Preparation and Electrochemical Properties of Ti/TiO2-MnO Nano Array Electrode for Supercapacitor

doi:10.3724/SP.J.1077.2013.13106

Abstract

Abstract: A Ti/TiO₂-MnO composite electrode was prepared by anodizing, chemical dipping and annealing. The crystalline structure and the microscopic morphology of the sample were characterized by XRD and SEM. The results show that the pore diameters of the Ti/TiO₂ nanotube arrays (NTAs) range from 60 nm to 95 nm, and their lengths range from 350 nm to 820 nm. Ti/TiO₂ nanotube array obtained through anodizing at ambient temperature is amorphous. However, it transforms from amorphous to anatase after annealing at 500℃. Only MnO is found after the sample is immersed in MnSO₄ solution. A button supercapacitor device is assembled and its cyclic voltammetry curves are determined. It shows that its cyclic voltammetry curves have a pair of redox peaks, which corresponds to the calation/intercalation process of H⁺in NTAs. The intercalation/calation process of H⁺ is controlled by diffusion. The CV response current of Ti/TiO₂-MnO electrode decreases as TiO₂ transforms from amorphous structure to anatase and MnO deposites in NTAs.

Key words: anodic oxidation, Ti/TiO₂-MnO nanotube array electrode, supercapacitor, electrochemical properties

CLC Number:

TQ152

HUANG You-Guo, ZHENG Feng-Hua, REN Meng-De, LI Qing-Yu, WANG Hong-Qiang. Preparation and Electrochemical Properties of Ti/TiO₂-MnO Nano Array Electrode for Supercapacitor[J]. Journal of Inorganic Materials, 2013, 28(11): 1228-1232.

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Preparation and Electrochemical Properties of Ti/TiO₂-MnO Nano Array Electrode for Supercapacitor

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