Bi2Mn4O10: Preparation by Polyacrylamide Gel Method and Electrochemical Performance

doi:10.15541/jim20190488

Abstract

Abstract:

Due to competitive theoretical capacity, Bi₂Mn₄O₁₀ has been deemed as an efficient Li-ion battery anode material. Bi₂Mn₄O₁₀ powder was prepared by polyacrylamide gel method using bismuth nitrate and manganese acetate as raw materials. The effects of preparation conditions on the phase, morphology and electrochemical cycling performance of powder were investigated. Results showed that the spheroid Bi₂Mn₄O₁₀ powder with narrow size distribution was successfully prepared under the conditions of molar ratio of acrylamide to total metal ions of 8 : 1, the glucose concentrations of 1.11 mol/L and heat treatment temperature of 873 K. Lithium ion batteries with as-prepared Bi₂Mn₄O₁₀ as anode material, acquired excellent cycle and rate performances. Its discharge specific capacity is 496.8 mAh/g at 0.2C (1C=800 mA/g) rate after 50 cycles, corresponding to a high capacity of 76.9%. Even at 3C rate, a superior rate capacity of 232 mAh/g is retained.

Key words: lithium ion battery, anode material, Bi₂Mn₄O₁₀, electrochemical performance

CLC Number:

TM912

ZHAN Jing,XU Changfan,LONG Yiyu,LI Qihou. Bi₂Mn₄O₁₀: Preparation by Polyacrylamide Gel Method and Electrochemical Performance[J]. Journal of Inorganic Materials, 2020, 35(7): 827-833.

Figures/Tables 6

Fig. 1 SEM images ((a) 2 : 1, (b) 4 : 1, (c) 6 : 1, (d)8 : 1), (e) XRD patterns and (f) cycling performance at 0.2C of the products obtained with different molar ratios of acrylamide to total metal ions, and Coulombic efficiency of the product with molar ratio of acrylamide to total metal ions of 8 : 1 (after 3 cycles at 0.1C, 1C=800 mA/g) Glucose concentrations: 1.11 mol/L, heat treatment temperature: 873 K, weight ratio of acrylamide to N,N’-methylene bisacrylamide: 5 : 1

Fig. 2 SEM images ((a) 0.28 mol/L, (b) 0.56 mol/L, (c) 0.83 mol/L, (d) 1.11 mol/L), (e) XRD patterns and (f) cycling performance at 0.2C of the products obtained with different glucose concentrations, and Coulombic efficiency of the product with 1.11 mol/L glucose (after three cycles at 0.1C, 1C=800 mA/g) Molar ratio of acrylamide to total metal ions: 8 : 1; heat treatment temperature: 873 K; weight ratio of acrylamide to N,N’-methylene bisacrylamide of 5 : 1

Fig. 3 SEM images ((a) 873 K, (b) 923 K, (c) 973 K), (d) XRD patterns and (e) cycling performance at 0.2C of the products obtained with different heat treatment temperatures, and Coulombic efficiency of the product with heat-treatment temperature of 873 K (after three cycles at 0.1C, 1C=800 mA/g) Molar ratio of acrylamide to total metal ions: 8 : 1, glucose concentrations of 1.11 mol/L, weight ratio of acrylamide to N,N’-methylene bisacrylamide: 5 : 1

Fig. 4 (a) TEM and (b) HRTEM images of Bi2Mn4O10 obtained at optimized conditions

Fig. 5 (a) Particle size distribution and (b) N2 adsorption and desorption curves of Bi2Mn4O10 obtained at optimized conditions with inset in (b) showing the pore size distribution curve

Fig. 6 (a) CV curves, (b) voltage-specific capacity curves at 0.1C and (c) rate performance curve of Bi2Mn4O10 obtained at optimized conditions

References 29

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Bi₂Mn₄O₁₀: Preparation by Polyacrylamide Gel Method and Electrochemical Performance

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