Journal of Inorganic Materials ›› 2014, Vol. 29 ›› Issue (1): 71-76.DOI: 10.3724/SP.J.1077.2014.13200

• Research Paper • Previous Articles     Next Articles

Preparation and Dielectric Properties of the Three-phase Composites of Graphite Oxide/Barium Titanate/Epoxy Resin

KOU Si-Wang1,2, YU Shu-Hui2, SUN Rong2, YANG Hai-Peng1   

  1. (1. College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China; 2. Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China)
  • Received:2013-04-10 Revised:2013-05-22 Published:2014-01-20 Online:2013-12-09
  • About author:KOU Si-Wang. E-mail:kou8907@163.com
  • Supported by:

    National Natural Science Fourdation of China (51377157); Advanced Electronic Packaging Materials Innovation Team of Guangdong Province (2011D052); Shenzhen Outstanding Young Talents Project (JC201005270367A)

Abstract: Polymer-based dielectric composites have important applications in the fields of power engineering, microelectronics and high-density packaging. In this study, graphite oxide was prepared through oxidizing nature graphite ?akes with concentrated sulfuric acid and potassium permanganate. And graphite oxide/barium titanate/epoxy resin (GO/BT/ER) three-phase composites were prepared. Dielectric performance of the composites with varied GO loading amounts was investigated. The experimental results showed that the GO/BT/ER composites with low GO loading amount exhibited higher dielectric constant than that of BT/ER and the dielectric loss remained low. The dielectric constant of 3wt%GO/BT/ER composite was 42.6 and the dielectric loss was 0.043 (20℃, 1 kHz), while the dielectric constant of the BT/ER composites was 17.7. Therefore, the GO/BT/ER composites are promising candidates for the embedded dielectrics. Furthermore, the mechanism of graphite oxide on the dielectric properties of the composites also explored.

Key words: graphite oxide, barium titanate, epoxy resin, three-phase composite, dielectric properties

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