Study on Isothermal Crystallization Kinetics of Mica Glass Ceramics

Abstract

Abstract: The isothermal crystallization kinetics of mica-containing glass ceramics with addition of TiO2 asnucleation agent was investigated by XRD, SEM and DTA. Two distinct crystallization exotherm peaksin the DTA curve were observed and resolved corresponding to the initial formation of MgTi₂O₅,followed by the formation of KMg₃AlSi₃O₁₀F₂, confirmed by X-ray diffeaction analysis (XRD). By usingJohnson-Mehl-Avrami equation, the activation energics for precipitation of MgTi₂O₅ and mica crystalswere enaluated and the crystallization mechanism of mica was analyzed. The results indicated that the growth of KMg₃AlSi₃O₁₀F₂isa two-dimensional process, controlled by the crystal-glass in terface reaction. The average values of activation energies are 242kJ/mol and 265kJ/mol corresponding to that of MgTi₂O₅ and mica crystalized out of the glass, respectively.

Key words: mica, glass, crystalization, kinetics, phase separation, growth mechanism

CHENG Kangguo,WAN Julin,LIANG Kaiming. Study on Isothermal Crystallization Kinetics of Mica Glass Ceramics[J]. Journal of Inorganic Materials.

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