Preparation and Properties of Glucose Biosensor Based on Flower-like MoS2 Micrometer Material

doi:10.15541/jim20150352

Abstract

Abstract:

Flower-like MoS₂ micrometer material was successfully synthesized by hydrothermal reaction, which was then used to prepare the glucose biosensor. The performance of the prepared glucose biosensor was examined. Results indicated that as-synthesized MoS₂ is flower-like structure in good crystallinity at ~3.6 μm in length with specific surface area 9.646 m²/g. The biosensor with MoS₂ electrode has a high responsivity of glucose, due to good electrocatalytic activity and small electrical impedance of MoS₂. Glucose detection revealed that oxidation peak current showed a good linear relationship with glucose concentration in the range of 0~20 mmol/L with a correlation coefficient (R) 0.9653. The sensitivity is 262 μA•L/mmol.

Key words: MoS2, hydrothermal method, micron flower, biosensor

CLC Number:

O469

ZHAO De-Rui, ZHAI Ying-Jiao, LI Jin-Hua, CHU Xue-Ying, XU Ming-Ze, LI Xue, FANG Xuan, WEI Zhi-Peng, WANG Xiao-Hua. Preparation and Properties of Glucose Biosensor Based on Flower-like MoS₂Micrometer Material[J]. Journal of Inorganic Materials, 2016, 31(2): 153-158.

Figures/Tables 7

Fig. 1 XRD pattern of MoS2 sample

Fig. 2 Different magnification SEM images of MoS2 at5000 times (a), 10000 times (b), 20000 times (c), and EDS spectrum (d) of MoS2

Fig. 3 (a) BJH pore size distributiona and (b) nitrogen adsorption-desorption isotherms of MoS2

Fig. 4 Cyclic voltammetry curves (scan rate range 10-100 mV/s) (a) and redox peak current and scan rate of the square root of the linear fitting curve of MoS2 electrode (b)

Fig. 5 AC impedance spectrum of NF electrodes and MoS2-NF electrodes (Inset with its equivalent circuit)

Fig. 6 Cyclic voltammetry curves of MoS2 electrodes in the electrolyte before (a) and after (b) the addition of glucose

Fig. 7 MoS2 electrode for glucose detection (a) MoS2 electrode detecting cyclic voltammetry curves of different concentrations of glucose solution; (b) Linear relationship diagram of glucose concentration and oxidation peak current

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Preparation and Properties of Glucose Biosensor Based on Flower-like MoS₂Micrometer Material

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