Characteristics of Sb Film Electrode Prepared by Vacuum Depositing

doi:10.3724/SP.J.1077.2012.11502

Journal of Inorganic Materials ›› 2012, Vol. 27 ›› Issue (7): 746-750.DOI: 10.3724/SP.J.1077.2012.11502

• Research Paper • Previous Articles Next Articles

Characteristics of Sb Film Electrode Prepared by Vacuum Depositing

LI Yan-Hong, QIU Xin-Ping, LIU Yuan

(Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China)

Received:2011-08-12 Revised:2011-09-30 Published:2012-07-20 Online:2012-06-06
About author:LI Yan-Hong. E-mail: aiorange@126.com
Supported by:
Major State Basic Research Development Program (2009CB220100-G)

Abstract

Abstract: Vacuum depositing was employed to prepare antimony (Sb) film electrode as anode for lithium-ion batteries. The crystal structure, surface morphology, electrochemical properties and lithium insertion/ extraction characteristics of the so-obtained film electrode were investigated by XRD, SEM, constant current charge-discharge testing and CV. The results show that Sb film is obtained with a hexagonal structure and (003) preferred orientation. The morphology of Sb film is similar to that of Cu foil and Sb metal possesses a platelet shape. It can be observed that Li₃Sb alloy appears and Sb phase disappears during the first lithium insertion process, and Sb phase appeares and Li₃Sb alloy disappears reversibly during the lithium extraction process. The initial lithium insertion/ extraction specific capacity of Sb film can reach 652 and 454 mAh/g, respectively. And insertion specific capacity is 300 mAh/g after 16 cycles, which is larger than that of Sb powder electrode.

Key words: lithium-ion batteries, cathode, Sb film, electrochemical characteristics

CLC Number:

TM911

LI Yan-Hong, QIU Xin-Ping, LIU Yuan. Characteristics of Sb Film Electrode Prepared by Vacuum Depositing[J]. Journal of Inorganic Materials, 2012, 27(7): 746-750.

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Characteristics of Sb Film Electrode Prepared by Vacuum Depositing

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