颗粒级配对黏结剂喷射打印碳化硅陶瓷性能的影响

doi:10.15541/jim20230216

无机材料学报 ›› 2023, Vol. 38 ›› Issue (12): 1373-1378.DOI: 10.15541/jim20230216

所属专题：【制备方法】3D打印(202312)

• 研究论文 • 下一篇

颗粒级配对黏结剂喷射打印碳化硅陶瓷性能的影响

顾薛苏¹(), 殷杰¹(), 王康龙¹, 崔崇², 梅辉³, 陈忠明¹, 刘学建¹, 黄政仁¹^,⁴()

1.中国科学院上海硅酸盐研究所, 上海 200050
2.南京理工大学材料科学与工程学院, 南京 210094
3.西北工业大学材料学院, 西安 710072
4.中国科学院宁波材料技术与工程研究所, 宁波 315201

收稿日期:2023-05-05 修回日期:2023-06-16 出版日期:2023-06-28 网络出版日期:2023-06-28
通讯作者: 殷杰, 副研究员. E-mail: jieyin@mail.sic.ac.cn;
黄政仁, 研究员. E-mail: zhrhuang@mail.sic.ac.cn
作者简介:顾薛苏(1997-), 男, 硕士研究生. E-mail: guxs2022@163.com
基金资助:
国家自然科学基金(U22A20129);国家自然科学基金(52073299);国家自然科学基金(52172077);国家重点研发计划(2022YFB3706300)

Effect of Particle Grading on Properties of Silicon Carbide Ceramics by Binder Jetting Printing

GU Xuesu¹(), YIN Jie¹(), WANG Kanglong¹, CUI Chong², MEI Hui³, CHEN Zhongming¹, LIU Xuejian¹, HUANG Zhengren¹^,⁴()

1. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
2. School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
3. School of Materials, Northwestern Polytechnical University, Xi’an 710072, China
4. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Received:2023-05-05 Revised:2023-06-16 Published:2023-06-28 Online:2023-06-28
Contact: YIN Jie, associate professor. E-mail: jieyin@mail.sic.ac.cn;
HUANG Zhengren, professor. E-mail: zhrhuang@mail.sic.ac.cn
About author:GU Xuesu(1997-), male, Master candidate. E-mail: guxs2022@163.com
Supported by:
National Natural Science Foundation of China(U22A20129);National Natural Science Foundation of China(52073299);National Natural Science Foundation of China(52172077);National Key R&D Program of China(2022YFB3706300)

摘要/Abstract

摘要：

碳化硅(SiC)陶瓷作为一种高性能结构功能一体化的陶瓷材料, 在航空航天、核能工业和制动系统等领域应用广泛。然而, 传统的制造方法无法满足大尺寸复杂结构SiC陶瓷日益增长的市场需求, 例如发动机喷嘴、襟翼和涡轮叶片等。黏结剂喷射(BJ)3D打印突破了传统成型的约束, 可以提供新的制造思路。本工作采用颗粒级配SiC的思路, 基于级配理论优化较佳的颗粒度配比, 研究了BJ打印对级配前后SiC陶瓷素坯及烧结体性能的影响。研究发现, BJ打印级配后的SiC素坯经过一次前驱体浸渍裂解(PIP)处理, 能够快速制备抗弯强度最大达到(16.70± 0.53) MPa的SiC素坯, 相比采用20 μm中位径未级配的样品提高了116%。进一步采用液相渗硅制备了致密的SiC陶瓷, 其密度、抗弯强度、弹性模量和断裂韧性分别达到(2.655±0.001) g/cm³, (285±30) MPa, (243±12) GPa和(2.54±0.02) MPa·m^1/2。XRD分析表明, SiC烧结体主要以3C-β-SiC晶为主。本研究基于颗粒级配的原料, 采用黏结剂喷射打印, 结合一次浸渍裂解与液相渗硅制备工艺, 高效可靠地制备了高性能SiC陶瓷材料。

关键词: 碳化硅, 颗粒级配, 黏结剂喷射打印, 前驱体浸渍裂解

Abstract:

Silicon carbide (SiC) ceramics, as a high-performance structural-functional integrated material, are widely used in aerospace, nuclear industry and braking system. However, the conventional fabrication methods can not meet the increasing demands for large-scale and complex-structured SiC ceramics, such as engine nozzles, flaps and turbine blades. Binder jetting (BJ) 3D printing technology can overcome the traditional obstacle and provide a novel manufacturing roadmap. Here, we adopted this technique via SiC particle grading, optimized the particle size ratio based on gradation theory, and studied the influence of BJ printing on properties of SiC green body and as-sintered ceramic. For the particle-graded green body after BJ printing, SiC ceramics with a maximum flexural strength of (16.70±0.53) MPa was obtained after one precursor impregnation and pyrolysis (PIP) treatment, whose flexural strength was improved by 116% as compared with that BJ printed from a median diameter of 20 μm. SiC ceramics were further densified using liquid phase siliconization, with the density, flexural strength, elastic modulus, and fracture toughness reaching (2.655±0.001) g/cm³, (285±30) MPa, (243±12) GPa, and (2.54±0.02) MPa·m^1/2, respectively. XRD results demonstrated that the sintered SiC ceramics were mainly composed of 3C structured-β-SiC. All results show that high-performance SiC ceramic materials are innovatively prepared by an efficient and reliable method, based on the combined techniques of particle grading, BJ printing, PIP and liquid silicon infiltration.

Key words: silicon carbide, particle grading, binder jetting printing, precursor impregnation and pyrolysis

中图分类号:

TQ174

顾薛苏, 殷杰, 王康龙, 崔崇, 梅辉, 陈忠明, 刘学建, 黄政仁. 颗粒级配对黏结剂喷射打印碳化硅陶瓷性能的影响[J]. 无机材料学报, 2023, 38(12): 1373-1378.

GU Xuesu, YIN Jie, WANG Kanglong, CUI Chong, MEI Hui, CHEN Zhongming, LIU Xuejian, HUANG Zhengren. Effect of Particle Grading on Properties of Silicon Carbide Ceramics by Binder Jetting Printing[J]. Journal of Inorganic Materials, 2023, 38(12): 1373-1378.

图/表 9

表1 不同中位径SiC粉末的级配比例及流动性指数

Table 1 Mass ratios and flowability indexes of SiC powders with different median diameters

Group	Fraction	Carr index/%
G0	20 μm (non-grading)	37.11
G1	5 μm:10 μm:20 μm:50 μm:80 μm =5:6:15:5:5	27.80
G2	5 μm:10 μm:20 μm:50 μm:80 μm =6:6:15:5:4	30.05
G3	5 μm:10 μm:20 μm:50 μm:80 μm =6:5:15:4:6	34.94

图1 BJ打印制备SiC陶瓷的工艺流程

Fig. 1 Flow chart of SiC ceramics by BJ process

表2 BJ打印素坯在PIP处理前后的体积密度和开气孔率

Table 2 Bulk densities and open porosities of BJ-printed SiC green body before and after PIP treatment

Group	Bulk density/(g•cm^-3)		Open porosity/%
Group	Before PIP	After PIP	Before PIP	After PIP
G0	1.236±0.008	1.533±0.005	61.12±0.47	47.48±0.84
G1	1.470±0.006	1.718±0.009	53.19±0.46	40.63±0.57
G2	1.313±0.007	1.598±0.003	59.72±0.20	46.44±0.63
G3	1.284±0.004	1.572±0.007	59.04±0.13	45.85±0.77

图2 BJ打印素坯经一次PIP后的抗弯强度

Fig. 2 Flexual strength of BJ-printed green body after one PIP

图3 PIP后素坯的断口形貌(a~d)以及PIP后素坯的孔径分布(e)

Fig. 3 Fracture morphologies (a-d), and pore size distributions (e) of green bodies after PIP (a) G0; (b) G1; (c) G2; (d) G3

图4 BJ打印SiC陶瓷的体积密度和开孔率

Fig. 4 Bulk densities and open porosities of BJ-printed SiC ceramics

图5 BJ打印SiC陶瓷的力学性能

Fig. 5 Mechanical properties of BJ-printed SiC ceramics (a) Flexural strength; (b) Elastic modulus; (c) Fracture toughness

图6 BJ打印SiC陶瓷的抛光面形貌

Fig. 6 Polished surface morphologies of BJ-printed SiC ceramics (a) G0; (b) G1; (c) G2; (d) G3

图7 BJ打印SiC陶瓷的XRD图谱

Fig. 7 XRD patterns of BJ-printed SiC ceramics

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颗粒级配对黏结剂喷射打印碳化硅陶瓷性能的影响

Effect of Particle Grading on Properties of Silicon Carbide Ceramics by Binder Jetting Printing

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