Preparation and Photocatalytic Properties of Mesoporous RGO/TiO2 Composites

doi:10.15541/jim20160349

Abstract

Abstract:

A series of mesoporous graphene oxide/TiO₂ composites (GO/TiO₂) with different mass fractions of graphene oxide (GO) were synthesized by an in-situ synthesized Sol-Gel step using GO, tetrabutyl titanate (TBT) as precursors, polyvinylpyrrolidone (PVP) as frame developing agent and citric acid as hydrolysis inhibitor and surfactant. Afterwards, mesoporous reduced graphene oxide/TiO₂ (RGO/TiO₂) composites were obtained by ultraviolet radiation reduction method. The composites were characterized by X-ray diffraction (XRD), Transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), UV-visible diffuse reflectance spectroscope (UV-Vis DRS), and photoluminescence (PL) spectroscopy technology. The morphology and pore size distribution of RGO/TiO₂ and the effects of RGO on the lifetime of photogenerated electron-hole pairs, adsorption capacity and photocatalytic activity of composite photocatalysts were investigated. The photocatalytic activity was evaluated under ultraviolet light and sunlight irradiation. Then the recovery test was studied under ultraviolet light irradiation. Results show that TiO₂ nanoparticles are well dispersed on the surface of the RGO sheets and RGO/TiO₂composites are mesoporous materials. The introduction of RGO effectively inhibits the recombination of photogenerated electron-hole pairs and improves the adsorption capacity and photocatalytic activity of composites. The 7wt% RGO/TiO₂shows the best adsorption capacity for methyl orange. And 5wt% RGO/TiO₂shows the best and stable photocatalytic activity, after four recovery test, its photocatalytic degradation of methyl orange under ultraviolet light irradiation for 50 min exceeded 90% of the first test.

Key words: reduced graphene oxide, titanium dioxide, mesoporous, ultraviolet light, sunlight

CLC Number:

TB34

LI Cui-Xia, JIN Hai-Ze, YANG Zhi-Zhong, YANG Xuan, DONG Qi-Zheng, LI Ting-Ting. Preparation and Photocatalytic Properties of Mesoporous RGO/TiO₂ Composites[J]. Journal of Inorganic Materials, 2017, 32(4): 357-364.

Figures/Tables 9

Fig. 1 XRD patterns of 5wt% RGO/TiO2 (a) 5wt% GO/TiO2 (b) and TiO2 (c)

Fig. 2 Mechanism of ultraviolet radiation reduction of GO

Fig. 3 TEM (a) and SAEDP(b) images of 5wt% RGO/TiO2

Fig. 4 N2 adsorption-desorption isotherms (a) and BJH pore size distribution plot (b) of 5wt%RGO/TiO2

Fig. 5 UV-visible diffuse reflectance spectra of TiO2 and 5wt%RGO/TiO2

Fig. 6 Photoluminescence spectra of RGO/TiO2 composites with different contents of RGO

Fig. 7 Adsorption activity of RGO/TiO2 composites with different contents of RGO

Fig. 8 Degradation rate of photocatalyst under different light irradiation(a) Ultraviolet light; (b) Sunlight

Fig. 9 Recovery test of 5wt% RGO/TiO2

References 33

[1]	ZHANG G X, DONG X B,ZHENG S L.Photocatalytic performance of nano-TiO2/diatomite composite. Journal of Inorganic Materials, 2016, 31(4): 407-412.
[2]	LIU Y L,ZHENG Y Y,SHANG P B.Preparation, characterization and photocatalytic property of Eu-doped TiO2 hollow microspheres. Journal of Inorganic Materials, 2015, 30(7): 699-705.
[3]	O'REGAN B, GRÄTZEL M.A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353(6346): 737-740.
[4]	Al-HARBI L M, KOSA S A, ABD EI MAKSOD H I, et al. The photocatalytic activity of TiO2-zeolite composite for degradation of dye using synthetic UV and Jeddah sunlight. Journal of Nanomaterials, 2015, 2015: 1-6.
[5]	YAO Y J, QIN J C, CHEN H, et al.One-pot approach for synthesis of N-doped TiO2/ZnFe2O4 hybrid as an efficient photocatalyst for degradation of aqueous organic pollutants.Journal of Hazardous Materials, 2015, 291C: 28-37.
[6]	HASSAN M, CHEN J, LIU G L, et al.Enhanced photocatalytic degradation of methyl orange dye under the daylight irradiation over CN-TiO2 modified with OMS-2. Materials, 2014, 7(12): 8024-8036.
[7]	ARAMENDIA M A, MARINAS A, MARINAS J M, et al.Photocatalytic degradation of herbicide fluroxypyr in aqueous suspension of TiO2. Catalysis Today, 2005, 101(101): 187-193.
[8]	CHATTERJEE D, DASGUPTA S.Visible light induced photocatalytic degradation of organic pollutants. Journal of Photochemistry & Photobiology C Photochemistry Reviews, 2005, 6(2/3): 186-205.
[9]	MATTHEWS R W, MCEVOY R S, OLLIIS D F.Photocatalytic degradation of phenol in the presence of near-UV illuminated titanium dioxide. Journal of Photochemistry & Photobiology A Chemistry, 1992, 64: 231-246.
[10]	CHEN F, ZHAO J C, HIDAKA H.Adsorption factor and photocatalytic degradation of dye-constitutent aromatics on the surface of TiO2 in the presence of phosphate anions. Research on Chemical Intermediates, 2003, 29(7/9): 733-748.
[11]	PANT H R, PANT B, POKHAREL P, et al.Photocatalytic TiO2- RGO/nylon-6 spider-wave-like nano-nets via electrospinning and hydrothermal treatment. Journal of Membrane Science, 2013, 429(4): 225-234.
[12]	ZHANG N, ZHANG Y H, PAN X Y, et a1. Constructing ternary CdS-graphene-TiO2 hybrids on the flatland of graphene oxidewith enhanced visible-light photoactivity for selective transformation. Journal of Physical Chemistry C, 2012, 116: 1802.
[13]	NAINANI R K, THAKUR P.Facile synthesis of TiO2-RGO composite with enhanced performance for the photocatalytic mineralization of organic pollutants. Water Science & Technology, 2016.
[14]	HUMMERS W S, OFFEMAN R E.Preparation of graphitic oxide. Journal of the American Chemical Society, 1958, 80(6): 1339.
[15]	STANKOVICH S, DINKIN D A, PINER R D, et al.Synthesis of grapheme-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon, 2007, 45(7): 1558-1565.
[16]	ZHU Y W, MURALI S, STOLLER M D, et al.Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors. Carbon, 2010, 48(7): 2118-2122.
[17]	ZHU Y W, STOLLER M D, CAI W W, et al.Exfoliation of graphite oxide in propylene carbonate and thermal reduction of the resulting graphene oxide platelets. Acs Nano, 2010, 4(2): 1227-1233.
[18]	AKHAVAN O, ABDOLAHAD M, ESFANDIAR A, et al.Photodegradation of graphene oxide sheets by TiO2 nanoparticles after a photocatalytic reduction. Journal of Physical Chemistry C, 2010, 114(30): 12955-12959.
[19]	WANG H L, LIU X H.Preparation of silver nanoparticle loaded mesoporous TiO2 and its photocatalytic property. Journal of Inorganic Materials, 2016, 31(5): 555-560.
[20]	ANTONELLI D M, YING J Y.Synthesis of hexagonally packed mesoporous TiO2 by a modified Sol-Gel method. Angewandte Chemie International Edition, 1995, 34(18): 2014-2017.
[21]	DU J, LAI X Y, YANG N L, et al.Hierarchically ordered macro-mesoporous TiO2-graphene composite films: improved mass transfer, reduced charge recombination, and their enhanced photocatalytic activities. ACS Nano, 2011, 5(1): 590-596.
[22]	ALVARO M, APRILE C,BENITEZ M, et al.Photocatalytic activity of structured mesoporous TiO2 materials. Journal of Physical Chemistry B, 2006, 110(13): 6661-6665.
[23]	LI S P, WU Q S, CUI C, et al.Preparation of TiO2/Al-MCM-41 mesoporous materials from coal-series kaolin and photodegradation of methyl orange. Materials Science-Poland, 2013, 31(3): 372-377.
[24]	SHEN Y, WANG W X, XIAO J.Synthesis of three-dimensional carbon felt supported TiO2 monoliths for photocatalytic degradation of methyl orange. Journal of Environmental Chemical Engineering, 2016, 4(1): 1259-1266.
[25]	CORNISH B J P A, LAWTON L A, ROBERTSON P K J. Hydrogen peroxide enhanced photocatalytic oxidation of microcystin-LR using titanium dioxide. Applied Catalysis B Environmental, 2000, 25(1): 59-67.
[26]	STORCK S, BRETINGER H, MAIER W F.Characterization of micro-and mesoporous solid by physisorption methods and pore-size analysis. Applied Catalysis A: General, 1998, 174(1): 137-146.
[27]	EVERETT D H.Manual of symbols and terminology for physicochemical quantities and units, appendix II: Definitions, terminology and symbols in colloid and surface chemistry : pure and applied chemistry. Pure & Applied Chemistry, 1972, 31(4): 71-90.
[28]	SEGAWA H,TATEISHI K, ARAI Y, et al.Patterning of hybrid titania film using photopolymerization. Thin Solid Films, 2004, 466(1/2): 48-53.
[29]	JIANG L X, LI K X, YAN L S, et al.Preparation of Ag(Au)/Graphene-TiO2 composite photocatalysts and their catalytic performance under simulated sunlight irradiation. Chinese Journal of Catalysis, 2012, V33(12): 1974-1981.
[30]	YU J H, FAN M G, LI B, et al.Preparation and photocatalytic activity of mixed phase TiO2-graphene composites. Acta Physico-Chimica Sinica, 2015, 31(3): 519-526.
[31]	HU Y, ZHANG J L, MINAGAWA M, et al.The origin of the decline in the photocatalytic activity of TiO2 in the decomposition of NO: TPD spectra of the adsorbed NO species. Research on Chemical Intermediates, 2003, 29(2): 125-135.
[32]	WANG D T, LI X, CHEN J F, et al. Enhanced photoelectrocatalytic activity of reduced graphene oxide/TiO2 composite films for dye degradation.Chemical Engineering Journal, 2012, s 198-199(4): 547-554.
[33]	FAN S H, SUN Z F, WU Q Z, et al.Adsorption and photocatalytic kinetics of Azo Dyes. Acta Phys.-Chim. Sin., 2003, 19(01): 25-29.

Preparation and Photocatalytic Properties of Mesoporous RGO/TiO₂ Composites

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