Journal of Inorganic Materials ›› 2019, Vol. 34 ›› Issue (7): 685-693.DOI: 10.15541/jim20180515
Special Issue: 药物载体与防护材料
• REVIEW • Next Articles
LI Hao-Geng1,2,GU Hong-Yu1,ZHANG Yu-Zhi1,2(),SONG Li-Xin1,2(
),WU Ling-Nan1,QI Zhen-Yi1,ZHANG Tao1
Received:
2018-10-29
Revised:
2018-11-29
Published:
2019-07-20
Online:
2019-06-26
Supported by:
CLC Number:
LI Hao-Geng,GU Hong-Yu,ZHANG Yu-Zhi,SONG Li-Xin,WU Ling-Nan,QI Zhen-Yi,ZHANG Tao. Surface Protection of Polymer Materials from Atomic Oxygen: a Review[J]. Journal of Inorganic Materials, 2019, 34(7): 685-693.
Fig. 2 PI surface modification to form polyamic acid: NaOH hydrolysis of PI (Step 1) to form sodium salt of polyamic acid followed by acidification (Step 2) to form polyamic acid[50]
Fig. 3 SEM images of AO exposed (effective fluence ~2.0×1020atoms/cm2) samples: untreated samples[52,53] (a) masked section and (b) exposed section, images of ImplantoxTM treatment being (c) masked and (d) exposed sections, and AO exposed (e) Implantox-treated section and (f) untreated sections
Sample | F/(×1020 O atom?cm-2) | ΔM/mg | A/cm2 | (ΔM/A)/(mg?cm-2) | E/(×10-24, cm3atom-1) |
---|---|---|---|---|---|
Kapton | 3.09 | 5.03 | 3.14 | 1.60 | 3.65 |
SiOx coated PI | 3.09 | 0.17 | 3.14 | 0.05 | 0.12 |
Table 1 Erosion yield of atomic oxygen on PI samples[56]
Sample | F/(×1020 O atom?cm-2) | ΔM/mg | A/cm2 | (ΔM/A)/(mg?cm-2) | E/(×10-24, cm3atom-1) |
---|---|---|---|---|---|
Kapton | 3.09 | 5.03 | 3.14 | 1.60 | 3.65 |
SiOx coated PI | 3.09 | 0.17 | 3.14 | 0.05 | 0.12 |
Fig. 5 Initial (left, t=0) and final (right, t=35 ps) simulation snapshots of different PI protection system under AO impact[71]:PI-grafted (a) 15wt% POSS and (b) 30wt% POSS; 15wt% graphene (c) randomly oriented and (d) aligned
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