High Temperature Hydrogenation Behavior of Bulk Titanium Aluminum Carbide

doi:10.15541/jim20130584

Abstract

Abstract:

Ti₃AlC₂ is a new type of nano-layered machinable ceramic with numerous salient properties. Therefore, recently it is considered to be a promising candidate for new generation reactors as the key structural material. In this work, the reaction product and material morphology between nano-layered Ti₃AlC₂ and hydrogen were investigated by XRD, SEM, EDS, XPS and Raman. The resulted gaseous products were calculated by Factsage sofeware. Under the condition of 700-1000℃, hydrogen atmosphere (low oxygen pressure), solid products are Al₂O₃, TiO₂ and C and gaseous product is CH₄. Hydrides are not detected in the current experiments. The SEM results indicate that the reacted samples keep intact and cracks are not formed on the surface, indicating the high temperature thermal stability of Ti₃AlC₂ in hydrogen. These results can be attributed to the formation of oxides on the surface of specimens.

Key words: Ti3AlC2, hydrogen atmosphere, thermal stability, hydrogen resistance

CLC Number:

TQ174

CHEN Chen, ZHANG Hai-Bin, PENG Shu-Min, ZHAO Lin-Jie, ZHU Jian-Guo. High Temperature Hydrogenation Behavior of Bulk Titanium Aluminum Carbide[J]. Journal of Inorganic Materials, 2014, 29(8): 864-868.

Figures/Tables 6

Fig. 1 XRD patterns of Ti3AlC2 specimens after treatment at 700-1000℃ for 10 h in 1mol% H2 and 99mol% Ar(contain-ing 10-6wt% O2)

Fig. 2 Raman spectra of bulk Ti3AlC2 after treatment at 700- 1000℃ in 1mol% H2 and 99mol% Ar(containing 10-6wt% O2)

Fig. 3 XPS surface analysis of Ti3AlC2 after hydrogen treatment (containing 10-6 wt% O2) at 800℃ and 1000℃ (a) Al2p; (b) O1s; and (c) Ti2p contrast

Fig. 4 Surface morphologies of the Ti3AlC2 specimens after treatment for 10 h at (a) 700℃, (b) 800℃, (c) 900℃ and (d) 1000℃ in the 1mol% H2 and 99mol% Ar (containing 10-6wt% O2)

Table 1 EDS analyses of spots A, B, C, D, E in Fig. 4

	A	B	C	D	E
O/wt%	20.29	36.23	46.57	42.27	56.53
Al/wt%	14.30	41.67	12.97	31.33	35.99
Ti/wt%	51.54	18.38	32.59	19.22	7.48

Fig. 5 Simulated result of gaseous reaction product of Ti3AlC2 and H2 at 500-1200℃

References 8

[1]	GRAEME ACKLAND. Controlling radiation damage. Materials Science, 2010, 327(5973): 1587-1588.
[2]	BARNES L A, DIETZ RAGO N L, LEIBOWITZ L. Corrosion of ternary carbides by molten lead. Journal of Nuclear Materials, 2008, 373(1/2/3): 424-428.
[3]	HEINZEL A, MÜLLER G, WEISENBURGER A. Compatibility of Ti3SiC2 with liquid Pb and PbBi containing oxygen. Journal of Nuclear Materials, 2009, 392(2): 255-258.
[4]	张磊. 辐照损伤材料的实验模拟研究:含氦薄膜制备及MAX相材料离子辐照行为. 上海: 复旦大学博士学位论文, 2011.
[5]	WHITTLE K R, BLACKFORD M G, AUGHTERSON R D, et al. Radiation tolerance of Mn+1AXn phases, Ti3AlC2 and Ti3SiC2. Acta Materialia, 2010, 58(13): 4362-4368.
[6]	王晓辉. 层状可加工陶瓷Ti3AlC2、Ti2AlC的合成与性能. 沈阳: 中国科学院沈阳金属研究所博士学位论文, 2005.
[7]	QU X D, WANG Y X, SHI L Q, et al. Effect of hydrogen-doping on bonding properties of Ti3SiC2. Physica B, 2011, 406(23): 4460-4465.
[8]	ZHANG HAIBIN, VOLKER PRESSER, CHRISTOPH BERTH-OLD, et al. Mechanisms and kinetics of the hydrothermal oxidation of bulk titanium silicon carbide. Journal of American Ceramic Society, 2010, 93(4): 1148-1155.

[1]	LI Yue, ZHANG Xuliang, JING Fangli, HU Zhanggui, WU Yicheng. Growth and Property of Ce³⁺-doped La₂CaB₁₀O₁₉ Crystal [J]. Journal of Inorganic Materials, 2023, 38(5): 583-588.
[2]	LIU Ding, YU Yang, MI Le, YU Yun, SONG Li-Xin. Preparation of Room Temperature Curable Organic-inorganic Hybrid Thermal Control Coatings [J]. Journal of Inorganic Materials, 2018, 33(8): 914-918.
[3]	FAN Guang-Xin, LIU Ze-Ping, WEN Yin, LIU Bao-Zhong. Surface Treatment on Structure and Property of LiNi_0.8Co_0.15Al_0.05O₂ by Silane Coupling Agent [J]. Journal of Inorganic Materials, 2018, 33(7): 749-755.
[4]	YANG Jing-Feng, WANG Qi-Hua, WANG Ting-Mei. Synthesis and Property of Alumina Aerogel [J]. Journal of Inorganic Materials, 2018, 33(3): 259-265.
[5]	ZHANG Heng-Fei, LIU Wei, LEI Jiao-Jiao, SONG Hua-Ting, QI Hong. Pd Doping on H₂/CO₂ Separation Performance and Hydrothermal Stability of Organic-inorganic Hybrid SiO₂ Membranes [J]. Journal of Inorganic Materials, 2018, 33(12): 1316-1322.
[6]	WANG Mi-Tang, FANG Long, LI Mei, LIU Zhao-Gang, HU Yan-Hong, ZHANG Xiao-Wei. Effect of Rare Earth Dopant on Thermal Stability and Structure of ZnO-B₂O₃-SiO₂ Glass [J]. Journal of Inorganic Materials, 2017, 32(6): 643-648.
[7]	LONG Pei-Qing, LIU Xi-Tao, YI Zhi-Guo. Effect of Sintering Process on Microstructure and Properties of Ba_0.85Ca_0.15)(Ti_0.9Zr_0.1)O₃Lead-free Ceramics [J]. Journal of Inorganic Materials, 2017, 32(3): 299-304.
[8]	WANG Nai-Qian, ZHANG Qun, SHIEH Han-Ping. Influence of Double Channel Layers on the Performance of Nitrogen Doped Indium-zinc-oxide Thin Film Transistors [J]. Journal of Inorganic Materials, 2016, 31(7): 745-750.
[9]	XIE Xiao-Hua, LI Xiao-Zhe, LI Wei-Biao, SHAO Guang-Jie, XIA Bao-Jia. Fabrication and Performance of PET-ceramic Separators [J]. Journal of Inorganic Materials, 2016, 31(12): 1301-1305.
[10]	LUO Ling-Hong, YU Hui, HUANG Zu-Zhi. Research Progress of the Sealing Glass for Intermediate Temperature Solid Oxide Fuel Cell [J]. Journal of Inorganic Materials, 2015, 30(2): 113-121.
[11]	LI Xian-Hua, ZHANG Lei-Gang, WANG Xue-Xue, YU Qing-Bo. Synthesis of Porous g-C₃N₄ Loaded With Highly Dispersed PANI by Interfacial Polymerization and Its Photocatalytic Performance [J]. Journal of Inorganic Materials, 2015, 30(10): 1018-1024.
[12]	YIN Dong-Mei, TU De-Yang, CHE Bing-Chen, ZHANG Fang-Fang, LIN Chang-Gui, DAI Shi-Xun. Effect of Sn Addition on the Structure and Optical Properties of Ge-Se-Te Chalcogenide Glasses [J]. Journal of Inorganic Materials, 2014, 29(3): 279-283.
[13]	PENG Cheng, ZHANG Chu-Xin, L? Ming, LI Zhi-Hong, WU Jian-Qing. Co-precipitation Synthesis and Thermal Stability of Zircon Encapsulated Carbon Black [J]. Journal of Inorganic Materials, 2013, 28(8): 847-852.
[14]	ZHANG Li-Jie, GU Jing-Hua, YAO Hong-Ying, ZHANG Yue. Preparation and Thermal Stability of Porous Silica-based Monoliths [J]. Journal of Inorganic Materials, 2011, 26(9): 949-954.
[15]	LI Zhi, MIAO Chun-Yu, MA Chun-Yu, ZHANG Qing-Yu. Structural and Optical Properties of HfLaO Films Prepared by RF Magnetron Sputtering [J]. Journal of Inorganic Materials, 2011, 26(12): 1281-1286.