAO C Z, ZHANG X Q, CHENG X B, et al. An anion- immobilized composite electrolyte for dendrite-free lithium metal anodes. Proc. Natl. Acad. Sci. USA, 2017,114(42):11069-11074. DOI URL PMID
[12]	LIU M, CHENG Z, GANAPATHY S, et al. Tandem interface and bulk Li-ion transport in a hybrid solid electrolyte with microsized active filler. ACS Energy Letters, 2019,4(9):2336-2342.
[13]	KUMAR B, SCANLON L G. Composite electrolytes for lithium rechargeable batteries. Journal of Electroceramics, 2000,5(2):127-139. DOI URL
[14]	LI W W, SUN C, JIN J, et al. Realization of the Li⁺ domain diffusion effect via constructing molecular brushes on the LLZTO surface and its application in all-solid-state lithium batteries. Journal of Materials Chemistry A, 2019,7(48):27304-27312.
[15]	HUANG Z Y, PANG W Y, LIANG P, et al. A dopamine modified Li_6.4La₃Zr_1.4Ta_0.6O₁₂-PEO solid-state electrolyte enhanced thermal and electrochemical properties. Journal of Materials Chemistry A, 2019,7:16425-16436.
[16]	YUAN C, LI J, HAN P, et al. Enhanced electrochemical performance of poly(ethylene oxide) based composite polymer electrolyte by incorporation of nano-sized metal-organic framework. Journal of Power Sources, 2013,240:653-658.
[17]	ZHOU L, ZHANG X H, CHEN Y L. Modulated synthesis of zirconium metal-organic framework UiO-66 with enhanced dichloromethane adsorption capacity. Materials Letters, 2017,197:167-170.
[18]	KINIK F P, UZUN A, KESKIN S. Ionic liquid/metal-organic framework composites: from synthesis to applications. ChemSusChem, 2017,10(14):2842-2863. DOI URL PMID
[19]	HUO H, WU B, ZHANG T, et al. Anion-immobilized polymer electrolyte achieved by cationic metal-organic framework filler for dendrite-free solid-state batteries. Energy Storage Materials, 2019,18:59-67.

MOF/Poly(Ethylene Oxide) Composite Polymer Electrolyte for Solid-state Lithium Battery

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 3

References 19

Related Articles 7

Recommended Articles

Metrics

Comments

[1]	CHEN Xinli, LI Yan, WANG Weisheng, SHI Zhiwen, ZHU Liqiang. Gelatin/Carboxylated Chitosan Gated Oxide Neuromorphic Transistor [J]. Journal of Inorganic Materials, 2023, 38(4): 421-428.
[2]	LI Rui,WANG Hao,FU Qiang,TIAN Ziyu,WANG Jianxu,MA Xiaojian,YANG Jian,QIAN Yitai. Stable Li-metal Depositon on Lithiophilic 3D CuO Nanosheet-decorated Cu Mesh [J]. Journal of Inorganic Materials, 2020, 35(8): 882-888.
[3]	YAN Yiyuan, JU Jiangwei, YU Meiyan, CHEN Shougang, CUI Guanglei. In-situ Polymerization Integrating 3D Ceramic Framework in All Solid-state Lithium Battery [J]. Journal of Inorganic Materials, 2020, 35(12): 1357-1364.
[4]	LI Dong, LEI Chao, LAI Hua, LIU Xiao-Lin, YAO Wen-Li, LIANG Tong-Xiang, ZHONG Sheng-Wen. Recent Advancements in Interface between Cathode and Garnet Solid Electrolyte for All Solid State Li-ion Batteries [J]. Journal of Inorganic Materials, 2019, 34(7): 694-702.
[5]	LI Cheng-Bin, YUE Hong-Yun, WANG Qiu-Xian, LI Jing-Xian, YANG Shu-Ting. Preparation and Property of a Novel Heat-resistant Ceramic Composite Solid-state Electrolyte for Lithium Batteries [J]. Journal of Inorganic Materials, 2017, 32(8): 801-805.
[6]	HUANG Le-Zhi, WEN Zhao-Yin, JIN Jun, LIU Yu. Preparation and Characterization of PEO-LATP/LAGP Ceramic Composite Electrolyte Membrane for Lithium Batteries [J]. Journal of Inorganic Materials, 2012, 27(3): 249-252.
[7]	TAO Shan-Wen,PENG Ding-Kun,MENG Guang-Yao. Conduction Mechanism of Inorganic-Salt-Oxide Composite Electrolytes [J]. Journal of Inorganic Materials, 1999, 14(2): 203-210.