Tolerance Factor of ABO3-type Ilmenite Compound

doi:10.3724/SP.J.1077.2008.00881

Abstract

Abstract: The tolerance factor of ABO₃-type ilmenite by analyzing the ABO₃ilmenite crystal structure is established, and combining with the electronegativity difference, regularities governing the formation and the stability of ilmenite-type compounds are discussed. The tolerance factor equation is proved appropriate for ilmenite structure by analyzing the structure stability of some ilmenite compounds, such as MgTiO₃, NiTiO₃, CoTiO₃, ZnTiO₃ and (Zn_1-x, M_x)TiO₃(M denote Mg, Ni, Co). According to the results of statistical analyzing the tolerance factor and electronegativity difference of the present ABO₃-type ilmenite, the
experience tolerance factor value and experience electronegativity difference value to form stable ilmenite compound are obtained, that is, t>0.80 and e>1.465.

Key words: ilmenite, stability, tolerance factor, electronegativity difference, structure

CLC Number:

TM28
O78

LIU Xiang-Chun,GAO Feng,DENG Jun-Ping,TIAN Chang-Sheng. Tolerance Factor of ABO₃-type Ilmenite Compound[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2008.00881.

References

[1] Perkins J D, del Cueto J A, Alleman J L, et al. Thin Solid Films, 2002, 411 (1): 152--160.
[2] Wu X H, Wang Y D, Tian Z H, et al. Solid-State Electron., 2002, 46 (5): 715--719.
[3] Wu X H, Wang Y D, Liu H L, et al. Mater. Lett., 2002, 56 (5): 732--736.
[4] Yuan Z Y, Huang F, Sun J T, et al. Chem. Lett., 2002,31 (3): 408--409.
[5] Wang B, Chen S C, Greenblatt M. J. Solid State Chem., 1994, 108 (1): 184--188.
[6] Liu X C, Gao F, Zhao L L, et al. Journal of Alloys and Compounds, 2007, 436 (1-2): 285--289.
[7] Liu X C, Gao F, Zhao M, et al. Materials Science Forum, 2007, 546-549: 2215--2218.
[8] 孟范成. 武汉: 武汉理工大学硕士论文, 2003. 11--13.
[9] Wakiya N, Wang J, Saiki A. Journal of the European Ceramic Society, 1999, 19 (6-7): 1071--1075.
[10] Sohn J H, Inaguma Y, Yoon SO, et al. Jpn. J. Appl. Phys., 1994,33(9B): 5466--5470.
[11] 李标荣, 王筱珍, 张绪礼. 无机电介质. 武汉: 华中理工大学出版社, 1995.
[12] 张栋杰, 都有为. 压电与声光, 2002, 24 (5): 415--417.
[13] 陈刚, 廖理几. 晶体物理学基础. 北京: 科学出版社, 1992.
[14] Kim H T, Hwang J C, Nam J H, et al. J. Mater. Res., 2003, 18 (5): 1067--1072.
[15] Kim H T, Lanagan M T. J. Am. Ceram. Soc., 2003, 86 (11): 1874--1878.
[16] Liu X C, Gao F, Tian C S. Materials Research Bulletin, 2008, 43(3): 693--699.
[17] 刘向春, 高峰, 许冰, 等. 稀有金属材料与工程, 2007,36 (S3): 121--125.
[18] Chang Y S, Chang Y C, ChenI G, et al. Solid State Communications, 2003, 128 (5): 203--208.
[19] 罗君, 张梅, 邢献然, 等. 无机化学学报, 2006, 22 (4): 625--628.
[20] Kinomura N, Kumada N, Muto F. Mater. Res. Bull., 1984, 19 (3): 299--304. [21] Kumada N, Ozawa N, Kinomura N, et al. J. Solid. State. Chem., 1985, 57 (2): 267--268.
[22] Kumada N, Kinomura N, Sleight A W. Materials Research Bulletin, 2000,35 (14-15): 2397--2402.
[23] Shen Y S, Zhang T S. Sensors Actuators B, 1993, 12 (1): 5--9.
[24] Xu J, Liu Y, Niu X. Journal of the Chinese Ceramic Society, 2002,30 (3):321--324.
[25] 刘焕林, 吴兴惠. 功能材料, 1999,30 (5): 549--550.
[26] Wang C, Xu B. Journal of Solid State Chemistry, 2004, 177 (10):3448--3453.
[27] Kovacheva D, Petrov K. Solid State Ionics, 1998, 109 (3-4):327--332.
[28] Guo Y, Kakimoto K, Ohsato H. Applied Physics Letters, 2004, 85 (18): 4121--4123.
[29] Randall C A, Bhalla A S, Shrout T R, et al. J. Mater. Res., 1990, 5 (4): 829--834.

Tolerance Factor of ABO₃-type Ilmenite Compound

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