Investigation of Bond Properities in LiNbO3

Journal of Inorganic Materials

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Investigation of Bond Properities in LiNbO₃

GAO Fa-Ming

College of Materials Science and Chemical Engineering; Yanshan University; Qinhuangdao 066004; China

Received:2000-02-15 Revised:2000-03-06 Published:2001-01-20 Online:2001-01-20

Abstract

Abstract: By using the average bond-gap model, chemical bond properities of LiNbO₃ were studied. Calculated results showed that covalency of Nb-O bond was 0.2, and of Li-O bond 0.42. Racah parameter of Cr³⁺ ion and Mossbauer isomer shifts of Fe²⁺ ion in LiNbO₃ were calculated by using the chemical surrounding factor, h, definited by covalency and electronic polarizability,and the results agreed with the experimental values.

Key words: LiNbO₃, chemical bond, racah parameters, mossbauer isomer shifts

CLC Number:

O723

GAO Fa-Ming. Investigation of Bond Properities in LiNbO₃[J]. Journal of Inorganic Materials.

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Investigation of Bond Properities in LiNbO₃

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