Temperature Stability of the Pb(Mn1/3Sb2/3)0.05Zr0.47Ti0.48O3 Piezoelectric Ceramics

doi:10.3724/SP.J.1077.2012.00271

Abstract

Abstract: The Effects of ragid additive of MnO₂, soft additive of, Nb₂O₅and double additive of Cr₂O₃on the crystallographic phase and temperature stability of Pb(Mn_1/3Sb_2/3)_0.05Zr_0.47Ti_0.48O₃(PMSZT5) piezoelectric ceramic were studied. The results show that the pure perovskitic structure is obtained after calcined at 900℃. With these additives increasing, the amount of tetroganal phases decrease, and the morphotropic phase boundary(MPB) is correspondingly shift to the rhombohedral phase. Considering the effects of ion doping on the electric properties and temperature stability comprehensively, the PMSZT5 ceramic doped with MnO₂ has more excellent temperature stability than that doped with Nb₂O₅ and Cr₂O₃. A well-situated property of relative dielectric constant ε₃₃^T/ε₀ (1560), piezoelectric constant d₃₃ (350 pC/ N) and planar coupling factor K_p (0.63) are obtained for the composition of PMSZT5+ 0.1wt% MnO₂. Accordingly, the average temperature coefficients of f_r, K₃₁ and d₃₁, the PMSZT ceramics are 72×10^-6/℃, -0.027%/℃, 0.100%/℃ at the temperature range of -25℃ to 80℃.

Key words: PMSZT piezoelectric ceramic, doping, crystallographic phase, temperature stability

CLC Number:

TM282

LU Cui-Min, LIU Qing-Suo, ZUO Jian-Bo, SUN Qing-Chi. Temperature Stability of the Pb(Mn_1/3Sb_2/3)_0.05Zr_0.47Ti_0.48O₃ Piezoelectric Ceramics[J]. Journal of Inorganic Materials, 2012, 27(3): 271-276.

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Temperature Stability of the Pb(Mn_1/3Sb_2/3)_0.05Zr_0.47Ti_0.48O₃ Piezoelectric Ceramics

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