Preparation of Octyltrimethoxysilane Modified SiO2 Hydrophobic Antireflective Coating

doi:10.15541/jim20150490

Abstract

Abstract:

The standard SiO₂ sol was prepared by sol-gel process using tetraethylorthosilicate (TEOS) as precursor and ammonia as catalyst. Octyltrimethoxysilane (OTMS) was added into the standard SiO₂ sols before and after refluxing to obtain different organosilane modified silica sols, respectively. Silica antireflective (AR) coatings were then prepared from different SiO₂ sols by dip-coating method. The optical and structural properties of the AR coatings were characterized by Fourier transform infrared spectroscopy, liquid-state ²⁹Si NMR, UV-Vis-NIR spectrometer, atomic force microscope and water contact angle measurement. The results show that the AR coating prepared from OTMS modified before refluxing has the best moisture-resistant performance. The coated glass substrate obtains a high peak transmittance of 99.7%, with water contact angle of 120°. After been placed in a humid environment for 4 w, the transmittance of SiO₂ coatings modified before refluxing is decreased only by 0.23%.

Key words: Sol-Gel, antireflective coating, octyltrimethoxysilane

CLC Number:

O484

NIU Yan-Yan, WANG Xiao-Dong, YAO Lan-Fang, TIAN Bing-Tao, FENG Jian-Bin, CAO Yuan-Yuan, ZHANG Qing-Hua, SHEN Jun. Preparation of Octyltrimethoxysilane Modified SiO₂ Hydrophobic Antireflective Coating[J]. Journal of Inorganic Materials, 2016, 31(5): 499-504.

Figures/Tables 6

Fig. 1 Flow chart of OTMS modified silica sols synthesis process

Fig. 2 Surface morphologies of SiO2 coating prepared from unmodified (a), OTMS modification after refluxing (b) and before refluxing (c) sols

Fig. 3 FTIR spectra of SiO2 coatings prepared from unmodified (a), OTMS modification after refluxing (b) and before refluxing (c) sols

Fig. 4 29Si NMR spectra of sols prepared from OTMS modification before refluxing

Fig. 5 Transmittance spectra for the substrate coated with silica antireflective coatings (a) and evolution of peak transmittance for the coated substrate in humid enviroment (b)

Fig. 6 Water contact angles of silica coatings (a) F0; (b) AF-0.5-1; (c) AF-1-1; (d) BF-0.5-1; (e) BF-1-1

References 21

[1]	FAN DIAN-YUAN, ZHANG XIAO-MIN.Laser fusion and high power laser: history and progress. Physics, 2010, 39(9): 589-596.
[2]	MOSES EDWARD I.The National ignition facility (NIF): a path to fusion energy.Energy Conversion and Management, 2008, 49(7): 1795-1802.
[3]	THOMAS IAN M.High laser damage threshold porous silica antireflective coating.Applied Optics, 1986, 25(9): 1481-1483.
[4]	ZHANG QING-HUA, ZHOU LIAN, YANG WEI, et al.Sol-Gel preparation of a silica antireflective coating with enhanced hydrophobicity and optical stability in vacuum.Chinese Optics Letters, 2014, 12(7): 071601.
[5]	WANG XIAO-DONG, SHEN JUN.Sol-Gel derived durable antireflective coating for solar glass.Journal of Sol-Gel Science and Technology, 2010, 53(2): 322-327.
[6]	RAUT HEMANT KUMAR, GANESH V ANAND, NAIR A SREEKUMARAN, et al.Anti-reflective coatings: a critical, in-depth review.Energy & Environmental. Science, 2011, 4(10): 3779-3804.
[7]	WANG XIAO-DONG, SHEN JUN.A review of contamination-resistant antireflective Sol-Gel coatings.Journal of Sol-Gel Science and Technology, 2012, 61(1): 206-212.
[8]	ZHANG QING-HUA, WEI YAO-WEI, YANG WEI, et al.Improvement on contamination resistance to volatile organics and moisture of Sol-Gel silica antireflective coating for 351 nm laser system by structural modulation with fluorinated compounds.RSC Advances, 2015, 5(6): 4529-4536.
[9]	TAURINO ROSA, FABBRI ELENA, MESSORI MASSIMO, et al.Facile preparation of superhydrophobic coatings by Sol-Gel processes.Journal of Colloid and Interface Science, 2008, 325(1): 149-156.
[10]	ZHANG XIN-XIANG, LIN MING-YUE, LIN LI-XIAO, et al.Sol-Gel preparation of fluoro-containing ORMOSIL antireflective coating with resistance simultaneously to hydrophilic and oleophilic pollutants.Journal of Sol-Gel Science and Technology, 2015, 74(3): 698-706.
[11]	YE LONG-QIANG, ZHANG QING-HUA, ZHANG YU-LU, et al.Design and preparation of SiO2/TiO2/SiO2-TiO2 antireflective coatings with excellent abrasion-resistance and transmittance via Sol-Gel process.Journal of Inorganic Materials, 2012, 27(8): 871-875.
[12]	XIAO BO, ZHANG YU-LU, ZHANG XIN-XIANG, et al.Focus on moisture-resistance and hydrophobicity of SiO2 antireflective film improved by poly (isopropylene oxide) glycerolether.Journal of Sol-Gel Science and Technology, 2011, 60(7): 11-16.
[13]	LIU YUAN, SHEN JUN, ZHOU BIN, et al.Effect of hydrophobicity on the stability of Sol-Gel silica coatings in vacuum and their laser damage threshold.Journal of Sol-Gel Science and Technology, 2013, 68(1): 81-87.
[14]	SHI YAN-LONG, FENG XIAO-JUAN, YANG WU, et al.Superhydrophobicity of ZnO microrod films induced by surface silane modification.Chinese Journal of Applied Chemistry, 2011, 28(4): 402-407.
[15]	SHI YAN-LONG, FENG XIAO-JUAN, YANG WU, et al.Fabrication of superhydrophobic titanium oxide and study of its superhydropbilicity induced by irradiation of ultraviolet light.Chinese Journal of Inorganic Chemistry, 2010, 26(12): 2209-2214.
[16]	YANG TAI-SHENG, TIAN HUI, CHEN YU-QING.Preparation of superhydrophobic silica films with honeycomb-like structure by emulsion method.Journal of Sol-Gel Science and Technology, 2009, 49(2): 243-246.
[17]	ZHANG XIN-XIANG, SU WEN-MU, LIN MING-YUE, et al.Non-supercritical drying Sol-Gel preparation of superhydrophobic aerogel ORMOSIL thin films with controlled refractive index.Journal of Sol-Gel Science and Technology, 2015, 74(3): 594-602.
[18]	ALMEIDA RUI M, PANTANO CARLO G.Structural investigation of silica gel films by infrared spectroscopy.Journal of Applied Physics, 1990, 68(8): 4225-4232.
[19]	GONCALVES GIL, MARQUES PAULA A A P, PINTO RICARDO J B, et al. Surface modification of cellulosic fibres for multi-purpose TiO2 base nanocomposites.Composites Science and Technology, 2009, 69(7/8): 1051-1056.
[20]	ZHANG XIN-XIANG, XIA BI-BO, YE HAI-PING, et al.One-step Sol-Gel preparation of PDMS-silica ORMOSILs as environment-resistant and crack-free thick antireflective coatings. Journal of Materials Chemistry, 2012, 22(26): 13132-13140.
[21]	SUN XIAN-YONG, XU YAO, XU WU-JUN, et al.Liquid-state 29Si NMR investigation on ammonia-catalyzed hydrolysis kinetics of a mixture of tetraethoxysilane and dimethyldiethoxysilane.Acta Chimica Sinica, 2005, 63(23): 2103-2111.
	LI HAI-YUAN, TANG YONG-XING.Study on stability of porous silica antireflective coatings prepared by Sol-Gel processing.Chinese Journal of Lasers, 2005, 32(6): 839-843.

Preparation of Octyltrimethoxysilane Modified SiO₂ Hydrophobic Antireflective Coating

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