Journal of Inorganic Materials ›› 2010, Vol. 25 ›› Issue (11): 1228-1232.DOI: 10.3724/SP.J.1077.2010.10223

• Research Letter • Previous Articles    

Preparation and Characterization of Micro-patterned BiFeO3 Films by Photolithography-self-assembly Method

WANG Yan, TAN Guo-Qiang, MIAO Hong-Yan   

  1. (Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology, Xi'an710021, China)
  • Received:2010-04-08 Revised:2010-05-31 Published:2010-11-20 Online:2010-11-01
  • Supported by:

    National Natural Science Foundation of China(50872077); Innovation Team Fundation of Shaanxi University of Science and Technology(TD09-05); Graduate Innovation Foundation of Shaanxi University of Technology(SUST-A04)

Abstract: Micro-patterned BiFeO3 thin films were prepared successfully on glass substrates by photolithography-self-assembly method. The characterizations of samples were carried out through XRD, SEM, AFM, XPS and EDS. The results of AFM and contact angle test show that the modification of octadecyltrichlorosilane (OTS) monomolecular layer is achieved by UV-irradiation through a photomask, generating hydrophilic silanol areas and hydrophobic self-assembled monolayer (SAM) regions. XRD and XPS indicate that the films absorbed to the glass substrates are pure rhombohedrally distorted structure BiFeO3. In addition, SEM and EDS are employed to confirm that no continuous BiFeO3 particles deposited on SAM regions could be easily peeled off by ultrasonication, while a uniform and clear patterned film with good adherence is site-selectively formed in the hydrophilic silanol regions.

Key words: photolithography-self-assembly, BiFeO3 films, micro-patterns

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