Journal of Inorganic Materials ›› 2017, Vol. 32 ›› Issue (9): 936-942.DOI: 10.15541/jim20160623
• Orginal Article • Previous Articles Next Articles
LI Gui-Fang, YANG Qian, WEI Yun-Ge
Received:
2016-11-15
Revised:
2017-02-10
Published:
2017-09-30
Online:
2017-08-29
CLC Number:
LI Gui-Fang, YANG Qian, WEI Yun-Ge. Synthesis and Photoluminescence Properties of Double Perovskite NaLaMgWO6: Eu3+ Red Phosphor[J]. Journal of Inorganic Materials, 2017, 32(9): 936-942.
Fig. 6 Emission spectra of NaLa0.5Eu0.5MgWO6 phosphors at different excitation wavelength Inset shows schematic energy-level diagram Eu3+ ions in NaLaMgWO6
Transition | Wavelength/nm-1 | Transition rate/s-1 | β/% |
---|---|---|---|
5D0→7F0 | 17241.38 | 27.468 | 1.33 |
5D0→7F1 | 16891.89 | 220.392 | 10.70 |
5D0→7F2 | 16207.45 | 1795.735 | 87.18 |
5D0→7F3 | 15313.93 | 7.645 | 0.37 |
5D0→7F4 | 14388.49 | 8.523 | 0.42 |
Table 1 Radiative transition rates and branch ratios for5D0→7FJ of NaLaMgWO6 phosphors
Transition | Wavelength/nm-1 | Transition rate/s-1 | β/% |
---|---|---|---|
5D0→7F0 | 17241.38 | 27.468 | 1.33 |
5D0→7F1 | 16891.89 | 220.392 | 10.70 |
5D0→7F2 | 16207.45 | 1795.735 | 87.18 |
5D0→7F3 | 15313.93 | 7.645 | 0.37 |
5D0→7F4 | 14388.49 | 8.523 | 0.42 |
Host | Source | Ω2/ (10-20, cm2) | Ω4/ (10-20, cm2) | τ /ms |
---|---|---|---|---|
BaWO4: Eu3+, Sm3+ | [25] | 8.650 | 3.67 | 0.55 |
NaY(WO4)2: Eu3+ | [26] | 8.610 | 1.12 | 1.03 |
Ba5Gd8Zn4O21 | [27] | 12.700 | 4.50 | 0.75 |
NaLaMgWO6: Eu3+ | Present work | 8.735 | 0.82 | 0.45 |
Table 2 J-O parameters of NaLaMgWO6: Eu3+ phosphors
Host | Source | Ω2/ (10-20, cm2) | Ω4/ (10-20, cm2) | τ /ms |
---|---|---|---|---|
BaWO4: Eu3+, Sm3+ | [25] | 8.650 | 3.67 | 0.55 |
NaY(WO4)2: Eu3+ | [26] | 8.610 | 1.12 | 1.03 |
Ba5Gd8Zn4O21 | [27] | 12.700 | 4.50 | 0.75 |
NaLaMgWO6: Eu3+ | Present work | 8.735 | 0.82 | 0.45 |
[1] | LI GOU-GANG, TIAN YING, ZHAO YUN,et al.Recent progress in luminescence tuning of Ce3+ and Eu2+ activated phosphors for pc-WLED. Chem. Soc. Rev., 2015, 44(23): 8688-8713. |
[2] | ZENG QI-HUA, ZHANG XIN-GUO, HE PEI,et al. Research on rare-earth tungstates red phosphors for white-light emitting diode. Journal of Inorganic Materials, 2010, 25(10): 1009-1014. |
[3] | SHANG MENG-MENG, LI CHUN-XIA, LIN JUN.How to produce white light in a single-phase host.Chem. Soc. Rev., 2014, 45(18): 1372-1386. |
[4] | CHIEN TZU-CHIN, HWANG CHII-SHYANG, YOSHIMURA MASAHIRO,et al.Synthesis and photoluminescence properties of fluorite-related (Y1-xEux)10W2O21 phospho. Ceram. Int., 2015, 41(1): 155-161. |
[5] | SUN WEN-ZHI, PANG RAN, LI HAI-FENG,et al. Synthesis and photoluminescence properties of novel red-emitting Ca14Mg2 ( SiO4)8: Eu3+/ Sm3+ phosphors. J. Rare Earth, 2015, 33(8): 814-819. |
[6] | WANG PING, YANG DING-MING, HE XIAO-LIN,et al.Synthesis and luminescence properties of red-emitting phosphor Na2ZnSiO4: Eu3+ under blue light excitatio. Journal of the Chinese Ceramic Society, 2015, 43(1): 93-97. |
[7] | ZHANG FENG, ZHANG WEI-FENG, ZHANG ZHI-YA,et al.Luminescent characteristics and energy transfer of a red-emitting YVO4: Sm3+, Eu3+ phosphor. J. Lumin. , 2014, 152(2): 160-164. |
[8] | DENG CHAO, LIN LI-TIAN, TANG LI,et al.Synthesis and luminescence of ScVO4: Eu3+, Bi3+, A13+ phosphor. Chinese Journal of Luminescence, 2015, 36(11): 1246-1250. |
[9] | YAN MI-FANG, XUE LI-HONG, YAN YOU-WEI.Preparation and luminescence properties of Ml.95P2O7: 0.05Eu3+(M=Ba, Sr, Ca) red emitting phosphor.Journal of the Chinese Ceramic Society, 2013, 41(3): 342-346. |
[10] | WANG TAO, HU YI-HUA, LI CHEN,et al.Luminescence properties and energy transfer of a red-emitting Ca3 ( PO4)2: Sm3+, Eu3+ phospho. J. Mater. Sci: Mater Electron., 2015, 26(7): 5360-5367. |
[11] | GUO CHONG-FENG, YANG HYUN-KYOUNG, JEONG JUNG-HYUN.Preparation and luminescent properties of phosphor MGd2(MoO4)4: Eu3+ (M=Ca, Sr and Ba. J. Lumin., 2010, 130(8): 1390-1393. |
[12] | JIN YE, ZHENG JIN-JU.Photoluminescence studies of red-emitting Y5Mo2O12: Eu3+, Sm3+ as a near-UV convertible phospho.Mater. Lett. 2014, 114: 4-6. |
[13] | LI GUI-FANG, GAO SHUO, HE WEN-WEN.Preparation and photoluminescence properties of the Sm3+, Eu3+ co-doped CaWO4 phosphors. Optik-International Journal for Light and Electron Optics, 2015, 126(21): 3272-3275. |
[14] | HOU JING-SHAN, YIN XIN, HUANG FU-QIANG,et al. Synthesis and photoluminescence properties of NaLaMgWO6: RE3+ (RE =Eu, Sm, Tb) phosphor for white LED applicatio. Mater. Res. Bull., 2012, 47(6): 1295-1300. |
[15] | SHANNON R D.Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenide.Acta Cryst., 1976, A32(5): 751-767. |
[16] | ZHANG LE, LIU QUAN, DING NAN,et al.Dual-channel enhanced luminescence of double perovskite NaGdMgWO6: Eu3+ phosphor based on alternative excitation and delayed quenchin. J. Alloys Compd., 2015, 642: 45-52. |
[17] | ZHANG LE, ZHOU LU, PENG HAN,et al.Synthesis and photoluminescence of Eu3+-activated double perovskite NaGdMg(W, Mo)O6- a potential red phosphors for solid state lightin. J. Mater. Chem. C, 2012, 1(1): 54-57. |
[18] | LONG SHENG, HOU JING-SHAN, ZHANG GANG-HUA,et al.High quantum efficiency red-emission tungstate based phosphor Sr(La1-xEux)2Mg2W2O12 for WLEDs applicatio. Ceram. Int., 2013, 39(5): 6013-6017. |
[19] | MAO JIN-WEI, LU SHU-CHEN, QU XIU-RONG, et al. Preparation Preparation and luminescent properties of Sr0.8-xBaxEu0.2WO4 red phosphors for white LED. Acta Phys.Sin , 2013, 62(3): 037803-1-7 . |
[20] | LI LIN-LIN, LIU LU, ZI WEN-WEN,et al. Synthesis and luminescent properties of high brightness MLa(WO4)2: Eu3+ ( M=Li, Na, K) and NaRE(WO4)2: Eu3+ , 2013, 143(6): 14-20. |
[21] | ZHU HE-KAI, FANG MING-HAO, HUANG ZHAO-HUI,et al.Photoluminescence properties of Li2Mg2( WO4)3: Eu3+ red phosphors with high color purity for white LEDs application. J. Lumin., 2015, 172: 180-184. |
[22] | HUANG SHI-HUA, LOU LI-REN.Concentration dependence of sensitizer fluorescence intensity in energy transfe.Chinese Journal of Luminescence, 1990, 11(1): 1-7. |
[23] | TIAN YUE, CHEN BAO-JIU, TIAN BI-NING,et al.Concentration dependent luminescence and energy transfer of flower-like Y2 ( MoO4)3: Dy3+ phosphor. J. Alloys Compd., 2011, 509(20): 6096-6101. |
[24] | TIAN YUE, CHEN BAO-JIU, HUA RUI-NIAN, et al. Optical transition . Optical transition, electron-phonon coupling and fluorescent quenching of La2 (MoO4)3: Eu3+ phosphors. J. Appl. Phys., 2011, 109(5): 053511-1- . |
[25] | BOUZIDI C, FERHI M, ELHOUICHET H,et al.Spectroscopic properties of rare-earth (Eu3+, Sm3+) doped BaWO4 powde. J. Lumin., 2015, 161: 448-455. |
[26] | TIAN YUE, CHEN BAO-JIU, HUA RUI-NIAN,et al.Self-assembled 3D flower-shaped NaY(WO4)2: Eu3+ microarchitectures: Microwave-assisted hydrothermal synthesis, growth mechanism and luminescent propertie. CrystEngComm., 2012, 12: 1760-1769. |
[27] | TIAN BI-NING, CHEN BAO-JIU, TIAN YUE, et al. Excitation pathway and temperature dependent luminescence in color tunable Ba5Gd8Zn4O21: Eu3+ phosphors.J. Mater. Chem. C, 2013, 1: 2338-2344. |
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