锂离子电池正极材料LiNiO2存在的问题与解决办法

摘要/Abstract

摘要： 锂离子电池正极材料LiNiO₂存在合成困难、循环性能差和热稳定性差等问题.这些问题都与LiNiO₂本身的晶体结构有关.本文从LiNiO₂晶体结构入手,分析了产生这些问题的原因,并对解决这些问题的办法进行了简要的综述.现有研究资料表明,仅仅通过优化合成条件只能在一定程度上改善LiNiO₂的循环性能,要从根本解决LiNiO₂的存在问题,关键是通过掺杂改性稳定其晶体结构.

关键词: 锂离子电池, 正极材料, LiNiO₂, 存在问题, 解决办法

Abstract: As a cathode material for lithium ion batteries, LiNiO₂ has various drawbacks such as difficulty to be
synthesized, poor cycling performance and poor thermal stability, which are all related to its crystal structure. Stared from the crystal structure,
this paper analyzed the causes that result in these drawbacks and reviewed the improve ways briefly. It was shown that just optimizing the synthesis
conditions could only improve the cycling performance to a degree. In order to overcome these drawbacks thoroughly, the most important thing is to
stabilize the layered structure of LiNiO₂ by part substitution of suitable elements for nickel or/and oxygen.

Key words: lithium ion batteries, cathode, LiNiO_2, drawbacks, improve ways

中图分类号:

TM912

叶乃清,刘长久,沈上越. 锂离子电池正极材料LiNiO₂存在的问题与解决办法[J]. 无机材料学报.

YE Nai-Qing,LIU Chang-Jiu,SHEN Shang-Yue. Drawbacks and Improve Ways of LiNiO₂ as a Cathode Material for Lithium Ion Batteries[J]. Journal of Inorganic Materials.

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锂离子电池正极材料LiNiO₂存在的问题与解决办法

Drawbacks and Improve Ways of LiNiO₂ as a Cathode Material for Lithium Ion Batteries

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