Synthesis and Properties of LiV3O8 Nanomaterials as the Cathode Material for Li-ion Battery

doi:10.3724/SP.J.1077.2007.00447

Journal of Inorganic Materials

• Research Paper • Previous Articles Next Articles

Synthesis and Properties of LiV₃O₈Nanomaterials as the Cathode Material for Li-ion Battery

YANG Hui¹, LI Juan ^1,2, ZHANG Jiao-Gang ^1,3, JIA Dian-Zeng ¹

1. Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, China; 2. School of Science, Xi’an Jiaotong University, Xi’an 710049, China; 3.College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Received:2006-06-12 Revised:2006-10-25 Published:2007-05-20 Online:2007-05-20

Abstract

Abstract: A novel technique was employed to preparing LiV₃O₈ in which LiOH·H₂O and NH₄VO₃ were used as the raw materials. The structure, morphology and properties of the sample were investigated by XRD, TGA/DTA, TEM, charge-discharge and CV. The results of XRD and TEM show that different calcining temperatures result in different structure and morphology, which lead to different discharge capacities. The specific discharge capacity of the sample calcined at 300℃ for 6h, in the range of 1.8--3.8V, is up to 342mAh/g in the first cycle. The capacity of the sampl is decreased with the increase of calcining temperatures.

Key words: lithium ion battery, nanomaterial, LiV3O8, electrochemical properties

CLC Number:

TM911

YANG Hui,LI Juan,ZHANG Jiao-Gang,JIA Dian-Zeng. Synthesis and Properties of LiV₃O₈Nanomaterials as the Cathode Material for Li-ion Battery[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2007.00447.

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Synthesis and Properties of LiV₃O₈Nanomaterials as the Cathode Material for Li-ion Battery

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