大面积有机-无机杂化钙钛矿薄膜及其光伏应用研究进展

doi:10.15541/jim20230448

无机材料学报 ›› 2024, Vol. 39 ›› Issue (5): 457-466.DOI: 10.15541/jim20230448

• 综述 • 下一篇

大面积有机-无机杂化钙钛矿薄膜及其光伏应用研究进展

张慧¹^,²(), 许志鹏¹^,², 朱从潭¹^,², 郭学益¹^,², 杨英¹^,²()

1.中南大学冶金与环境学院, 长沙 410083
2.中南大学有色金属资源循环利用湖南省重点实验室, 长沙 410083

收稿日期:2023-09-28 修回日期:2023-12-15 出版日期:2024-05-20 网络出版日期:2024-01-08
通讯作者: 杨英, 教授. E-mail: muyicaoyang@csu.edu.cn
作者简介:张慧(2001-), 女, 硕士研究生. E-mail: 223512181@csu.edu.cn
基金资助:
国家重点研发计划(2023YFC3906103);湖南省自然科学基金面上项目(2022JJ30757);清远市创新创业科研团队项目(2018001)

Progress on Large-area Organic-inorganic Hybrid Perovskite Films and Its Photovoltaic Application

ZHANG Hui¹^,²(), XU Zhipeng¹^,², ZHU Congtan¹^,², GUO Xueyi¹^,², YANG Ying¹^,²()

1. School of Metallurgy and Environment, Central South University, Changsha 410083, China
2. Hunan Key Laboratory of Nonferrous Metal Resources Recycling, Central South University, Changsha 410083, China

Received:2023-09-28 Revised:2023-12-15 Published:2024-05-20 Online:2024-01-08
Contact: YANG Ying, professor. E-mail: muyicaoyang@csu.edu.cn
About author:ZHANG Hui (2001-), female, Master candidate. E-mail: 223512181@csu.edu.cn
Supported by:
National Key R&D Program of China(2023YFC3906103);Hunan Provincial Natural Science Foundation(2022JJ30757);Qingyuan Innovation and Entrepreneurship Research Team Program(2018001)

摘要/Abstract

摘要：

有机-无机杂化钙钛矿太阳能电池具有制备成本低、光电转换效率(Photoelectric Conversion Efficiency, PCE)高的巨大优势, 显示出广阔的商业化前景。经过十几年的深入研究, 钙钛矿太阳能电池(Perovskite Solar Cells, PSCs)的实验室器件(<1 cm²)、大面积器件(1~10 cm²)、迷你模组级器件(10~800 cm²)和模组级器件(>800 cm²)的最高认证PCE已分别提升至26.10%、24.35%、22.40%和18.60%。随着PSCs面积扩大, PCE急剧下降, 这主要是因为制备方法的局限性，难以获得高质量的大面积钙钛矿薄膜。实验室器件常采用的旋涂法难以应用到实际生产中, 目前大面积钙钛矿薄膜的制备方法主要有刮涂法和狭缝涂布法, 但其存在薄膜成核结晶过程难以精确控制等问题。本文从大面积有机-无机杂化钙钛矿薄膜的制备方法入手, 介绍了大面积钙钛矿层成膜机制及薄膜质量提升策略。最后, 对未来高PCE、高稳定性的大面积PSCs的制备技术和应用进行了展望, 旨在对高性能的大面积PSCs研究提供有益参考。

关键词: 钙钛矿薄膜, 钙钛矿太阳能电池, 大面积, 成膜控制, 综述

Abstract:

Recently, organic-inorganic hybrid perovskite solar cells have demonstrated a broad commercial prospect due to their high photoelectric conversion efficiency (PCE) and low fabricating costs. During the past decades, the highest reported PCE of small-area (<1 cm²) perovskite solar cells (PSCs) rose to 26.10%, and those of large-area (1-10 cm²), mini-module level (10-800 cm²) and module level (>800 cm²) PSCs increased to 24.35%, 22.40% and 18.60%, respectively. The performance of PSCs decreases dramatically with the area increasing due to limitation of the deposition method and the poor quality of large-area perovskite films. Spin-coating method is not suitable for actual industrial production, while the scalable deposition methods including blade-coating and slot-die coating still face the difficulty of precisely controlling nucleation and crystallization of the perovskite films with large area. This review summarized preparation methods of large-area perovskite films, and discussed the film-forming mechanism and strategies for high-quality perovskite films. Finally, relevant outlooks on technologies and applications for large-area PSCs with high performances and stabilities were analyzed. This review is expected to provide insights on the research of large-area PSCs with high performance.

Key words: perovskite film, perovskite solar cell, large area, film-forming control, review

中图分类号:

TQ174

张慧, 许志鹏, 朱从潭, 郭学益, 杨英. 大面积有机-无机杂化钙钛矿薄膜及其光伏应用研究进展[J]. 无机材料学报, 2024, 39(5): 457-466.

ZHANG Hui, XU Zhipeng, ZHU Congtan, GUO Xueyi, YANG Ying. Progress on Large-area Organic-inorganic Hybrid Perovskite Films and Its Photovoltaic Application[J]. Journal of Inorganic Materials, 2024, 39(5): 457-466.

图/表 6

图1 大面积PSCs的可扩展沉积方法示意图

Fig. 1 Scalable-deposition techniques of large-area PSCs (a) Blade-coating; (b) Slot-die coating; (c) Bar coating[21]; (d) Inkjet printing[22]; (e) Screen printing[23]; (f) Co-evaporation[24]; (g) Vacuum flash-assisted solution process (VASP)[26]

表1 不同大面积(≥1 cm2)钙钛矿层组成、沉积方法和相应PSCs的性能总结

Table 1 Summary of large area (≥1 cm2) perovskite layer composition, deposition techniques and corresponding PSCs performance

Perovskite layer composition	Deposition technique	V_OC/V	J_SC/(mA·cm^-2)	FF/%	PCE/%	Area/cm²	Ref.
FA_0.88Cs_0.12PbI₃	One-step blade-coating	1.00	21.21	72	15.30	205	[3]
MAPbI₃	One-step blade-coating	1.08	23.17	68	17.06	1	[16]
FAPbI₃	Two-step blade-coating	6.71	3.47	71	16.54	25	[17]
FAPbI₃	Two-step blade-coating	6.65	3.72	75	18.65	25	[18]
(FACs)Pb(IBr)	Vacuum evaporation+blade-coating	1.20 4.72	24.42 5.59	82 76	24.03 20.02	1 16	[19]
FA_0.15MA_0.85PbI₃	Screen printing	1.10	23.93	69	18.12	1	[23]
MAPbI₃	Co-evaporation	6.71	3.68	73	18.13	21	[24]
FA_0.81MA_0.15PbI_2.51Br_0.45	Two-step spin-coating+VASP	1.14	23.19	76	20.38	1	[26]
FA_0.995MA_0.005Pb(I_0.995Br_0.005)₃	Vacuum evaporation+spin-coating	1.18	24.55	77	22.26	1	[30]

图2 钙钛矿层的成膜机制

Fig. 2 Film-forming mechanism of perovskite layer (a) LaMer model for nucleation and growth of perovskite films[5]; (b) Relationship between volumetric and interfacial energy for the energy barrier to form a nucleus[28]; (c) Photographs and PCEs of PSCs from devices fabricated on test areas of the respective substrates (>100 cm2) (u0: speed of air knife)[29]; (d) J-V curves of perovskite crystal array (PCA) treated PSCs[30]

图3 钙钛矿材料ABX3的组分工程

Fig. 3 Composition engineering of perovskite material ABX3 (a) Schematic diagram of crystal structure of perovskite[32]; (b) J-V curves of solar modules based on W/O and W/Cs perovskite films[34]; (c) X-ray diffraction patterns of CsxFA1-xPbI1.8Br1.2 perovskite films[35]; (d) Roles of cations in the realized degradation routes[36] (IC: instability index); (e) Fill factor limitation comprises nonradiative loss (blue area) and transport loss (pink area)[39]; (f) J-V curves of 1.03 cm2 PSCs and 10.93 cm2 mini-module level PSCs with insets showing their pictures[39]; (g) Scanning electron microscopy (SEM) images of FACs perovskite films with different compositions[40]; (h) J-V curves of FACs perovskite solar cells with different compositions before and after light soaking[40]; (i) Pb4f high-resolution X-ray photoelectron spectra of perovskite films using PbI2 precursor films with light irradiation for 0-8 h[43]

图4 钙钛矿前驱液添加剂工程

Fig. 4 Additive engineering of perovskite precursor ink (a) SEM images of vapor deposited PbI2 (V-PbI2) with solution processed PbI2 (S-PbI2) as the control films, or solution processed NH4Cl-PbI2 films, and their corresponding perovskite films[60]; (b) J-V curve and picture of a large-area PSC (1.01 cm2) based on NpMAI (NpMA: 1-naphthalenemethylammounium) treated films[61]; (c) Digital images of two pieces of representative crown-FACsPbI3 films (16 and 100 cm2 area) [63]; (d) J-V curves for the champion sulfolane treated PSCs with 0.09, 0.16, and 1 cm2 working areas[64]; (e) J-V curves of a larger device (1 cm2) with perfluorobenzene (HFB)[65]; (f) PCE distributions of 10 independent PSCs with (target) and without (control) modification[66]; (g) J-V curve and photograph of a 5 cm×5 cm BTAI-MAPbI3 based perovskite solar module (PSM)[67]

表2 不同大面积(≥1 cm2)钙钛矿层组成、促进结晶的因素(溶剂体系和添加剂种类)和相应PSCs的性能总结

Table 2 Summary of large area (≥1 cm2) perovskite layer composition, factors influencing the crystallinity (solvent system and additive type) and performance of corresponding PSCs

Perovskite layer composition	Factor affecting perovskite crystallinity		V_OC/V	J_SC/(mA·cm^-2)	FF/%	PCE/%	Area/cm²	Ref.
FA_0.83Cs_0.17PbI₃	Solvent system	DMF/NMP	15.35	1.67	76	19.54	65	[45]
MA_0.6FA_0.4PbI₃		2-ME/DMSO/CBH	5.81 16.07	4.25 1.53	78 78	18.126 19.15	18 50	[46]
(FAPbI₃)_0.875(CsPbBr₃)_0.125		DMF/DMPU	6.69	3.70	72	17.71	10	[47]
(FAPbI₃)_0.95(CsPbBr₃)_0.05		DMF/DMPU	10.82	2.15	77	17.94	20	[48]
FA_0.83Cs_0.17PbI_2.83Br_0.17		DMF/NMP/DPSO	1.08	20.63	74	16.63	21	[49]
(FAPbI₃)_0.95(MAPbBr₃)_0.05		2-ME/DMI	15.46	1.71	76	20.15	81	[50]
(FAPbI₃)_0.95(MAPbBr₃)_0.05		2-ME/CHP	5.79 11.79	4.54 2.14	80 81	20.99 20.40	15 31	[51]
MAPbI₃		2-ME/DMSO	3.19	7.19	70	14.57	2	[52]
FAPbI₃		2-ME/ACN	8.36	3.06	67	17.10	13	[53]
MAPbI₃		2-ME/DMSO/ACN	18.90	1.17	76	16.90	64	[54]
FAPbI₃		DMF/DMSO/ACN	9.00	3.14	76	21.90	16	[55]
Cs_0.03(FA_0.97MA_0.03)_0.97Pb(I_0.97Br_0.03)₃		DMF/DMSO/EtOH	1.19 3.50	23.98 7.57	74 72	21.04 18.95	1 3	[57]
(FAMA)PbI₃	Type of additive	NH₄Cl^a	7.31	2.96	67	14.55	25	[60]
(FAMA)PbI₃		NpMAI^a	1.19	24.53	76	22.26	1	[61]
(FACs)PbI₃		Crown	5.63 14.29	4.17 1.67	71 58	16.69 13.84	16 100	[63]
MAPbI₃		Sulfolane	7.44	3.04	71	16.06	37	[64]
FAPbI₃		Hexaflorobenzene	1.21	25.2	80	25.12	1	[65]
FAPbI₃		NAMHI	6.61	3.85	79	20.10	10	[66]
MAPbI₃		BTAI	6.52	3.51	80	18.57	12	[67]
FA_0.9MA_0.03Cs_0.07Pb(I_0.92Br_0.08)₃		PMA-AA	11.54	2.37	80	21.95	14	[68]

参考文献 68

[1]	NREL. Best research-cell efficiency chart [2023-12-13]. https://www.nrel.gov/pv/cell-efficiency.html.
[2]	GREEN M A, DUNLOP E D, YOSHITA M, et al. Solar cell efficiency tables (version 62). Prog. Photovoltaics, 2023, 31(7): 651.
[3]	BU T L, ONO L K, LI J, et al. Modulating crystal growth of formamidinium-caesium perovskites for over 200 cm² photovoltaic sub-modules. Nat. Energy, 2022, 7(6): 528.
[4]	LIN H, YANG M, RU X N, et al. Silicon heterojunction solar cells with up to 26.81% efficiency achieved by electrically optimized nanocrystalline-silicon hole contact layers. Nat. Energy, 2023, 8(8): 789.
[5]	LEE J, LEE D, JEONG D, et al. Control of crystal growth toward scalable fabrication of perovskite solar cells. Adv. Funct. Mater., 2019, 29(47): 1807047.
[6]	关英翔. 大面积钙钛矿型太阳能电池及组件制作工艺. 北京: 北京信息科技大学硕士学位论文, 2015.
[7]	RONG Y G, HOU X M, HU Y, et al. Synergy of ammonium chloride and moisture on perovskite crystallization for efficient printable mesoscopic solar cells. Nat. Commun., 2017, 8: 14555. DOI PMID
[8]	PARIDA B, SINGH A, SOOPY A K K, et al. Recent developments in upscalable printing techniques for perovskite solar cells. Adv. Sci., 2022, 9(14): 220308.
[9]	丁建宁. 新型薄膜太阳能电池. 北京: 化学工业出版社, 2018: 81-82.
[10]	ZHANG H, ZHAO C X, YAO J X, et al. Dopant-free NiO_x nanocrystals: a low-cost and stable hole transport material for commercializing perovskite optoelectronics. Angew. Chem. Int. Ed., 2023, 62(24): e202219307.
[11]	LIU C, YANG Y, CHEN H, et al. Bimolecularly passivated interface enables efficient and stable inverted perovskite solar cells. Science, 2023, 382(6672): 810. DOI PMID
[12]	WU X, GAO D P, SUN X L, et al. Backbone engineering enables highly efficient polymer holetransporting materials for inverted perovskite solar cells. Adv. Mater., 2022, 35(12): 2208431.
[13]	CHEN Y, LIN P, CAI B, et al. Research progress of inorganic hole transport materials in perovskite solar cells. J. Inorg. Mater., 2023, 38(9): 991.
[14]	ZHU C T, GAO J, CHEN T, et al. Intrinsic thermal stability of inverted perovskite solar cells based on electrochemical deposited PEDOT. J. Energy Chem., 2023, 83: 445. DOI
[15]	PARK B W, KWON H W, LEE Y H, et al. Stabilization of formamidinium lead triiodide α-phase with isopropylammonium chloride for perovskite solar cells. Nat. Energy, 2021, 6(8): 419.
[16]	LI J B, MUNIR R, FAN Y Y, et al. Phase transition control for high-performance blade-coated perovskite solar cells. Joule, 2(7): 1313.
[17]	ZHANG J W, BU T L, LI J, et al. Two-step sequential blade-coating of high quality perovskite layers for efficient solar cells and modules. J. Mater. Chem. A, 2020, 8(17): 8447.
[18]	WEN Y T, LI J, GAO X F, et al. Two-step sequential blade-coating large-area FA-based perovskite thin film via a controlled PbI₂ microstructure. Acta Phys.-Chim. Sin., 2023, 32(2): 2203048.
[19]	TAN L G, ZHOU J J, ZHAO X, et al. Combined vacuum evaporation and solution process for high-efficiency large‐area perovskite solar cells with exceptional reproducibility. Adv. Mater., 2023, 35(3): 2205027.
[20]	杨志春, 吴狄, 剡晓波, 等. 大面积钙钛矿薄膜制备技术的研究进展. 材料导报, 2021, 35(1): 1046.
[21]	LI D Y, ZHANG D Y, LIM K S, et al. A review on scaling up perovskite solar cells. Adv. Funct. Mater., 2021, 31(12): 2008621.
[22]	CHEN Y J, WU H J, MA J J, et al. Droplet manipulation and crystallization regulation in inkjet-printed perovskite film formation. CCS Chem., 2022, 4(5): 1465.
[23]	CHEN C S, CHEN J X, HAN H C, et al. Perovskite solar cells based on screen-printed thin films. Nature, 2022, 612(7939): 266.
[24]	LI J, WANG H, CHIN X Y, et al. Highly efficient thermally co-evaporated perovskite solar cells and mini-modules. Joule, 2020, 4(5): 1035.
[25]	LEYDEN M R, JIANG Y, QI Y B, et al. Chemical vapor deposition grown formamidinium perovskite solar modules with high steady state power and thermal stability. J. Mater. Chem. A, 2016, 4(34): 13125.
[26]	LI X, BI D Q, YI C Y, et al. A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells. Science, 2016, 353(6294): 58. DOI PMID
[27]	SANCHEZ S, PFEIFER L, VACHOPOUOUS N, et al. Rapid hybrid perovskite film crystalization form solution. Chem. Sov. Rev., 2021, 50(12): 7108.
[28]	LIU C, CHENG Y B, GE Z Y. Understanding of perovskite crystal growth and film formation in scalable deposition processes. Chem. Sov. Rev., 2020, 49(6): 1653.
[29]	GEISTERT K, TERNES S, RITZER D B, et al. Controlling thin film morphology formation during gas quenching of slot-die coated perovskite solar modules. ACS Appl. Mater. Interfaces, 2023, 15(45): 52519.
[30]	SHEN Z C, HAN Q F, LUO X H, et al. Crystal-array-assisted growth of a perovskite absorption layer for efficient and stable solar cells. Energy Environ. Sci., 2022, 15(3): 1078.
[31]	DUNLAP-SHOHL W A, ZHOU Y Y, PADTURE N P, et al. Synthetic approaches for halide perovskite thin films. Chem. Rev., 2019, 119(5): 3193. DOI
[32]	ZHENG Z W, WANG S Y, HU Y, et al. Development of formamidinium lead iodide-based perovskite solar cells: efficiency and stability. Chem. Sci., 2022, 13(8): 2167.
[33]	MUSCARELLA L A, EHRLER B. The influence of strain on phase stability in mixed-halide perovskites. Joule, 2022, 6(9): 2016.
[34]	LIU X H, CHEN M, ZHANG Y, et al. High-efficiency perovskite photovoltaic modules achieved via cesium doping. Chem. Eng. J., 2022, 431(4): 133713.
[35]	XIAO K, LIN H Y, ZHANG M, et al. Scalable processing for realizing 21.7%-efficient all-perovskite tandem solar modules. Science, 2022, 376(6594): 762. DOI PMID
[36]	SUN S J, TIIHONEN A, OVIEDO F, et al. A data fusion approach to optimize compositional stability of halide perovskites. Matter, 2021, 4(4): 1305.
[37]	SALIBA M, MATSUI T, DOMANSKI K, et al. Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance. Science, 2016, 354(6309): 206. PMID
[38]	ZHAO Y, MA F, QU Z H, et al. Inactive (PbI₂)₂RbCl stabilizes perovskite films for efficient solar cells. Science, 2022, 377(6605): 531.
[39]	CHANG J H, FENG E M, LI H Y, et al. Crystallization and orientation modulation enable highly efficient doctor-bladed perovskite solar cells. Nano-Micro Letter, 2023, 15(issue): 164.
[40]	DENG Y H, XU S, CHEN S S, et al. Defect compensation in formamidinium-caesium perovskites for highly efficient solar mini- modules with improved photostability. Nat. Energy, 2021, 6(6): 633.
[41]	JACOBSSON T J, CORREA-BAEBA J P, NARAKI E H, et al. Unreacted PbI₂ as a double-edged sword for enhancing the performance of perovskite solar cells. J. Am. Chem. Soc., 2016, 138(32): 10331.
[42]	MACPHERSON S, DOHERTY T A S, WINCHESTAR A J, et al. Local nanoscale phase impurities are degradation sites in halide perovskite. Nature, 2022, 607(7918): 294.
[43]	LIANG J W, HU X Z, WANG C, et al. Origins and influences of metallic lead in perovskite solar cells. Joule, 6(4): 816.
[44]	CHAO L F, NIU T T, GAO W Y, et al. Solvent engineering of the precursor solution toward large-area production of perovskite solar cells. Adv. Mater., 2021, 33(14): 2005410.
[45]	BU T L, LI J, LI H Y, et al. Lead halide-templated crystallization of methylamine-free perovskite for efficient photovoltaic modules. Science, 2021, 372(6548): 1327. DOI PMID
[46]	CHEN S S, DAI X Z, XU S, et al. Stabilizing perovskite-substrate interfaces for high-performance perovskite modules. Science, 2021, 373(6557): 902. DOI PMID
[47]	LI H Y, BU T, LI J, et al. Ink engineering for blade coating FA-dominated perovskites in ambient air for efficient solar cells and modules. ACS Appl. Mater. Interfaces, 2021, 13(16): 18724.
[48]	LEE D K, LIM K S, LEE J W, et al. Scalable perovskite coating via anti-solvent-free Lewis acid-base adduct engineering for efficient perovskite solar modules. J. Mater. Chem. A, 2021, 9(5): 3018.
[49]	YANG Z C, ZHANG W J, WU S H, et al. Slot-die coating large-area formamidinium-cesium perovskite film for efficient and stable parallel solar module. Adv. Sci., 2021, 7(18): eabg3749.
[50]	CHUNG J, KIM S, LI Y, et al. Engineering perovskite precursor inks for scalable production of high-efficiency perovskite photovoltaic modules. Adv. Energy Mater., 2023, 13(22): 2300595.
[51]	YOO J W, JANG J H, KIM U, et al. Efficient perovskite solar mini-modules fabricated via bar-coating using 2-methoxyethanol- based formamidinium lead tri-iodide precursor solution. Joule, 2021, 5(9): 2420.
[52]	LI J Z, DAGAR J, SHARGAIEVA O, et al. 20.8% slot-die coated MAPbI₃ perovskite solar cells by optimal DMSO-content and age of 2-ME based precursor inks. Adv. Energy Mater., 2021, 11(10): 2003460.
[53]	LI J Z, DAGAR J, SHARGAIEVA O, et al. Ink design enabling slot-die coated perovskite solar cells with >22% power conversion efficiency, micro-modules, and 1 year of outdoor performance evaluation. Adv. Energy Mater., 2022, 13(33): 2203898.
[54]	DENG Y H, BRACKE C H V, DAI X Z, et al. Tailoring solvent coordination for high-speed, room-temperature blading of perovskite photovoltaic films. Sci. Adv., 2019, 5(12): eaax7537.
[55]	YUAN L H, CHEN X N, GUO X M, et al. Volatile perovskite precursor ink enables window printing of phase-pure FAPbI₃ perovskite solar cells and modules in ambient atmosphere. Angew. Chem. Int. Ed., 2024, 63(7): e202316954.
[56]	NOEL N K, HABISREYTINGER S N, WENGER B, et al. A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films. Energy Environ. Sci., 2016, 10(1): 145.
[57]	LIANG Q, LIU K, SUN M, et al. Manipulating crystallization kinetics in high-performance blade-coated perovskite solar cells via cosolvent-assisted phase transition. Adv. Mater., 2022, 34(16): 2200276.
[58]	ZHAI P, REN L X, LI S Q, et al. Light modulation strategy for highest-efficiency water-processed perovskite solar cells. Matter, 2022, 5(12): 4450.
[59]	WANG W, ZHOU J, TANG W. Passivation strategies of perovskite film defects for solar cells. J. Inorg. Mater., 2022, 37(2): 129. DOI
[60]	TONG G Q, SON D, ONO L K, et al. Scalable fabrication of >90 cm² perovskite solar modules with >1000 h operational stability based on the intermediate phase strategy. Adv. Energy Mater., 2021, 11(10): 2003712.
[61]	ZHOU T, XU Z Y, WANG R, et al. Crystal growth regulation of 2D/3D perovskite films for solar cells with both high efficiency and stability. Adv. Mater., 2022, 34(17): 2200705.
[62]	MING Y, HU Y, MEI A, et al. Application of lead acetate additive for printable perovskite solar cell. J. Inorg. Mater., 2022, 37(2): 197. DOI
[63]	CHEN R H, WU Y Z, WANG Y K, et al. Crown ether-assisted growth and scaling up of FACsPbI₃ films for efficient and stable perovskite solar modules. Adv. Funct. Mater., 2021, 31(11): 2008760.
[64]	HUANG H H, LIU Q H, TSAI H, et al. A simple one-step method with wide processing window for high-quality perovskite mini-module fabrication. Joule, 2021, 5(4): 958.
[65]	HUANG Z J, BAI Y, HUANG X D, et al. Anion-π interactions supress phase impurities in FAPbI₃ solar cells. Nature, 2023, 623(2023): 531.
[66]	MENG Y Y, WANG Y L, LIU C, et al. Epitaxial growth of α-FAPbI₃ at a well-matched heterointerface for efficient perovskite solar cells and solar modules. Adv. Mater., 2024, 36(6): 2309208.
[67]	MIAO Y, REN M, WANG H F, et al. Surface termination on unstable methylammonium-based perovskite using a steric barrier for improved perovskite solar cells. Angew. Chem. Int. Ed., 2023, 62(51): e202312726.
[68]	LIU D C, CHEN C, WANG X Z, et al. Enhanced quasi-Fermi level splitting of perovskite solar cells by universal dual-functional polymer. Adv. Mater., 2023, 36(13): 2310962.

大面积有机-无机杂化钙钛矿薄膜及其光伏应用研究进展

Progress on Large-area Organic-inorganic Hybrid Perovskite Films and Its Photovoltaic Application

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 68

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王伟明, 王为得, 粟毅, 马青松, 姚冬旭, 曾宇平. 以非氧化物为烧结助剂制备高导热氮化硅陶瓷的研究进展[J]. 无机材料学报, 2024, 39(6): 634-646.
[2]	蔡飞燕, 倪德伟, 董绍明. 高熵碳化物超高温陶瓷的研究进展[J]. 无机材料学报, 2024, 39(6): 591-608.
[3]	吴晓晨, 郑瑞晓, 李露, 马浩林, 赵培航, 马朝利. SiC_f/SiC陶瓷基复合材料高温环境损伤原位监测研究进展[J]. 无机材料学报, 2024, 39(6): 609-622.
[4]	赵日达, 汤素芳. 多孔碳陶瓷化改进反应熔渗法制备陶瓷基复合材料研究进展[J]. 无机材料学报, 2024, 39(6): 623-633.
[5]	方光武, 谢浩元, 张华军, 高希光, 宋迎东. CMC-EBC损伤耦合机理及一体化设计研究进展[J]. 无机材料学报, 2024, 39(6): 647-661.
[6]	张幸红, 王义铭, 程源, 董顺, 胡平. 超高温陶瓷复合材料研究进展[J]. 无机材料学报, 2024, 39(6): 571-590.
[7]	陈甜, 罗媛, 朱刘, 郭学益, 杨英. 有机-无机共添加增强柔性钙钛矿太阳能电池机械弯曲及环境稳定性能[J]. 无机材料学报, 2024, 39(5): 477-484.
[8]	李宗晓, 胡令祥, 王敬蕊, 诸葛飞. 氧化物神经元器件及其神经网络应用[J]. 无机材料学报, 2024, 39(4): 345-358.
[9]	于嫚, 高荣耀, 秦玉军, 艾希成. 上转换发光纳米材料对钙钛矿太阳能电池迟滞效应和离子迁移动力学的影响[J]. 无机材料学报, 2024, 39(4): 359-366.
[10]	鲍可, 李西军. 化学气相沉积法制备智能窗用热致变色VO₂薄膜的研究进展[J]. 无机材料学报, 2024, 39(3): 233-258.
[11]	胡梦菲, 黄丽萍, 李贺, 张国军, 吴厚政. 锂/钠离子电池硬碳负极材料的研究进展[J]. 无机材料学报, 2024, 39(1): 32-44.
[12]	柯鑫, 谢炳卿, 王忠, 张敬国, 王建伟, 李占荣, 贺会军, 汪礼敏. 第三代半导体互连材料与低温烧结纳米铜材的研究进展[J]. 无机材料学报, 2024, 39(1): 17-31.
[13]	董思吟, 帖舒婕, 袁瑞涵, 郑霄家. 低维卤化物钙钛矿直接型X射线探测器研究进展[J]. 无机材料学报, 2023, 38(9): 1017-1030.
[14]	韩旭, 姚恒大, 吕梅, 陆红波, 朱俊. 单分子液晶添加剂在甲脒铅碘钙钛矿太阳能电池中的应用[J]. 无机材料学报, 2023, 38(9): 1097-1102.
[15]	方万丽, 沈黎丽, 李海艳, 陈薪羽, 陈宗琦, 寿春晖, 赵斌, 杨松旺. NiO_x介孔层的成膜过程对碳电极钙钛矿太阳能电池性能的影响[J]. 无机材料学报, 2023, 38(9): 1103-1109.