Structure and Property of Bi5Ti3FeO15 Film

doi:10.15541/jim20160630

Abstract

Abstract:

Bi₅Ti₃FeO₁₅(BTFO15) thin films were grown on Pt/Ti/SiO₂/Si substrate by pulsed laser deposition (PLD) method. The structure, magnetic properties, ferroelectric properties, and ferroelectric domains were studied by using X ray diffraction, scanning electron microscopy and scanning TEM high-angle annular dark-field (HAADF STEM). Results showed that the BTFO15 film had high crystallization with perfect layered lattice structure. It stacked like a sandwich which three Bi layers and Ti(Fe)O₆ octahedra were sandwiched by two closely stacked Bi layers. In addtion, room-temperature magnetic hystersis loop and ferroelectric hysteresis loop confirmed that the BTFO15 film had weak ferromagnetism and ferroelectricity. The piezo response force microscope was used to study the domain and domain switching, the in-plane and out-of-plane PFM images were obtained by applying the voltage of ±3 V and ±10 V. These results are important to understand the relationship between microstructure and property of multiferroic materials.

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Key words: Bi₅Ti₃FeO₁₅ film, multiferroic, ferroelectric domain

CLC Number:

TQ174

HUANG Zhi-Deng, ZHAO Hong-Yang, MA Zhi-Bin, FU Qiu-Ming, TAO Hong, FAN Zi-Ran. Structure and Property of Bi₅Ti₃FeO₁₅ Film[J]. Journal of Inorganic Materials, 2017, 32(10): 1018-1022.

Figures/Tables 7

Fig. 1 XRD pattern of BTFO15 film

Fig. 2 SEM image of BTFO15 film

Fig. 3 HAADF STEM image of a BTFO15 film

Fig. 4 Magnetic hysteresis loops of BTFO15 film measured at different temperaturesInset is the enlarge figure of the magnetic hysteresis loops of BTFO15 film measured at 300 K

Fig. 5 PFM images of BTFO15 film(a) Topography; (b) +3 V in-plane polarization; (c) -3 V in-plane polarization; (d) Topography; (e) +10V out-of-plane polarization; (f) -10 V out-of-plane polarization

Fig. 6 Ferroelectric hysteresis loops of BTFO15 film measured at room temperature and 60 Hz

Fig. 7 Curves of the dielectric constant and dielectric loss versus frequency for BTFO15 film

References 17

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Structure and Property of Bi₅Ti₃FeO₁₅ Film

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