Degradation of Dye Wastewater over NH2-UiO-66: Piezoelectrically Induced Mechano-Catalytic Effect

doi:10.15541/jim20190542

Abstract

Abstract:

Metal-organic frameworks (MOF) as piezoelectrical materials used in mechano-catalytic degradation of organic dye are rarely investigated. In this work, NH₂-UiO-66 was synthesized by the solvothermal method and applied in mechano-catalytic degradation of Rhodamine B under ultrasonic vibration. The results show that NH₂- UiO-66 behaves a high mechano-catalytic decomposition efficiency of 80% for Rhodamine B within 5 h vibration and possesses a good stability. The piezoelectrically induced electric charges on the surfaces of NH₂-UiO-66 via the piezoelectric effect could induce hydroxyl radicals as strong oxidants to decompose Rhodamine B. The piezoelectrical effect of MOFs is potential in utilizing vibration energy for dye wastewater treatment.

Key words: metal-organic frameworks, NH₂-UiO-66, piezoelectrical materials, mechano-catalysis, dye degradation

CLC Number:

TQ174

ZHANG Xincong,GUO Ke,PENG Lianlian,WU Jieyu,ZHANG Fumin,ZHU Weidong,FU Yanghe. Degradation of Dye Wastewater over NH₂-UiO-66: Piezoelectrically Induced Mechano-Catalytic Effect[J]. Journal of Inorganic Materials, 2020, 35(9): 1023-1028.

Figures/Tables 7

Fig. 1 Characterizations of NH2-UiO-66 (a) XRD patterns; (b) FT-IR spectra; (c) SEM image; (d) N2 adsorption-desorption isotherm; (e) Ferroelectric hysteresis loop

Fig. 2 Equilibrium curve for the adsorption of RhB over NH2- UiO-66

Fig. 3 Degradation results of RhB solution over NH2-UiO-66 under ultrasound with different frequencies

Fig. 4 UV-Vis DRS of NH2-UiO-66 with different ultrasonic vibration time

Fig. 5 Degradation results of RhB solution under different conditions (a) NH2-UiO-66 without vibration; (b) Vibration without catalyst; (c) Vibration+NH2-UiO-66+EDTA; (d) Vibration+NH2-UiO-66+BQ; (e) Vibration+NH2-UiO-66+IPA; (f) Vibration+NH2-UiO-66

Fig. 6 Schematic diagram for the mechano-catalytic degradation of RhB over NH2-UiO-66

Fig. 7 Reusability of NH2-UiO-66 in the mechano-catalytic degradation of RhB

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Degradation of Dye Wastewater over NH₂-UiO-66: Piezoelectrically Induced Mechano-Catalytic Effect

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