Preparation and Characteristic of Hollow BN Fibers Derived from Organic Precursors

doi:10.3724/SP.J.1077.2012.12074

Journal of Inorganic Materials ›› 2012, Vol. 27 ›› Issue (11): 1216-1222.DOI: 10.3724/SP.J.1077.2012.12074

• Research Paper • Previous Articles Next Articles

Preparation and Characteristic of Hollow BN Fibers Derived from Organic Precursors

CHEN Ming-Wei^{1, 2}, Ge Min¹, ZHANG Wei-Gang¹

(1. State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China; 2. Graduate University of the Chinese Academy of Sciences, Beijing 100049, China)

Received:2012-02-06 Revised:2012-04-03 Published:2012-11-20 Online:2012-10-25
About author:CHEN Ming-Wei. E-mail: mwchen@home.ipe.ac.cn
Supported by:
863 Program (2012AA03A210)

Abstract

Abstract: BN fibers with cylindrical hollow structures were prepared from organic polymeric precursors through melt spinning, curing and pyrolysis processes. The microstructure, solid phase and morphologies of the synthesized hollow BN fibers were investigated by XRD, SEM and TEM, respectively. Moreover, the dielectric properties of BN hollow fibers were also measured. The results show that heating temperature and heating rate are the key factors affected the structure and dielectric properties of BN hollow fibers. Moreover, the BN hollow fibers synthesized in the optimized process conditions have good resistance towards oxidation up to 950℃ in an oxidation atmosphere, and possess very low dielectric constant (ε′) and loss tangent (tanδ) less than 3.30 and 0.00064 (7-18 GHz), respectively.

Key words: boron nitride, ceramic fibers, dielectric properties, organic polymetric precursor

CLC Number:

TQ343

CHEN Ming-Wei, Ge Min, ZHANG Wei-Gang. Preparation and Characteristic of Hollow BN Fibers Derived from Organic Precursors[J]. Journal of Inorganic Materials, 2012, 27(11): 1216-1222.

References

[1] Paquette D G. Method of Making a Radar Transparent Window Material Operable Above 2000℃. US, patent 5627542. 1997-03-06.

[2] Dodds C G, Richard A T. Boron Nitride-Toughened Single Phase Silicon Aluminum Oxynitride Composite, Article and Method of Making Same patent; US, 5925584.1999-07-20.

[3] Medri V, Bracisiewicz M, Krnel K, et al. Degradation of mechanical and electrical properties after long-term oxidation and corrosion of non-oxide structural ceramic composites. Journal of the European Ceramic Society, 2005, 25(10): 1723–1731.

[4] Duriez C, Framery E, Toury B, et al. Boron nitride thin fibres obtained from a new copolymer borazine- tri(methylamino) borazine precursor. J. Organomet. Chem., 2002, 657(1):107–114.

[5] Toury B, Miele P, Cornu D, et al. Boron nitride fibers prepared from symmetric and asymmetric alkylaminoborazine. Advanced Functional Materials,?2002, 12(3): 228–234.

[6] Toury B, Miele P. A new polyborazine-based route to boron nitride. Journal of Materials Chemistry, 2004, 14(17): 2609–2611.

[7] Paciorek K J, Kratzer R H, Kimble P F, et al．Boron-nitrogen polymers 3:nitrogen-and oxygen-bridged compounds．Inorganic Chemistry, 1988, 27 (14): 2432–2436.

[8] Wideman T, Remsen E E, Cortez E, et al．Amone-modified polyborazylenes: second-generation precursors to boron nitride. Chemistry of Materials?, 1998, 10(1): 412–421.

[9] Okana Y, Yamashita H. Boron Nitride Fiber and Process for Production Thereof: US Patent, 5780154. 1998-07-14.

[10] Cornu D, Bernard S, Duperrier S, et al. Alkylaminoborazine-based precursors for the preparation of boron nitride fibers by the polymer-derived ceramics (PDCs) route. Journal of the European Ceramic Society, 2005, 25(2/3):111–121.

[11] GE Min, SHEN Zhi-Xun, CHEN Ming-Wei, et al. Synthesis of polycarbosilane modified by B-trichloroborazine and its ceramic conversion. Materials Science and Technology, 2010, 18(4): 504–508.

[12] WANG Yu, WANG Xi, CAO Wei-liang, et al. Preparation and characterization of B-trichloroborazine and its derivatives. The Chinese Journal of Process Engineering, 2007, 7(6): 1099–1106.

[13] Cofer C C, Economy J. Oxidation and hydrolytic stability of boron nitride-a new approach to improving the oxidation resistance of carbonaceous structures. Carbon, 1995, 33(4): 389–395.

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Preparation and Characteristic of Hollow BN Fibers Derived from Organic Precursors

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