TiB-Ti周期序构复合材料设计、制备及性能研究

doi:10.15541/jim20230557

无机材料学报 ›› 2024, Vol. 39 ›› Issue (6): 662-670.DOI: 10.15541/jim20230557

TiB-Ti周期序构复合材料设计、制备及性能研究

孙海洋(), 季伟(), 王为民, 傅正义()

武汉理工大学材料复合新技术国家重点实验室, 武汉 430070

收稿日期:2023-12-04 修回日期:2024-01-19 出版日期:2024-06-20 网络出版日期:2024-01-22
通讯作者: 傅正义, 教授. E-mail: zyfu@whut.edu.cn;
季伟, 研究员. E-mail: jiwei@whut.edu.cn
作者简介:孙海洋(1999-), 男, 硕士研究生. E-mail: sunhaiyang@whut.edu.cn
基金资助:
国家自然科学基金重点项目(92163208);国家自然科学基金优秀青年科学基金(52322207)

Design, Fabrication and Properties of Periodic Ordered Structural Composites with TiB-Ti Units

SUN Haiyang(), JI Wei(), WANG Weimin, FU Zhengyi()

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

Received:2023-12-04 Revised:2024-01-19 Published:2024-06-20 Online:2024-01-22
Contact: FU Zhengyi, professor. E-mail: zyfu@whut.edu.cn;
JI Wei, professor. E-mail: jiwei@whut.edu.cn
About author:SUN Haiyang (1999-), male, Master candidate. E-mail: sunhaiyang@whut.edu.cn
Supported by:
National Natural Science Foundation of China Key Program(92163208);National Natural Science Foundation of China(52322207)

摘要/Abstract

摘要：

高性能结构材料部件在航空航天、交通汽车、电子信息、冶金等领域具有重要的应用价值, 得到了广泛研究。增强结构材料部件整体性能的方法主要包括材料本征性能提升和结构复合设计优化, 但提高单一结构材料的本征力学性能的研究已接近极限。本研究旨在提出周期序构结构材料的理念, 并采用一体化烧结制备出整体性能更好的结构复合材料, 从而探索高性能结构复合材料发展的新范式。通过周期序构化的设计, 构建了兼具陶瓷高硬度和金属强韧性的TiB-Ti功能单元, 设计制备了不同周期序构模式的TiB-Ti高性能结构复合材料。在此基础上, 对这些结构进行了力学性能研究, 并通过分析其断裂模式来探究不同序构模式对材料整体性能的影响。结果表明, 周期序构化可以通过改变材料宏观断裂模式和应力分散特性来提高材料的整体性能。这一研究新范式对其他结构复合材料的结构设计和性能突破具有指导和借鉴意义。对周期序构模式的复杂化探索, 对周期序构结构材料的应用场景探索和其他性能测试研究也将是未来需要重点关注的问题。

关键词: 复合材料, 周期序构, 力学性能, 结构设计

Abstract:

High-performance structural material components are widely researched because of their curcial applications in aerospace, transportation and automotive, electronic information, metallurgy, and other fields. Traditional methods for enhancing the overall performance of structural material components mainly include improving intrinsic material properties and optimizing structural composite design. However, research on enhancing the intrinsic mechanical properties of single structural materials is reaching its limits. This study aims to explore a new paradigm for the development of high-performance structural composites by proposing the concept of periodic ordered structural materials and preparing the structural composites with improved overall properties through integrated sintering. The TiB-Ti functional unit with high hardness of ceramics and strong toughness of metal was structured through periodical sequencing, and high-performance TiB-Ti structural composites with different periodical sequencing modes were designed and prepared. On this basis, the mechanical properties of these structures were investigated, and their fracture modes were analyzed to understand how different ordering modes affect the overall properties of the materials. The results show that periodic ordered structure can improve the overall performance of materials by altering their macroscopic fracture modes and stress distribution properties. This new paradigm of research provides valuable insights and guidance for the structural design and performance breakthrough of other structural composites. Future research may focus on the exploration of the complexity of the periodic ordered structure modes, identifying potential application scenarios for these materials, and conducting additional performance testing studies.

Key words: composite material, periodic order, mechanical property, structural design

中图分类号:

TB333

孙海洋, 季伟, 王为民, 傅正义. TiB-Ti周期序构复合材料设计、制备及性能研究[J]. 无机材料学报, 2024, 39(6): 662-670.

SUN Haiyang, JI Wei, WANG Weimin, FU Zhengyi. Design, Fabrication and Properties of Periodic Ordered Structural Composites with TiB-Ti Units[J]. Journal of Inorganic Materials, 2024, 39(6): 662-670.

图/表 12

图1 原料的形貌和相组成

Fig. 1 Morphologies and phase compositions of raw materials (a, b) Microstructures of (a) Ti powder and (b) TiB2powder; (c) XRD patterns of Ti and TiB2powders

图2 TiB-Ti周期序构的结构示意图

Fig. 2 Structure diagrams of periodic ordered structural composites with TiB-Ti units

图3 六种周期序构复合材料的XRD图谱

Fig. 3 XRD patterns of periodic ordered structure composites

图4 SPS制备的TiB-Ti复合材料的断口微观形貌

Fig. 4 Fractural microstructures of TiB-Ti composites prepared by SPS (a) TiB fracture surface; (b) Ti fracture surface; (c) Two-phase interface fracture

图5 EPMA测试的TiB-Ti周期序构复合材料ababab截面上元素的分布图

Fig. 5 Distribution of elements on ababab section of TiB-Ti periodic ordered composite tested by EPMA (a) Sample selection photo; (b) Ti element distribution; (c) B element distribution; (d) Backscattered electron (BSE) image

图6 TiB-Ti复合材料界面的EDS面扫描分析

Fig. 6 EDS mappings of the TiB-Ti composite materials interface (a)SEM image; (b) Ti element; (c) B element

表1 TiB陶瓷和Ti金属材料的力学参数

Table1 Mechanical properties of TiB ceramic and Ti metal materials

Parameter	TiB	Ti
Density/(g·cm^-3)	4.56	4.50
E/GPa	370	110
K_IC/(MPa·m^1/2)	6.1	29.3
Bending strength/MPa	489.95	238.32
Compressive strength/MPa	1035.43	1596.26
Hardness/GPa	20.0	1.7

图7 六种TiB-Ti周期序构复合材料的力学性能

Fig. 7 Mechanical properties of six TiB-Ti periodic ordered composites (a) Bending strength stress-strain curves; (b) Bending strength line chart; (c) Compressive strength stress-strain curves; (d) Compressive strength line chart; Colorful figures are available on website

图8 六种TiB-Ti周期序构复合材料的三点抗弯试样宏观裂纹形貌(a~f)和压缩试样破坏形貌(a'~f')

Fig. 8 Macro-cracked morphologies (a-f) and fracture appearances (a'-f') of six TiB-Ti periodic ordered composite bending samples and compressed samples (a, a') aaabbb; (b, b') aabbab; (c, c') aababb; (d, d') abbaab; (e, e') abaabb; (f, f') ababab

图9 六种TiB-Ti周期序构复合材料的三点抗弯试样宏观断口形貌

Fig. 9 Macro fracture morphologies of six TiB-Ti periodic ordered composite bending samples (a) aaabbb; (b) aabbab; (c) aababb; (d) abbaab; (e) abaabb; (f) ababab

图10 TiB-Ti周期序构复合材料ababab结构的压缩试样宏观破坏形貌

Fig. 10 Macro fracture morphology of TiB-Ti periodic ordered composite sample with compressed ababab structure

图11 TiB-Ti周期序构复合材料的抗弯微观断口形貌(a, b)和压缩显微断口形貌(c, d)

Fig. 11 Microscopic fracture morphologies of TiB-Ti periodic ordered composite bending samples (a, b) and compressed samples (c, d) (a, c) TiB layer; (b, d) Ti layer

参考文献 27

[1]	OYA T, TIESLER N, KAWANISHI S, et al. Experimental and numerical analysis of multilayered steel sheets upon bending. Journal of Materials Processing Technology, 2010, 210(14): 1926.
[2]	GO Y H, CHO J, JEONG C Y, et al. Stress distribution of bulk metallic glass/metal laminate composites during uni-axial fracture. Materials Science and Engineering A, 2007, 460/461: 377.
[3]	AGHDAM M M, KAMALIKHAH A. Micromechanical analysis of layered systems of MMCs subjected to bending-effects of thermal residual stresses. Composite Structures, 2004, 66(1-4):563.
[4]	KUO, D H; KRIVEN, W M. Fracture of multilayer oxide composites. Materials Science and Engineering: A, 1998, 241(1):241.
[5]	LUO W, YAN S, ZHOU J. Ceramic-based dielectric metamaterials. Interdisciplinary Materials, 2022, 1(1):11.
[6]	LUO J. Computing grain boundary “phase” diagrams. Interdisciplinary Materials, 2023, 2(1):137.
[7]	EAST D, GIBSON M A, LIANG D, et al. Production and mechanical properties of roll bonded bulk metallic glass/aluminum laminates. Metallurgical and Materials Transaction A, 2013, 44(5): 2010.
[8]	CARREÑO F, CHAO J, POZUELO M, et al. Microstructure and fracture properties of an ultrahigh carbon steel-mild steel laminated composite. Scripta Materialia, 2003, 48(8):1135.
[9]	SYN C K, LESUER D R, SHERBY O D. Enhancing tensile ductility of a particulate-reinforced aluminum metal matrix composite by lamination with Mg-9%Li alloy. Materials Science and Engineering, 1996, 206(2):201.
[10]	OHASHI Y, WOLFENSTINE J, KOCH J, et al. Fracture behavior of a laminated steel-brass composite in bend tests. Materials Science and Engineering, 1992, 151(1):37.
[11]	SMITH D J, ZUO Y Q, PARTRIDGE P G, et al. Bend stiffness and strength of laminates composed of titanium alloy and titanium metal matrix composite. Materials Science and Technology, 1997, 13(1):35.
[12]	LIU B X, HUANG L J, GENG L, et al. Fabrication and superior ductility of laminated Ti-(TiB_w/Ti) composites by diffusion welding. Journal of Alloys and Compounds, 2014, 602: 187.
[13]	LIU B X, HUANG L J, GENG L, et al. Gradient grain distribution and enhanced properties of novel laminated TiTiB_w/Ti composites by reaction hot-pressing. Materials Science and Engineering: A, 2014, 595: 257.
[14]	LIU B X, HUANG LJ, GENG L, et al. Microstructure and tensile behavior of novel laminated Ti-TiB_w/Ti composites by reaction hot pressing. Materials Science and Engineering A, 2013, 583: 182.
[15]	GUPTA N, MUKHOPADHYAY A, PAVANI K, et al. Spark plasma sintering of novel ZrB₂-SiC-TiSi₂ composites with better mechanical properties. Materials Science and Engineering: A, 2012, 534: 111.
[16]	MALIK P, KADOLI R. Thermo-elastic response of SUS316-Al₂O₃ functionally graded beams under various heat loads. International Journal of Mechanical Sciences, 2017, 128: 206.
[17]	KHOA N D, THIEM H T, DUC N D. Nonlinear buckling and postbuckling of imperfect piezoelectric S-FGM circular cylindrical shells with metal-ceramic-metal layers in thermal environment using Reddy’s third-order shear deformation shell theory. Mechanics of Advanced Materials and Structures, 2019, 26(3):248.
[18]	FENG H B, JIA D C, ZHOU Y. Spark plasma sintering reaction synthesized TiB reinforced titanium matrix composites. Composites Part A: Applied Science and Manufacturing, 2005, 36(5):558.
[19]	神祥博, 张朝晖, 王富耻, 等. 放电等离子烧结法制备 TiB 陶瓷刀具材料的显微结构和力学性能. 模具制造, 2010, 10(12):92.
[20]	NAMBU S, MICHIUCHI M, INOUE J, et al. Effect of interfacial bonding strengthon tensile ductility of multilayered steel composites. Composites Science and Technology, 2009, 69(11/12): 1936.
[21]	WADGAONKAR S C, PARAMESWARAN V. Structure of near-tip stress field and variation of stress intensity factor for a crack in a transversely graded material. Journal of Applied Mechanics, 2009, 76(1):011014.
[22]	KIDANE A, ADDIS A. Quasi-static and dynamic fracture initiation toughness of Ti/TiB layered functionally graded material under thermo-mechanical loading. Engineering Fracture Mechanics, 2010, 77(3):479.
[23]	LIU B X, HUANG L J, GENG L, et al. Fracture behaviors and micro-structural failure mechanisms of laminated Ti-TiB_w/Ti composites. Material Science and Engineering: A, 2014; 611: 290.
[24]	HAN Y F, DUAN H Q, LU W J, et al. Fabrication and characterization of laminated Ti-(TiB+La₂O₃)/Ti composite. Progress in Natural Science: Materials International, 2015, 25(5):453.
[25]	LIU B X, HUANG L J, GENG L. Elastic and plastic behaviors of laminated Ti-TiB_w/Ti composites. Journal of Wuhan University of Technology-Mater. Sci. Ed., 2015, 30(3):596.
[26]	KOSEKI T, INOUE J, NAMBU S. Development of multilayer steels for improved combinations of high strength and high ductility. Materials Transactions, 2014, 55(2):227.
[27]	STEIF P S. Bimaterial interface instabilities in plastic solids. International Journal of Solids and Structures, 1986, 22(2):195.

TiB-Ti周期序构复合材料设计、制备及性能研究

Design, Fabrication and Properties of Periodic Ordered Structural Composites with TiB-Ti Units

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