Preparation and Photoluminescence Properties of Pr-doped Mg2SnO4 Nanoparticles

doi:10.15541/jim20150173

Abstract

Abstract:

Pr doped Mg₂SnO₄in the scope of 0~1.5nm% was synthesized by hydrothermal method and corresponding calcination at low temperature. X-ray diffraction (XRD), Scanning electron microscope (SEM) and luminescence/ fluorescence spectrophotometer were applied to characterize Pr doped Mg₂SnO₄. The relationship between Pr doping contents and the morphologies of Mg₂SnO₄ particles was studied. The results show that the Mg₂SnO₄: Pr³⁺are confirmed to be the cubic inverse spinel structure and exhibit as cubic particles. An augment of the grain sizes and obvious sharpen edges of the cubic nanoparticles are observed with increasing Pr doping amounts. The emission spectra of Mg₂SnO₄nanoparticles with various Pr doping contents indicate two bands centered at 530 nm and 570 nm, respectively. The former emission band is related with the oxygen vacancies in Mg₂SnO₄ and the latter emission band is attributed to the ³P₀-³H₅energy transitions of Pr³⁺. The increase of luminescence center’s number and Pr-doped Mg₂SnO₄ particles size result in an obvious enhancement of emission intensity centered at 570 nm with increasing Pr doping contents.

Key words: Mg2SnO4, nanoparticles, Pr doping, photoluminescence

CLC Number:

TQ139

GUO Peng, PENG Lin-Zhi, ZHANG Wei-Hai, LIU Lei, XIONG Juan. Preparation and Photoluminescence Properties of Pr-doped Mg₂SnO₄Nanoparticles[J]. Journal of Inorganic Materials, 2015, 30(11): 1172-1176.

Figures/Tables 5

Fig. 1 XRD patterns of Mg2SnO4 doped with different amounts of Pr (a) Full pattern; (b) Partial enlarged pattern

Fig. 2 SEM images of Mg2SnO4 doped with different amount of Pr (a) 0; (b) 0.5mol%; (c) 1.0mol%; (d) 1.5mol%

Fig. 3 EDS spectra of Mg2SnO4 doped with different amount of Pr (a) 0; (b) 0.5mol%; (c) 1.0mol%; (d) 1.5mol%

Fig. 4 (a) Excitation and (b) emission spectra of Mg2SnO4 doped with different amount of Pr

Fig. 5 Schematic energy level diagram for Pr3+ ion

References 18

[1]	LEOSTEAN C, STEFAN M, PANA O, et al.Properties of Eu doped TiO2 nanoparticles prepared by using organic additives.Journal of Alloys and Compounds, 2013, 575(10): 29-39.
[2]	LEE MIN-HO, JUNG WOO-SIK.Facile synthesis of LaAlO3 and Eu (II)-doped LaAlO3 powders by a solid-state reaction.Ceramics International, 2015, 41(4): 5561-5567.
[3]	CHO IN-SU, KANG JUN-GILL, SOHN YOUNG-KU.Photoluminescence profile imaging of Eu (III), Tb(III) and Eu (III)/Tb (III)-doped yttrium oxide nanosheets and nanorods.Journal of Luminescence, 2015, 157(2): 264-274.
[4]	JU ZHENG-HUA, ZHANG SHUI-HE, GAO XIU-PING, et al.Reddish orange long afterglow phosphor Ca2SnO4: Sm3+ prepared by Sol-Gel method.Journal of Alloys and Compounds, 2011, 509(31): 8082-8087.
[5]	YU XUE, XU XU-HUI, QIU JIAN-BEI.Enhanced long persis-tence of Sr2SnO4: Sm3+ red phosphor by co-doping with Dy3+.Materials Research Bulletin, 2011, 46(4): 627-629.
[6]	ZHANG JIA-CHI, QIN QING-SONG, YU MING-HUI, et al.The photoluminescence, afterglow and up conversion photostimulated luminescence of Eu3+ doped Mg2SnO4 phosphors.Journal of Luminescence, 2012, 132(1): 23-26.
[7]	SHENG QIU-CHUN, WANG XIAO-LIN, CHEN DAN-PING.Near-infrared emission from Pr-doped borophosphate glass for broadband telecommunication.Journal of Luminescence, 2013, 135(3): 38-41.
[8]	SU JING, YANG XIAO-FENG, WANG LING, et al.Preparation, structure and optical properties of Pr: Gd2O3 phosphor.Materials Letters, 2011, 65(19/20): 2852-2854.
[9]	ZHANG JIA-CHI, QIN QING-SONG, YU MING-HUI, et al.Up-conversion photostimulated luminescence of Mg2SnO4 for optical storage.Chinese Physical Letters, 2011, 28(2): 027802.
[10]	LI GUO-GANG, ZHANG XIAO, PENG CHONG, et al.Cyan- emitting Ti4+- and Mn2+-coactivated Mg2SnO4 as a potential phosphor to enlarge the color gamut for field emission display.Journal of Materials Chemistry, 2011, 21(8): 6477-6479.
[11]	CAI LIANG, HE JING-FU, LIU QING-HUA, et al.Vacancy-induced ferromagnetism of MoS2 nanosheets.Journal of the American Chemical Society, 2015, 137(7): 2622-2627.
[12]	YE MEI-DAN, XIN XU-KAI, LIN CHANG-JIAN, et al.High efficiency dye-sensitized solar cells based on hierarchically structured nanotubes.Nano Letters, 2011, 11(8): 3214-3220.
[13]	TANG MIAN-MIAN, WANG XU-SHENG, PENG DENG-FENG, et al.Strong green and red up-conversion emission in Ho3+, Yb3+ and Li+ co- or tri-doped SrAl2O4 ceramics.Journal of Alloys and Compounds, 2012, 529: 49-51.
[14]	CHUANG SHIOW-HUEY, LINA HONG-CAI, CHEN CHING- HSIANG.Oxygen vacancy relationship to photoluminescence and heat treatment methods in hafnium oxide powders.Journal of Alloys and Compounds, 2014, 534: 42-46.
[15]	LI YE-ZHOU, WANG ZHAO-FENG, SUN LU-YI, et al.Investigation of oxygen vacancy and photoluminescence in calcium tungstate nanophosphors with different particle sizes.Materials Research Bulletin, 2014, 50: 36-41.
[16]	SUN HAI-PING, PENG DENG-FENG, WANG XU-SHENG, et al.Green and red emission for (K0.5Na0.5)NbO3: Pr ceramics.Journal of Applied Physics, 2012, 111: 046102.
[17]	TISEAN CARMEN, PARVULESCU VASILE, AVRAM DANIEL, et al.Structural, down- and phase selective up-conversion emission properties of mixed valent Pr doped into oxides with tetravalent cations.Physical Chemistry Chemical Physics, 2014, 16: 5793-5802.
[18]	QIANG R F, XIAO SIGUO, DING J W, et al.Red emission in B3+- and Li+-doped SrAl2O4: Eu3+ phosphor under UV excitation.Journal of Luminescence, 2009, 129(8): 826-828.

Preparation and Photoluminescence Properties of Pr-doped Mg₂SnO₄Nanoparticles

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 5

References 18

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	YU Yefan, XU Ling, NI Zhongbing, SHI Dongjian, CHEN Mingqing. Prussian Blue Modified Biochar: Preparation and Adsorption of Ammonia Nitrogen from Sewage [J]. Journal of Inorganic Materials, 2023, 38(2): 205-212.
[2]	LIU Qi, ZHU Can, XIE Guizhen, WANG Jun, ZHANG Dongming, SHAO Gangqin. Optical Absorption and Photoluminescence Spectra of Ce-doped SrMgF₄Polycrystalline with Superlattice Structure [J]. Journal of Inorganic Materials, 2022, 37(8): 897-902.
[3]	WANG Xiaojun, XU Wen, LIU Runlu, PAN Hui, ZHU Shenmin. Preparation and Properties of Ag@C₃N₄ Photocatalyst Supported by Hydrogel [J]. Journal of Inorganic Materials, 2022, 37(7): 731-740.
[4]	GUAN Xufeng, LI Guifang, WEI Yunge. Microstructure and Thermal Quenching Characteristics of Na_1-_xM_xCaEu(WO₄)₃ (M=Li, K) Red Phosphor [J]. Journal of Inorganic Materials, 2022, 37(6): 676-682.
[5]	MA Hui, TAO Jianghui, WANG Yanni, HAN Yu, WANG Yabin, DING Xiuping. Gold Nanoparticles Supported on Silica & Titania Hybrid Mesoporous Spheres and Their Catalytic Performance Regulation [J]. Journal of Inorganic Materials, 2022, 37(4): 404-412.
[6]	ZHANG Guoqing, QIN Peng, HUANG Fuqiang. Reversible Conversion between Space-confined Lead Ions and Perovskite Nanocrystals for Confidential Information Storage [J]. Journal of Inorganic Materials, 2022, 37(4): 445-451.
[7]	DU Aochen, DU Qiyuan, LIU Xin, YANG Yimin, XIA Chenyang, ZOU Jun, LI Jiang. Ce:YAG Transparent Ceramics Enabling High Luminous Efficacy for High-power LEDs/LDs [J]. Journal of Inorganic Materials, 2021, 36(8): 883-892.
[8]	SU Li, YANG Jianping, LAN Yue, WANG Lianjun, JIANG Wan. Interface Design of Iron Nanoparticles for Environmental Remediation [J]. Journal of Inorganic Materials, 2021, 36(6): 561-569.
[9]	ZHANG Yiqing,ZHANG Shujuan,WAN Zhengrui,MO Han,WANG Niangui,ZHOU Liqun. RuFe Nanoparticles Modified Sheet-like BiVO₄ : High-efficient Synergistic Catalyst for Ammonia Borane Hydrolytic Dehydrogenation [J]. Journal of Inorganic Materials, 2020, 35(7): 809-816.
[10]	SHAO Kang,WANG Tao,WEN Yingting,TENG Yuanjie,LIU Huijun,PAN Zaifa. Modulation of Morphology and Luminescence Property of NaBiF₄:Yb³⁺/Er³⁺ Upconversion Nanoparticles by Organic Ligands [J]. Journal of Inorganic Materials, 2020, 35(4): 447-453.
[11]	ZHANG Zhijie,HUANG Hairui,CHENG Kun,GUO Shaoke. High Efficient Carbon Quantum Dots/BiOCl Nanocomposite for Photocatalytic Pollutant Degradation [J]. Journal of Inorganic Materials, 2020, 35(4): 491-496.
[12]	GUO Si-Lin, KANG Shuai, LU Wen-Qiang. Ge Nanoparticles in MXene Sheets: One-step Synthesis and Highly Improved Electrochemical Property in Lithium-ion Batteries [J]. Journal of Inorganic Materials, 2020, 35(1): 105-111.
[13]	LI Sheng-Song, ZHENG Yong-Chao, MENG Shu-Lin, WU Li-Zhu, ZHONG Jin- Yi, ZHAO Chong-Lin. Core/Shell Quantum Dots and Au Nanoparticles Assembly for Effective Detection of Nerve Agent Mimic [J]. Journal of Inorganic Materials, 2019, 34(8): 893-898.
[14]	ZHU Meng-Meng, LI Guo-Hua, ZHANG Xue-Ming, ZHAI Jia-Xin, GAN Si-Ping, SONG Xiao. Boron Nitride Nanosheets Supported Cu₂O Nanoparticles: Synthesis and Catalytic Reduction for 4-nitrophenol [J]. Journal of Inorganic Materials, 2019, 34(8): 817-826.
[15]	CHENG Tian-Sheng, PAN Jiong, XU Ying-Ying, BAO Qun-Qun, HU Ping, SHI Jian-Lin. Synthesis of Zn, Mn doped Fe₃O₄ Nanoparticles with Tunable Size [J]. Journal of Inorganic Materials, 2019, 34(8): 899-903.