Journal of Inorganic Materials ›› 2014, Vol. 29 ›› Issue (12): 1246-1252.DOI: 10.15541/jim20140185
• Orginal Article • Previous Articles Next Articles
YANG Nai-Tao1, SHEN Yi-Chi1, YAN Wei1, MENG Xiu-Xia1, TAN Xiao-Yao2, MA Zi-Feng3
Received:
2014-04-14
Revised:
2014-05-23
Published:
2014-12-20
Online:
2014-11-20
Supported by:
CLC Number:
YANG Nai-Tao, SHEN Yi-Chi, YAN Wei, MENG Xiu-Xia, TAN Xiao-Yao, MA Zi-Feng. Microstructure and Performance of Anode for Microtubular Solid Oxide Fuel Cells[J]. Journal of Inorganic Materials, 2014, 29(12): 1246-1252.
Fig. 1 Microstructures of YSZ/NiO-YSZ dual-layer hollow fibers (1450℃) Internal coagulant was (a) pure ethanol, (b) 70wt% ehanol/30 wt% NMP, (c) 50wt% ehanol/50 wt% NMP, (d) 30wt% ehanol/70wt% NMP and (e) pure NMP; 1-cross-section, 2-inner surface, 3-outer surface
Substance/mixtures | δ | δd | δp | δh |
---|---|---|---|---|
PESf | 21.9 | 17.6 | 10.4 | 7.8 |
NMP | 22.9 | 18 | 12.3 | 7.2 |
H2O | 47.9 | 15.5 | 16.0 | 42.3 |
Ethanol(EtOH) | 26.0 | 15.8 | 8.8 | 19.4 |
EtOH/NMP=7: 3 | 24.8 | 16.46 | 9.85 | 15.74 |
EtOH/NMP=5: 5 | 24.0 | 16.9 | 10.55 | 13.3 |
EtOH/NMP=3: 7 | 23.3 | 17.34 | 11.25 | 10.86 |
Table 1 Solubility parameters of the solvent and non-solvent
Substance/mixtures | δ | δd | δp | δh |
---|---|---|---|---|
PESf | 21.9 | 17.6 | 10.4 | 7.8 |
NMP | 22.9 | 18 | 12.3 | 7.2 |
H2O | 47.9 | 15.5 | 16.0 | 42.3 |
Ethanol(EtOH) | 26.0 | 15.8 | 8.8 | 19.4 |
EtOH/NMP=7: 3 | 24.8 | 16.46 | 9.85 | 15.74 |
EtOH/NMP=5: 5 | 24.0 | 16.9 | 10.55 | 13.3 |
EtOH/NMP=3: 7 | 23.3 | 17.34 | 11.25 | 10.86 |
Fig. 7 EIS of MT-SOFC based asymmetric anode at OCV (800℃) (a) Ratio of NMP/ethanol; (b) Total resistance(Rt), polarization resistance, activation resistance(Ra), and diffusion resistance (Rd)
NMP | Ro/Ω | Ra/Ω | Rt/Ω | Rp/Ω | Rd/Ω | (Ra/Rp)×100 | (Rd/Rp)×100 |
---|---|---|---|---|---|---|---|
0 | 0.16 | 0.37 | 1.22 | 1.06 | 0.69 | 34.91 | 65.09 |
30wt% | 0.16 | 0.23 | 0.86 | 0.70 | 0.47 | 32.86 | 67.14 |
50wt% | 0.16 | 0.22 | 0.76 | 0.60 | 0.38 | 36.67 | 63.33 |
70wt% | 0.16 | 0.21 | 0.50 | 0.34 | 0.13 | 61.76 | 38.24 |
100wt% | 0.16 | 0.26 | 0.56 | 0.40 | 0.14 | 65.00 | 35.00 |
Table 2 Resistance vs internal coagulants for MT-SOFC
NMP | Ro/Ω | Ra/Ω | Rt/Ω | Rp/Ω | Rd/Ω | (Ra/Rp)×100 | (Rd/Rp)×100 |
---|---|---|---|---|---|---|---|
0 | 0.16 | 0.37 | 1.22 | 1.06 | 0.69 | 34.91 | 65.09 |
30wt% | 0.16 | 0.23 | 0.86 | 0.70 | 0.47 | 32.86 | 67.14 |
50wt% | 0.16 | 0.22 | 0.76 | 0.60 | 0.38 | 36.67 | 63.33 |
70wt% | 0.16 | 0.21 | 0.50 | 0.34 | 0.13 | 61.76 | 38.24 |
100wt% | 0.16 | 0.26 | 0.56 | 0.40 | 0.14 | 65.00 | 35.00 |
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