Cs2AgBiBr6钙钛矿太阳能电池研究进展

doi:10.15541/jim20230049

无机材料学报 ›› 2023, Vol. 38 ›› Issue (9): 1044-1054.DOI: 10.15541/jim20230049

所属专题：【能源环境】钙钛矿(202310)；【能源环境】太阳能电池(202310)

Cs₂AgBiBr₆钙钛矿太阳能电池研究进展

张伦(), 吕梅, 朱俊()

合肥工业大学仪器科学与光电工程学院, 测量理论与精密仪器安徽省重点实验室, 合肥 230009

收稿日期:2023-01-31 修回日期:2023-04-28 出版日期:2023-09-20 网络出版日期:2023-06-02
通讯作者: 朱俊, 教授. E-mail: jzhu@hfut.edu.cn
作者简介:张伦(1992-), 男, 博士研究生. E-mail: zhanglunme@163.com
基金资助:
国家重点研发计划(2019YFE0101300);中央高校基本科研专项资金(JZ2022HGTA0327);中央高校基本科研专项资金(JZ2021HGQA0264)

Research Progress of Cs₂AgBiBr₆ Perovskite Solar Cell

ZHANG Lun(), LYU Mei, ZHU Jun()

Anhui Province Key Laboratory of Measuring Theory and Precision Instrument, School of Instrument Science and Optoelectronics Engineering, Hefei University of Technology, Hefei 230009, China

Received:2023-01-31 Revised:2023-04-28 Published:2023-09-20 Online:2023-06-02
Contact: ZHU Jun, professor. E-mail: jzhu@hfut.edu.cn
About author:ZHANG Lun (1992-), male, PhD candidate. E-mail: zhanglunme@163.com
Supported by:
National Key R&D Program of China(2019YFE0101300);Fundamental Research Funds for the Central Universities(JZ2022HGTA0327);Fundamental Research Funds for the Central Universities(JZ2021HGQA0264)

摘要/Abstract

摘要：

近年来, 有机-无机杂化钙钛矿太阳能电池以其优异的性能和低廉的制造成本受到了广泛关注。然而, 其含有铅元素的毒性以及稳定性阻碍了进一步商业化应用。双钙钛矿材料Cs₂AgBiBr₆具有稳定性优异、毒性低、载流子寿命长和载流子有效质量小的优势, 是一种颇具潜力的光伏材料, 已被应用于太阳能电池并展现出良好的性能。但是Cs₂AgBiBr₆钙钛矿太阳能电池的光电转换效率还无法与有机-无机杂化钙钛矿太阳能电池相媲美, 发展仍面临诸多挑战。本文首先介绍了Cs₂AgBiBr₆的晶体结构及容忍因子等结构参数; 然后介绍了溶液法、反溶剂辅助成膜法、气相法、真空辅助成膜法以及喷涂法等薄膜制备工艺的进展, 评述了各种薄膜制备工艺的优缺点; 接着从元素掺杂、添加剂工程及界面工程(界面能级匹配和界面缺陷钝化)三方面介绍了Cs₂AgBiBr₆钙钛矿太阳能电池的性能优化策略, 结合近年来的研究进展进行了评述; 最后指出Cs₂AgBiBr₆钙钛矿太阳能电池面临的挑战, 并从前驱体溶剂工程、带隙工程以及器件降解机理三方面展望了未来研究方向。

关键词: Cs₂AgBiBr₆, 太阳能电池, 光电转换效率, 双钙钛矿, 综述

Abstract:

In recent years, organic-inorganic hybrid perovskite solar cells have received a lot of attention for their excellent performance and low manufacturing cost. However, the toxicity of lead in organic-inorganic hybrid perovskite solar cells and instability inhibits its further commercialization. Double perovskite Cs₂AgBiBr₆ possess excellent stability, low toxicity, long carrier lifetime, and small effective carrier mass, and is considered as a promising photovoltaic material. It has been applied in solar cells and displayed superior performance. However, the power conversion efficiency of Cs₂AgBiBr₆ perovskite solar cell still lags behind organic-inorganic hybrid perovskite solar cells, and its development faces various challenges. This review firstly introduces the crystal structure and the structural parameters such as tolerance factor of Cs₂AgBiBr₆. And then, the progress of thin film preparation technologies such as solution processing method, anti-solvent assisted film forming method, vapor deposition processing method, vacuum-assisted film forming method, spray-coating method are summarized, and the advantages and disadvantages of various preparation technologies are discussed. The performance optimization strategies of Cs₂AgBiBr₆ perovskite solar cells are analyzed from three aspects: element doping, additive engineering, and interface engineering (interface energy level matching and interface defect passivation), and the research progress in recent years is reviewed. Finally, the challenges faced by Cs₂AgBiBr₆ perovskite solar cells are pointed out, and future research directions are prospected from three aspects: precursor solvent engineering, bandgap engineering, and device degradation mechanism.

Key words: Cs₂AgBiBr₆, solar cell, power conversion efficiency, double perovskites, review

中图分类号:

TM914

张伦, 吕梅, 朱俊. Cs₂AgBiBr₆钙钛矿太阳能电池研究进展[J]. 无机材料学报, 2023, 38(9): 1044-1054.

ZHANG Lun, LYU Mei, ZHU Jun. Research Progress of Cs₂AgBiBr₆ Perovskite Solar Cell[J]. Journal of Inorganic Materials, 2023, 38(9): 1044-1054.

图/表 8

图1 (a)钙钛矿ABX3和(b)双钙钛矿A2B+B3+X6晶体结构示意图[30]

Fig. 1 (a) Crystal structure diagrams of perovskite ABX3 and (b) double perovskite A2B+B3+X6[30]

图2 公式(3)中τ的取值范围[32]

Fig. 2 Value range of τ in Eq. (3)[32]

图3 Cs2AgBiBr6薄膜的制备工艺

Fig. 3 Fabrication processes of Cs2AgBiBr6 films (a) Solution processing method[19]; (b) Anti-solvent assisted film forming method[8]; (c) Vapor deposition processing method[35]; (d) Vacuum-assisted film forming method[37]; (e) Spray-coating method[38]

图4 采用(a) DMSO和(b) DMSO+DMF作为前驱溶剂沉积的Cs2AgBiBr6膜的SEM照片[34]; (c)气相法和(d)溶液法制备的Cs2AgBiBr6薄膜的SEM照片[36]

Fig. 4 SEM images of Cs2AgBiBr6 films deposited using (a) DMSO and (b) DMSO+DMF as precursor solvents[34] and prepared by (c) vapor deposition and (d) solution processing[36]

图5 离子掺杂优化Cs2AgBiBr6钙钛矿太阳能电池

Fig. 5 Ion doped Cs2AgBiBr6 perovskite solar cells (a) SEM images of Cs2AgBiBr6, Cs1.99Li0.01AgBiBr6(Cs), Cs1.99Na0.01AgBiBr6(Cs-Li), Cs1.99K0.01AgBiBr6(Cs-Na), and Cs1.99Rb0.01AgBiBr6(Cs-K) films; (b) J-V curves of Cs2AgBiBr6 perovskite solar cells (w/o: Cs2AgBiBr6, w Li+: Cs1.99Li0.01AgBiBr6, w Na+: Cs1.99Na0.01AgBiBr6, w K+: Cs1.99K0.01AgBiBr6, w Rb+: Cs1.99Rb0.01AgBiBr6)[54]; (c) Band structure diagram for Cs2AgBiBr6[57]; (d) Tauc plots of Cs2AgSbxBi1-xBr6 (x=0, 0.25, 0.50, 0.75) films[58]; (e) Crystal structure diagram of Cs2AgBiBr6-2xSx; (f) UV-Vis absorption spectra with inset showing corresponding Tauc plots (right) of Cs2AgBiBr6-2xSx film[60]. Colorful figures are available on website

图6 添加剂工程优化Cs2AgBiBr6薄膜

Fig. 6 Additive engineering optimization of Cs2AgBiBr6 films (a) Schematic illustration of MABr additive assisted Cs2AgBiBr6 crystallization process; (b) SEM images of Cs2AgBiBr6 films prepared (left) without and (right) with MABr[66]; (c) Schematic diagram of the mechanism of additive GuaSCN in the formation process of Cs2AgBiBr6 film; (d) SEM images of Cs2AgBiBr6 films prepared (left) without and (right) with GuaSCN [67]; (e) Schematic illustration of BMPyr+-Br- interaction between ionic liquid BMPyrCl and Cs2AgBiBr6 perovskite; (f) SEM images of Cs2AgBiBr6 films prepared (left) without and (right) with BMPyrCl[70]. Colorful figures are available on website

图7 Cs2AgBiBr6钙钛矿太阳能电池界面能级匹配示意图

Fig. 7 Schematic diagrams of the interface energy level alignments in Cs2AgBiBr6 solar cells (a) Cu2O[71] and (b) HTL-1, HTL-2 or HTL-3[72] as hole transport layers; (c) C60/TiO2 as electron transport layers[73]

图8 Cs2AgBiBr6钙钛矿太阳能电池界面缺陷钝化示意图

Fig. 8 Schematic diagrams of interface defect passivation in Cs2AgBiBr6 solar cells (a) PMMA[74], (b) Y-6[75] and (c) N719[76] passivating Cs2AgBiBr6/HTL interfaces; (d) MXene passivating Cs2AgBiBr6/ETL interface[77]. Colorful figures are available on website

参考文献 78

[1]	KOMIJA A, TESHIMA K, SHIRAI Y, et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. Journal of the American Chemical Society, 2009, 131(17): 6050. DOI PMID
[2]	NREL. Best research-cell efficiency chart. [2023-04-05]. https://www.nrel.gov/pv/cell-efficiency.html.
[3]	ZHAO J, WEI L, JIA C, et al. Metallic tin substitution of organic lead perovskite films for efficient solar cells. Journal of Materials Chemistry A, 2018, 6(41): 20224. DOI URL
[4]	LIU D, YIN Y X, LIU F J, et al. Thickness-dependent highly sensitive photodetection behavior of lead-free all-inorganic CsSnBr₃ nanoplates. Rare Metals, 2022, 41(5): 1753. DOI
[5]	HU W, HE X, FANG Z, et al. Bulk heterojunction gifts bismuth- based lead-free perovskite solar cells with record efficiency. Nano Energy, 2020, 68: 104362. DOI URL
[6]	JIA Q, LI C, TIAN W, et al. Large-grained all-inorganic bismuth- based perovskites with narrow band gap via Lewis acid-base adduct approach. ACS Applied Materials & Interfaces, 2020, 12(39): 43876.
[7]	MA Z, SHI Z, YANG D, et al. Electrically-driven violet light-emitting devices based on highly stable lead-free perovskite Cs₃Sb₂Br₉ quantum dots. ACS Energy Letters, 2020, 5(2): 385. DOI URL
[8]	GAO W, RAN W, XI J, et al. High-quality Cs₂AgBiBr₆ double perovskite film for lead-free inverted planar heterojunction solar cells with 2.2% efficiency. ChemPhysChem, 2018, 19(14): 1696. DOI URL
[9]	顾津宇, 齐朋伟, 彭扬, 等. 无机非铅钙钛矿太阳能电池研究进展. 物理化学学报, 2017, 33(7): 1379.
[10]	JIANG X, LI H, ZHOU Q, et al. One-step synthesis of SnI₂·(DMSO)_x adducts for high-performance tin perovskite solar cells. Journal of the American Chemical Society, 2021, 143(29): 10970. DOI URL
[11]	ZHOU J, HAO M, ZHANG Y, et al. Chemo-thermal surface dedoping for high-performance tin perovskite solar cells. Matter, 2022, 5(2): 683. DOI URL
[12]	YU B B, CHEN Z, ZHU Y, et al. Heterogeneous 2D/3D tin-halides perovskite solar cells with certified conversion efficiency breaking 14%. Advanced Materials, 2021, 33(36): 2102055. DOI URL
[13]	SLAVNEY A H, HU T, LINDENBERG A M, et al. A bismuth- halide double perovskite with long carrier recombination lifetime for photovoltaic applications. Journal of the American Chemical Society, 2016, 138(7): 2138. DOI URL
[14]	PAN W, WU H, LUO J, et al. Cs₂AgBiBr₆ single-crystal X-ray detectors with a low detection limit. Nature Photonics, 2017, 11(11): 726. DOI URL
[15]	FENG H J, DENG W, YANG K, et al. Double perovskite Cs₂BBiX₆ (B=Ag, Cu; X=Br, Cl)/TiO₂ heterojunction: an efficient Pb-free perovskite interface for charge extraction. The Journal of Physical Chemistry C, 2017, 121(8): 4471. DOI URL
[16]	LI Y J, WU T, SUN L, et al. Lead-free and stable antimony- silver-halide double perovskite (CH₃NH₃)₂AgSbI₆. RSC Advances, 2017, 7(56): 35175. DOI URL
[17]	IGBARI F, WANG Z K, LIAO L S. Progress of lead-free halide double perovskites. Advanced Energy Materials, 2019, 9(12): 1803150. DOI URL
[18]	BARTEL C J, CLARY J M, SUTTON C, et al. Inorganic halide double perovskites with optoelectronic properties modulated by sublattice mixing. Journal of the American Chemical Society, 2020, 142(11): 5135. DOI PMID
[19]	NING W, GAO F. Structural and functional diversity in lead-free halide perovskite materials. Advanced Materials, 2019, 31(22): 1900326. DOI URL
[20]	PECUNIA V, OCCHIPINTI L G, Chakraborty A, et al. Lead-free halide perovskite photovoltaics: challenges, open questions, and opportunities. APL Materials, 2020, 8(10): 100901. DOI URL
[21]	GREUL E, PETRUS M L, BINEK A, et al. Highly stable, phase pure Cs₂ABiBr₆ double perovskite thin films for optoelectronic applications. Journal of Materials Chemistry A, 2017, 5(37): 19972. DOI URL
[22]	ZHANG Z, SUN Q, LU Y, et al. Hydrogenated Cs₂AgBiBr₆ for significantly improved efficiency of lead-free inorganic double perovskite solar cell. Nature Communications, 2022, 13: 3397. DOI
[23]	ZHAO Y, MA F, QU Z, et al. Inactive (PbI₂)₂RbCl stabilizes perovskite films for efficient solar cells. Science, 2022, 377(6605): 531. DOI URL
[24]	JEONG S, SEO S, YANG H, et al. Cyclohexylammonium-based 2D/3D perovskite heterojunction with funnel-like energy band alignment for efficient solar cells (23.91%). Advanced Energy Materials, 2021, 11(42): 2102236. DOI URL
[25]	MIN H, KIM M, LEE S, et al. Efficient, stable solar cells by using inherent bandgap of α-phase formamidinium lead iodide. Science, 2019, 366(6466): 749. DOI URL
[26]	XIAO K, LIN R, HAN Q, et al. All-perovskite tandem solar cells with 24.2% certified efficiency and area over 1 cm² using surface- anchoring zwitterionic antioxidant. Nature Energy, 2020, 5(1): 870. DOI
[27]	TRESS W, SIRTL M T. Cs₂AgBiBr₆ double perovskites as lead-free alternatives for perovskite solar cells. Solar RRL, 2022, 6(2): 2100770. DOI URL
[28]	SAVORY C N, WALSH A, SCANLON D O, et al. Can Pb-free halide double perovskites support high-efficiency solar cells. ACS Energy Letters, 2016, 1(5): 949. DOI URL
[29]	YADAV S C, SRIVASTAVA A, MANJUNATH V, et al. Properties, performance and multidimensional applications of stable lead-free Cs₂AgBiBr₆ double perovskite. Materials Today Physics, 2022, 26: 100731. DOI URL
[30]	KUNG P K, LI M H, LIN P Y, et al. Lead-free double perovskites for perovskite solar cells. Solar RRL, 2020, 4(2): 1900306. DOI URL
[31]	LI C, LU X, DING W, et al. Formability of ABX₃ (X=F, Cl, Br, I) halide perovskites. Acta Crystallographica Section B: Structural Science, 2008, 64(6): 702. DOI URL
[32]	BARTEL C J, SUTTON C, GOLDSMITH B P, et al. New tolerance factor to predict the stability of perovskite oxides and halides. Science Advances, 2019, 5(2): eaav0693. DOI URL
[33]	SU J, MOU T, WEN J, et al. First-principles study on the structure, electronic, and optical properties of Cs₂AgBiBr_6-_xCl_x mixed-halide double perovskites. The Journal of Physical Chemistry C, 2020, 124(9): 5371. DOI URL
[34]	ZHAO D, WANG B, LIANG C, et al. Facile deposition of high-quality Cs₂AgBiBr₆ films for efficient double perovskite solar cells. Science China Materials, 2020, 63(8): 1518. DOI
[35]	WANG M, ZENG P, BAI S, et al. High-quality sequential- vapor-deposited Cs₂AgBiBr₆ thin films for lead-free perovskite solar cells. Solar RRL, 2018, 2(12): 1800217. DOI URL
[36]	IGBARI F, WANG R, WANG Z K, et al. Composition stoichiometry of Cs₂AgBiBr₆ films for highly efficient lead-free perovskite solar cells. Nano Letters, 2019, 19(3): 2066. DOI URL
[37]	WU C, ZHANG Q, LIU Y, et al. The dawn of lead-free perovskite solar cell: highly stable double perovskite Cs₂AgBiBr₆ film. Advanced Science, 2018, 5(3): 1700759. DOI URL
[38]	DAEM N, DEWALQUE J, LANG F, et al. Spray-coated lead-free Cs₂AgBiBr₆ double perovskite solar cells with high open-circuit voltage. Solar RRL, 2021, 5(9): 2100422. DOI URL
[39]	REN Y, DUAN B, XU Y, et al. New insight into solvent engineering technology from evolution of intermediates via one-step spin-coating approach. Science China Materials, 2017, 60(17): 392. DOI URL
[40]	TODOROV T, MITZI D B. Direct liquid coating of chalcopyrite light-asorbing layers for photovoltaic devices. European Journal of Inorganic Chemistry, 2010, 2010(1): 17. DOI URL
[41]	YANG J, BAO C, NING W, et al. Stable, high-sensitivity and fast-response photodetectors based on lead-free Cs₂AgBiBr₆ double perovskite films. Advanced Optical Materials, 2019, 7(13): 1801732.
[42]	DUAN J, YANG Y, TANG J, et al. MACl enhanced electron extraction in all-inorganic Cs₂AgBiBr₆perovskite photovoltaics. Chemical Communications, 2023, 59(9): 1173. DOI URL
[43]	PANTALER M, CHO K T, QUELOZ V I E, et al. Hysteresis-free lead-free double-perovskite solar cells by interface engineering. ACS Energy Letters, 2018, 3(8): 1781. DOI URL
[44]	NING W, WANG F, WU B, et al. Long electron-hole diffusion length in high-quality lead-free double perovskite films. Advanced Materials, 2018, 30(20): 1706246. DOI URL
[45]	THANH N T K, MACLEAN N, MAHIDDINE S. Mechanisms of nucleation and growth of nanoparticles in solution. Chemical Reviews, 2014, 114(15): 7610. DOI PMID
[46]	DUNLAP-SHOHL W A, ZHOU Y, PADTURE N P, et al. Synthetic approaches for halide perovskite thin films. Chemical Reviews, 2018, 119(5): 3193. DOI URL
[47]	JUNG M, JI S G, KIM G, et al. Perovskite precursor solution chemistry: from fundamentals to photovoltaic applications. Chemical Society Reviews, 2019, 48(7): 2011. DOI PMID
[48]	DING B, GAO L, LIANG L, et al. Facile and scalable fabrication of highly efficient lead iodide perovskite thin-film solar cells in air using gas pump method. ACS Applied Materials & Interfaces, 2016, 8(31): 20067.
[49]	BISHOP J E, READ C D, SMITH J A, et al. Fully spray-coated triple-cation perovskite solar cells. Scientific Reports, 2020, 10(1): 6610. DOI PMID
[50]	TURREN-CRUZ S H, HAGFELDT A, SALIBA M. Methylammonium-free, high-performance, and stable perovskite solar cells on a planar architecture. Science, 2018, 362(6413): 449. DOI URL
[51]	UCHIDA R, BINET S, ARORA N, et al. Insights about the absence of Rb cation from the 3D perovskite lattice: effect on the structural, morphological, and photophysical properties and photovoltaic performance. Small, 2018, 14(36): 1802033. DOI URL
[52]	YI C, LUO J, MELONI S, et al. Entropic stabilization of mixed A-cation ABX₃ metal halide perovskites for high performance perovskite solar cells. Energy & Environmental Science, 2016, 9(2): 656.
[53]	ZHANG Z, WU C, WANG D, et al. Improvement of Cs₂AgBiBr₆ double perovskite solar cell by rubidium doping. Organic Electronics, 2019, 74: 204. DOI URL
[54]	LI J, DUAN J, DU J, et al. Alkali metal ion-regulated lead-free, all-inorganic double perovskites for HTM-free, carbon-based solar cells. ACS Applied Materials & Interfaces, 2020, 12(42): 47408.
[55]	MCCLURE E T, BALL M R, WINDL W, et al. Cs₂AgBiX₆ (X = Br, Cl): new visible light absorbing, lead-free halide perovskite semiconductors. Chemistry of Materials, 2016, 28(5): 1348. DOI URL
[56]	FILIP M R, HILLMAN S, HAGHIGHIRAD A A, et al. Band gaps of the lead-free halide double perovskites Cs₂BiAgCl₆and Cs₂BiAgBr₆ from theory and experiment. The Journal of Physical Chemistry Letters, 2016, 7(13): 2579. DOI URL
[57]	SEBASTIÁ-LUNA P, CALBO J, ALBIACH-SEBASTIÁN N, et al. Tuning the optical absorption of Sn-, Ge-, and Zn-substituted Cs₂AgBiBr₆ double perovskites: structural and electronic effects. Chemistry of Materials, 2021, 33(20): 8028. DOI URL
[58]	LIU Y, ZHANG L, WANG M, et al. Bandgap-tunable double-perovskite thin films by solution processing. Materials Today, 2019, 28: 25. DOI
[59]	PANTALER M, OLTHOF S, MEERHOLZ K, et al. Bismuth-antimony mixed double perovskites Cs₂AgBi_1-_xSb_xBr₆ in solar cells. MRS Advances, 2019, 4(64): 3545. DOI URL
[60]	PAI N, LU J, WANG M, et al. Enhancement of the intrinsic light harvesting capacity of Cs₂AgBiBr₆ double perovskite via modification with sulphide. Journal of Materials Chemistry A, 2020, 8(4): 2008. DOI URL
[61]	LYU M, LEEA D K, PARK N G. Effect of alkaline earth metal chloride additives BCl₂ (B = Mg, Ca, Sr and Ba) on photovoltaic performance of FAPbI₃ based perovskite solar cells. Nanoscale Horiz, 2020, 5(9): 1332. DOI URL
[62]	LYU M, PARK N G. Effect of additives AX (A=FA, MA, Cs, Rb, NH₄, X=Cl, Br, I) in FAPbI₃ on photovoltaic parameters of perovskite solar cells. Solar RRL, 2020, 4(10): 2000331. DOI URL
[63]	FENG J, ZHU X, YANG Z, et al. Record efficiency stable flexible perovskite solar cell using effective additive assistant strategy. Advanced Materials, 2018, 30(35): 1801418. DOI URL
[64]	LI T, PAN Y, WANG Z, et al. Additive engineering for highly efficient organic-inorganic halide perovskite solar cells: recent advances and perspectives. Journal of Materials Chemistry A, 2017, 5(25): 12602. DOI URL
[65]	MOORE D T, SAI H, TAN K W, et al. Crystallization kinetics of organic-inorganic trihalide perovskites and the role of the lead anion in crystal growth. Journal of the American Chemical Society, 2015, 137(6): 2350. DOI PMID
[66]	WU H, WANG Y, LIU A, et al. Methylammonium bromide assisted crystallization for enhanced lead-free double perovskite photovoltaic performance. Advanced Functional Materials, 2022, 32(14): 2109402. DOI URL
[67]	YANG X, XIE A, XIANG H, et al. First investigation of additive engineering for highly efficient Cs₂AgBiBr₆-based lead-free inorganic perovskite solar cells. Applied Physics Reviews, 2021, 8: 041402. DOI URL
[68]	YANG A, ZHANG L, XU Y, et al. V_OC over 1.2 V for Cs₂AgBiBr₆ solar cells based on formamidinium acetate additive. Journal of Materials Science: Materials in Electronics, 2022, 33: 18758. DOI
[69]	ZHANG L, XU Y, NIU P J, et al. Regulating the film crystallization kinetics with thiourea additive in Cs₂AgBiBr₆ solar cells. Journal of Physics D: Applied Physics, 2023, 56(7): 075501. DOI
[70]	LI J, MENG X, WU Z, et al. Pinning bromide ion with ionic liquid in lead-free Cs₂AgBiBr₆ double perovskite solar cells. Advanced Functional Materials, 2022, 32(25): 2112991. DOI URL
[71]	XIAO B, TAN Y, YI Z, et al. Band matching strategy for all-inorganic Cs₂AgBiBr₆ double perovskite solar cells with high photovoltage. ACS Applied Materials & Interfaces, 2021, 13(31): 37027.
[72]	ZHANG Z, WU C, WANG D, et al. Efficient nonlead double perovskite solar cell with multiple hole transport layers. ACS Applied Energy Materials, 2020, 3(10): 9594. DOI URL
[73]	LUO T, ZHANG Y, CHANG X, et al. Dual interfacial engineering for efficient Cs₂AgBiBr₆ based solar cells. Journal of Energy Chemistry, 2021, 53: 373.
[74]	LI J, YAN F, YANG P, et al. Suppressing interfacial shunt loss via functional polymer for performance improvement of lead-free Cs₂AgBiBr₆ double perovskite solar cells. Solar RRL, 2021, 6(4): 2100791. DOI URL
[75]	LI B, WU X, ZHANG S, et al. Efficient and stable Cs₂AgBiBr₆ double perovskite solar cells through in-situ surface modulation. Chemical Engineering Journal, 2022, 446: 137144. DOI URL
[76]	YANG X, CHEN Y, LIU P, et al. Simultaneous power conversion efficiency and stability enhancement of Cs₂AgBiBr₆ lead-free inorganic perovskite solar cell through adopting a multifunctional dye interlayer. Advanced Functional Materials, 2020, 30(23): 2001557. DOI URL
[77]	LI Z, WANG P, MA C, et al. Single-layered MXene nanosheets doping TiO₂ for efficient and stable double perovskite solar cells. Journal of the American Chemical Society, 2021, 143(6): 2593. DOI URL
[78]	WANG B, LI N, YANG L, et al. Chlorophyll derivative-sensitized TiO₂ electron transport layer for record efficiency of Cs₂AgBiBr₆ double perovskite solar cells. Journal of the American Chemical Society, 2021, 143(5): 2207. DOI URL

Cs₂AgBiBr₆钙钛矿太阳能电池研究进展

Research Progress of Cs₂AgBiBr₆ Perovskite Solar Cell

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 78

相关文章 15

编辑推荐

Metrics

本文评价

[1]	代晓栋, 张露伟, 钱奕成, 任智鑫, 曹焕奇, 印寿根. 锡铅混合钙钛矿太阳能电池垂直组分梯度的溶剂工程调控[J]. 无机材料学报, 2023, 38(9): 1089-1096.
[2]	董思吟, 帖舒婕, 袁瑞涵, 郑霄家. 低维卤化物钙钛矿直接型X射线探测器研究进展[J]. 无机材料学报, 2023, 38(9): 1017-1030.
[3]	王马超, 唐扬敏, 邓明雪, 周真真, 刘小峰, 王家成, 刘茜. 共沉淀法制备Cs₂Ag_0.1Na_0.9BiCl₆:Tm³⁺双钙钛矿及其近红外发光性能[J]. 无机材料学报, 2023, 38(9): 1083-1088.
[4]	韩旭, 姚恒大, 吕梅, 陆红波, 朱俊. 单分子液晶添加剂在甲脒铅碘钙钛矿太阳能电池中的应用[J]. 无机材料学报, 2023, 38(9): 1097-1102.
[5]	方万丽, 沈黎丽, 李海艳, 陈薪羽, 陈宗琦, 寿春晖, 赵斌, 杨松旺. NiO_x介孔层的成膜过程对碳电极钙钛矿太阳能电池性能的影响[J]. 无机材料学报, 2023, 38(9): 1103-1109.
[6]	丁统顺, 丰平, 孙学文, 单沪生, 李琪, 宋健. Fmoc-FF-OH钝化钙钛矿薄膜及其太阳能电池性能研究[J]. 无机材料学报, 2023, 38(9): 1076-1082.
[7]	陈雨, 林埔安, 蔡冰, 张文华. 钙钛矿太阳能电池无机空穴传输材料的研究进展[J]. 无机材料学报, 2023, 38(9): 991-1004.
[8]	董怡曼, 谭占鳌. 宽带隙钙钛矿基二端叠层太阳电池复合层的研究进展[J]. 无机材料学报, 2023, 38(9): 1031-1043.
[9]	郭华军, 安帅领, 孟婕, 任书霞, 王文文, 梁子尚, 宋佳钰, 陈恒彬, 苏航, 赵晋津. 卤化物钙钛矿光电阻变机理研究进展[J]. 无机材料学报, 2023, 38(9): 1005-1016.
[10]	丁浩明, 李勉, 李友兵, 陈科, 肖昱琨, 周洁, 陶泉争, 尹航, 柏跃磊, 张毕堃, 孙志梅, 王俊杰, 张一鸣, 黄振莺, 张培根, 孙正明, 韩美康, 赵双, 王晨旭, 黄庆. 三元层状材料结构调控及性能研究进展[J]. 无机材料学报, 2023, 38(8): 845-884.
[11]	林俊良, 王占杰. 铁电超晶格的研究进展[J]. 无机材料学报, 2023, 38(6): 606-618.
[12]	陈强, 白书欣, 叶益聪. 热管理用高导热碳化硅陶瓷基复合材料研究进展[J]. 无机材料学报, 2023, 38(6): 634-646.
[13]	丁玲, 蒋瑞, 唐子龙, 杨运琼. MXene材料的纳米工程及其作为超级电容器电极材料的研究进展[J]. 无机材料学报, 2023, 38(6): 619-633.
[14]	杨卓, 卢勇, 赵庆, 陈军. X射线衍射Rietveld精修及其在锂离子电池正极材料中的应用[J]. 无机材料学报, 2023, 38(6): 589-605.
[15]	苑景坤, 熊书锋, 陈张伟. 聚合物前驱体转化陶瓷增材制造技术研究趋势与挑战[J]. 无机材料学报, 2023, 38(5): 477-488.