Journal of Inorganic Materials ›› 2019, Vol. 34 ›› Issue (6): 633-640.DOI: 10.15541/jim20180372

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A New Polyethylene Composite Material Based on Nano Silver Particels Loaded Graphene Oxide

Feng ZHANG1,2,Kai-Li ZHANG1,Ming-Ming ZHOU2,Chao CHEN3,Zhi-Wei CAI3,Guo-Hui WEI4,Xing-Mao JIANG4,5,Cheng ZHANG1,RUHLMANN Laurent6,Yao-Kang LÜ1()   

  1. 1. School of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
    2. The Children's Hospital, Zhejiang University School of Medicine, Hangzhou 310052, China
    3. Zhejiang Institute for Food and Drug Control, Hangzhou, 310052, China
    4. Changzhou Yingzhong Nano Technology Co., Ltd, Changzhou 213000, China
    5. School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology, Wuhan 430205, China;
    6. Institut de Chimie, Université de Strasbourg, Strasbourg 67081, France;
  • Received:2018-08-09 Revised:2018-09-04 Published:2019-06-20 Online:2019-05-23
  • Supported by:
    National Natural Science Foundation of China(21501148);Open Funding from Zhejiang Provincial Key Laboratory for Quality Control of Drug Contact Materials;Zhejiang Provincial Natural Science Foundation(LY19B01000)

Abstract:

A new nano silver particels loaded graphene oxide (AgNPs@GO) was obtained through ultrasonic assisted liquid phase method. In AgNPs@GO, nano silver particels (AgNPs) are mainly anchored at oxygen containing groups and defects of graphene oxide (GO) sheets, part of GO sheets are reduced and some Ag(0) atoms have been oxidized to Ag + ions. AgNPs@GO exhibits significantly stronger ability for inhibiting Pseudomonas aeruginosa than that of AgNPs and GO. Therefore, AgNPs@GO was further introduced to polyethylene (PE) matrix as an additive to prepare a new composite material 0.48wt%-AgNPs@GO/PE. Compare with bare PE and AgNPs doped PE composites, 0.48wt%-AgNPs@GO/PE not only has a better antibacterial ability and stronger water vapor barrier property, but also dissolves out less nonvolatile substance than PE in water and ethanol solution.

Key words: nano silver particels, graphene oxide, pseudomonas aeruginosa, polyethylene, antibacterial ability, water vapor barrier property

CLC Number: