MXene材料的纳米工程及其作为超级电容器电极材料的研究进展

doi:10.15541/jim20220566

无机材料学报 ›› 2023, Vol. 38 ›› Issue (6): 619-633.DOI: 10.15541/jim20220566

MXene材料的纳米工程及其作为超级电容器电极材料的研究进展

丁玲¹(), 蒋瑞¹, 唐子龙², 杨运琼³

1.武汉科技大学化学与化工学院, 煤转化与新型炭材料湖北省重点实验室, 武汉 430081
2.广州赛西标准检测研究院有限公司, 广州 510700
3. 江苏海洋大学环境与化学工程学院, 连云港 222005

收稿日期:2022-09-26 修回日期:2022-11-21 出版日期:2022-12-09 网络出版日期:2022-12-09
作者简介:丁玲(1976-), 女, 教授. E-mail: dingling@wust.edu.cn
基金资助:
国家自然科学基金(51972242);江苏省海洋资源开发研究院开放基金(JSIMR202117)

MXene: Nanoengineering and Application as Electrode Materials for Supercapacitors

DING Ling¹(), JIANG Rui¹, TANG Zilong², YANG Yunqiong³

1. Coal Conversion and New Carbon Materials Hubei Key Laboratory, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
2. CESI (Guangzhou) Standards & Testing Institute Co., Ltd., Guangzhou 510700, China
3. School of Environmental and Chemical Engineering, Jiangsu Ocean University, Lianyungang 222005, China

Received:2022-09-26 Revised:2022-11-21 Published:2022-12-09 Online:2022-12-09
About author:DING Ling (1976-), female, professor. E-mail: dingling@wust.edu.cn
Supported by:
National Natural Science Foundation of China(51972242);Open Fund of Jiangsu Institute of Marine Resources Development(JSIMR202117)

摘要/Abstract

摘要：

温室气体的过量排放对全球气候产生严重不良影响, 如何减少碳排放已成为全球性议题。超级电容器具有使用寿命长、功率密度高、碳排放量相对较低的优点。大力发展超级电容器储能是建立未来能源系统的可靠和有效措施。MXene材料具有优良的亲水性、电导率、高电化学稳定性和表面化学可调性, 近年来在超级电容器储能应用研究领域广受关注, 但MXene严重的自堆叠问题限制了其储能性能充分发挥, 开发更先进的MXene材料对于下一代高性能电化学储能设备至关重要。基于此, 本文综述了MXene材料在超级电容器储能应用领域的研究进展, 介绍了MXene的结构和储能特性, 探讨了MXene的储能机理, 重点剖析了纳米工程改进MXene电极性能的结构设计, 详细总结了MXene复合材料构效关系和在超级电容器应用方面的最新研究进展, 最后提出了MXene材料用作超级电容器电极的研究方向和发展趋势。

关键词: MXene, 储能性质, 纳米工程, 复合材料, 超级电容器, 综述

Abstract:

Excessive emission of greenhouse gases has serious adverse effects on global climate. How to reduce carbon emissions has become a global problem. Supercapacitors have advantages of long cycle life, high power density and relatively low carbon emissions. Developing supercapacitor energy storage is an effective measure to build the reliable future energy system. In recent years, MXene materials have achievedgreat popularity in the field of supercapacitor energy storage applications due to their excellent hydrophilicity, electrical conductivity, high electrochemical stability, and surface chemical tunability. However, the serious self-stacking problem of MXene limits its performance in energy storage. Developing advanced MXene materials is critical for next generation high-performance electrochemical energy storage devices. This paper reviews the research progress of MXene material in the field of supercapacitor energy storage. Firstly, the structure and energy storage properties of MXene are introduced, followed by analysis of the energy storage mechanism of MXene. Secondly, nanoengineering of structure design to improve the performance of MXene electrode is depicted. Thirdly, structure-performance relationship of MXene composite materials and its latest research progress in application of supercapacitor are summarized. Finally, research and development trends of MXene as an electrode for supercapacitor are broadly prospected.

Key words: MXene, energy storage property, nanoengineering, composite material, supercapacitor, review

中图分类号:

TM53
TB33

丁玲, 蒋瑞, 唐子龙, 杨运琼. MXene材料的纳米工程及其作为超级电容器电极材料的研究进展[J]. 无机材料学报, 2023, 38(6): 619-633.

DING Ling, JIANG Rui, TANG Zilong, YANG Yunqiong. MXene: Nanoengineering and Application as Electrode Materials for Supercapacitors[J]. Journal of Inorganic Materials, 2023, 38(6): 619-633.

图/表 10

图1 MXene在(a)水系和(b)非水系Li+电解质中的结构变化和电子结构变化示意图[21]

Fig. 1 Schematic illustration of structural and electronic structural changes of MXene in (a) aqueous and (b) nonaqueous Li+ electrolytes[21] φ, inner potential; ηe, electron electrochemical potential

图2 含碘端基MXene的制备方法与电化学性能[43]

Fig. 2 Preparation method and electrochemical performance of iodine-containing terminated MXene[43] (a) Preparing strategy by Lewis-acid melt etching; (b) CV curves of I-Ti3C2 MXene and HF-Ti3C2Tx MXene at 5 mV·s−1; WE, working electrode; RE, reference electrode; CE, counter electrode Colorful figures are available on website

图3 900N-Ti2CTx纳米片的合成方法与电化学性能[49]

Fig. 3 Synthesis procedure and electrochemical performance of 900N-Ti2CTx nanosheets[49] (a) Synthesis procedure; (b) CV curves at 100 mV·s−1; (c) Discharge current density as a function of scanning rate; 1 Å = 0.1 nm Colorful figures are available on website

图4 MXene带MR-0.5的(a)制备过程和(b)电化学性能[53]

Fig. 4 (a) Schematic illustration of the preparation and (b) electrochemical performance of the MXene ribbon MR-0.5[53] Colorful figures are available on website

图5 d-Ti3C2/NF复合材料的制备示意图和电化学性能[58]

Fig. 5 Schematic illustration and electrochemical performance of d-Ti3C2/NF composite[58] (a) Schematic illustration; (b) CV curves at 20 mV·s−1; (c) GCD curves at 1 A·g−1 Colorful figures are available on website

图6 MXene/PANI薄膜制备过程示意图和电化学性能[61]

Fig. 6 Preparative schematic illustration and electrochemical performance of MXene/PANI film[61] (a) Preparative schematic diagram; (b) CV plots of MP0, MP2, MP5 and MP8 at a scan rate of 50 mV·s−1 Colorful figures are available on website

图7 MXene尺寸分级设备示意图和尺寸细化效应表征的电化学性能[69]

Fig. 7 Schematic diagram of the equipment used for size grading MXene and size-refinement effect characterization[69] (a) Schematic diagram of the equipment; (b) Stress-strain curves; (c) GCD curves at 1 A·g−1 Colorful figures are available on website

图8 有序MXene水凝胶电极的多尺度结构工程制备策略示意图和电化学性能[70]

Fig. 8 Preparative schematic illustration of multi-scale structural engineering strategy and electrochemical performance of ordered MXene hydrogel supercapacitor electrode[70] (a) Preparative schematic illustration; (b) CV plots at 100 mV·s−1; (c) Rate performance Colorful figures are available on website

表1 MXene基电极电化学性能

Table 1 Examples of electrochemical properties of MXene-based electrodes

Electrode	Specific capacity	Rate capability	Power density/energy density	Electrolyte	Ref.
MXene-rHGO	1445 F·cm⁻³@2 mV·s⁻¹	988 F·cm⁻¹@500 mV·s⁻¹	38.6 Wh·L⁻¹/206 W·L⁻¹	3 mol·L⁻¹ H₂SO₄	[75]
Ti₃C₂/CNTs	134 F·g^-1@1 A·g^-1	-	2.77 Wh·kg⁻¹/311 W·kg⁻¹	6 mol·L⁻¹ KOH	[76]
MnO₂@MXene/CNT	371.1 F·cm⁻³@1 A·cm⁻³	-	8.22 mWh·cm⁻³/ 276.28 mW·cm⁻³	1 mol·L⁻¹ H₂SO₄	[77]
MnO₂/Ti₃C₂T_x	130.5 F·g⁻¹@0.2 A·g⁻¹	130.5 F·g⁻¹@0.2 A·g⁻¹	-	1 mol·L⁻¹ Na₂SO₄	[16]
Co₃O₄-Nb₂C	1061 F·g^-1@2 A·g^-1	547 F·g⁻¹@50 A·g⁻¹	60.3 Wh·kg⁻¹/670 W·kg⁻¹	6 mol·L⁻¹ KOH	[78]
Co-MXene	1081 F·g^-1@0.5 A·g^-1	-	26.06 Wh·kg⁻¹/700 W·kg⁻¹	6 mol·L⁻¹ KOH	[79]
MXene/MnCo₂O₄	806.67 F·g^-1@1 A·g^-1	545.83 F·g⁻¹@5 A·g⁻¹	26.8 Wh·kg⁻¹/2.88 kW·kg⁻¹	1 mol·L⁻¹ KOH	[80]
NiMoO₄/Ti₃C₂T_x	545.5 C·g⁻¹ (1364 F·g⁻¹)@0.5 A·g⁻¹	66.5 C·g⁻¹ @5 A·g⁻¹	33.36 Wh·kg⁻¹/400.08 W·kg⁻¹	3 mol·L⁻¹ KOH	[3]
MoO₃ NWs/MXene@CC	775 F·g^-1@1 A·g^-1	-	-	2 mol·L⁻¹ KOH	[81]
Ti₃C₂T_x/CoS₂	1320 F·g⁻¹@1 A·g⁻¹	1320 F·g⁻¹@1 A·g⁻¹	-	2 mol·L⁻¹ KOH	[82]
MXene-NiCo₂S₄@NF	596.69 C·g⁻¹@1 A·g⁻¹	596.69 C·g⁻¹@1 A·g⁻¹	-	3 mol·L⁻¹ KOH	[83]
Ti₃C₂-DA-NiMoS₄	1288 F·g^-1@1 A·g^-1	1288 F·g⁻¹@1 A·g⁻¹	40.5 Wh·kg⁻¹/810 W·kg⁻¹	Not mentioned	[84]
NiCo₂Se₄/MXene	953.8 F·g^-1@1 A·g^-1	-	22.4 Wh·kg⁻¹/800 W·kg⁻¹	3 mol·L⁻¹ KOH	[85]
Co Ni(Ox)Se @MXene	1782 F·g^-1@5 mV·s^-1	-	7.2 kW·kg⁻¹/131.9 Wh·kg⁻¹	1 mol·L⁻¹ KOH	[86]
NS-MXene	495 F·g^-1@1 A·g^-1	180 F·g⁻¹@10 A·g⁻¹	-	1 mol·L⁻¹ H₂SO₄	[46]
MXene-PANI/a-Fe₂O₃-MnO₂/MXene-PANI	661 F·g^-13138 mF·cm⁻³@3 mV·s ^-1	-	53.32 Wh·L⁻¹/17.45 Wh·kg⁻¹	1 mol·L⁻¹ H₂SO₄	[87]
Ti₃C₂T_x/Ni-MOFs	1124 F·g^-1@1 A·g^-1	697 F·g⁻¹@20 A·g⁻¹	24 Wh·kg⁻¹/8 kW·kg⁻¹	6 mol·L⁻¹ KOH	[88]
BiOCl-Ti₃C₂T_x	396.5 F·cm⁻³@1 A·g^-1	228 F·cm⁻³@15 A·g⁻¹	15.2 Wh·kg⁻¹/567.4 W·kg⁻¹	1 mol·L⁻¹ KOH	[89]

表1 MXene基电极电化学性能

Table 1 Examples of electrochemical properties of MXene-based electrodes

Electrode	Specific capacity	Rate capability	Power density/energy density	Electrolyte	Ref.
MXene-rHGO	1445 F·cm⁻³@2 mV·s⁻¹	988 F·cm⁻¹@500 mV·s⁻¹	38.6 Wh·L⁻¹/206 W·L⁻¹	3 mol·L⁻¹ H₂SO₄	[75]
Ti₃C₂/CNTs	134 F·g^-1@1 A·g^-1	-	2.77 Wh·kg⁻¹/311 W·kg⁻¹	6 mol·L⁻¹ KOH	[76]
MnO₂@MXene/CNT	371.1 F·cm⁻³@1 A·cm⁻³	-	8.22 mWh·cm⁻³/ 276.28 mW·cm⁻³	1 mol·L⁻¹ H₂SO₄	[77]
MnO₂/Ti₃C₂T_x	130.5 F·g⁻¹@0.2 A·g⁻¹	130.5 F·g⁻¹@0.2 A·g⁻¹	-	1 mol·L⁻¹ Na₂SO₄	[16]
Co₃O₄-Nb₂C	1061 F·g^-1@2 A·g^-1	547 F·g⁻¹@50 A·g⁻¹	60.3 Wh·kg⁻¹/670 W·kg⁻¹	6 mol·L⁻¹ KOH	[78]
Co-MXene	1081 F·g^-1@0.5 A·g^-1	-	26.06 Wh·kg⁻¹/700 W·kg⁻¹	6 mol·L⁻¹ KOH	[79]
MXene/MnCo₂O₄	806.67 F·g^-1@1 A·g^-1	545.83 F·g⁻¹@5 A·g⁻¹	26.8 Wh·kg⁻¹/2.88 kW·kg⁻¹	1 mol·L⁻¹ KOH	[80]
NiMoO₄/Ti₃C₂T_x	545.5 C·g⁻¹ (1364 F·g⁻¹)@0.5 A·g⁻¹	66.5 C·g⁻¹ @5 A·g⁻¹	33.36 Wh·kg⁻¹/400.08 W·kg⁻¹	3 mol·L⁻¹ KOH	[3]
MoO₃ NWs/MXene@CC	775 F·g^-1@1 A·g^-1	-	-	2 mol·L⁻¹ KOH	[81]
Ti₃C₂T_x/CoS₂	1320 F·g⁻¹@1 A·g⁻¹	1320 F·g⁻¹@1 A·g⁻¹	-	2 mol·L⁻¹ KOH	[82]
MXene-NiCo₂S₄@NF	596.69 C·g⁻¹@1 A·g⁻¹	596.69 C·g⁻¹@1 A·g⁻¹	-	3 mol·L⁻¹ KOH	[83]
Ti₃C₂-DA-NiMoS₄	1288 F·g^-1@1 A·g^-1	1288 F·g⁻¹@1 A·g⁻¹	40.5 Wh·kg⁻¹/810 W·kg⁻¹	Not mentioned	[84]
NiCo₂Se₄/MXene	953.8 F·g^-1@1 A·g^-1	-	22.4 Wh·kg⁻¹/800 W·kg⁻¹	3 mol·L⁻¹ KOH	[85]
Co Ni(Ox)Se @MXene	1782 F·g^-1@5 mV·s^-1	-	7.2 kW·kg⁻¹/131.9 Wh·kg⁻¹	1 mol·L⁻¹ KOH	[86]
NS-MXene	495 F·g^-1@1 A·g^-1	180 F·g⁻¹@10 A·g⁻¹	-	1 mol·L⁻¹ H₂SO₄	[46]
MXene-PANI/a-Fe₂O₃-MnO₂/MXene-PANI	661 F·g^-13138 mF·cm⁻³@3 mV·s ^-1	-	53.32 Wh·L⁻¹/17.45 Wh·kg⁻¹	1 mol·L⁻¹ H₂SO₄	[87]
Ti₃C₂T_x/Ni-MOFs	1124 F·g^-1@1 A·g^-1	697 F·g⁻¹@20 A·g⁻¹	24 Wh·kg⁻¹/8 kW·kg⁻¹	6 mol·L⁻¹ KOH	[88]
BiOCl-Ti₃C₂T_x	396.5 F·cm⁻³@1 A·g^-1	228 F·cm⁻³@15 A·g⁻¹	15.2 Wh·kg⁻¹/567.4 W·kg⁻¹	1 mol·L⁻¹ KOH	[89]

图9 (a)I-Ti3C2中间层插层PPy示意图和(b)I-Ti3C2中间层插层PPy原子尺度示意图[94]

Fig. 9 (a) Schematic and (b) atomic-scale schematic of intercalated PPy in the interlayer of I-Ti3C2[94]

参考文献 105

[1]	刘志成, 彭道刚, 赵慧荣, 等. 双碳目标下储能参与电力系统辅助服务发展前景. 储能科学与技术, 2022, 11(2):704.
[2]	ZHANG J, JIANG D, LIAO L, et al. Ti₃C₂T_x MXene based hybrid electrodes for wearable supercapacitors with varied deformation capabilities. Chemical Engineering Journal, 2022, 429: 132232. DOI URL
[3]	WANG Y, SUN J, QIAN X, et al. 2D/2D heterostructures of nickel molybdate and MXene with strong coupled synergistic effect towards enhanced supercapacitor performance. Journal of Power Sources, 2019, 414: 540. DOI URL
[4]	SHAN Q, MU X, ALHABEB M, et al. Two-dimensional vanadium carbide (V₂C) MXene as electrode for supercapacitors with aqueous electrolytes. Electrochemistry Communications, 2018, 96: 103. DOI URL
[5]	邵光伟, 郭珊珊, 于瑞, 等. 可拉伸超级电容器的研究进展: 电极、电解质和器件. 物理学报, 2020, 69(17):155.
[6]	NAGUIB M, KURTOGLU M, PRESSER V, et al. Two-dimensional nanocrystals produced by exfoliation of Ti₃AlC₂. Advanced Materials, 2011, 23(37):4248. DOI URL
[7]	NAGUIB M, MASHTALIR O, CARLE J, et al. Two-dimensional transition metal carbides. ACS Nano, 2012, 6(2):1322. DOI PMID
[8]	MASHTALIR O, NAGUIB M, MOCHALIN V N, et al. Intercalation and delamination of layered carbides and carbonitrides. Nature Communications, 2013, 4: 1716. DOI PMID
[9]	ZHANG J F, CAO H Y, WANG H B. Research progress of novel two-dimensional material MXene. Journal of Inorganic Materials, 2017, 32(6):561. DOI URL
[10]	YAN H T, LI X H, LIU M Z, et al. Quantum capacitance of supercapacitor electrodes based on the F-functionalized M₂C MXenes: a first-principles study. Vacuum, 2022, 201: 111094. DOI URL
[11]	WANG Q, PAN X, WANG X, et al. Fabrication strategies and application fields of novel 2D Ti₃C₂T_x (MXene) composite hydrogels: a mini-review. Ceramics International, 2021, 47(4):4398. DOI URL
[12]	ZHAO X, VASHISTH A, BLIVIN J W, et al. pH, nanosheet concentration, and antioxidant affect the oxidation of Ti₃C₂T_x and Ti₂CT_x MXene dispersions. Advanced Materials Interfaces, 2020, 7(20):2000845. DOI URL
[13]	BU F, ZAGHO M M, IBRAHIM Y, et al. Porous MXenes: synthesis, structures, and applications. Nano Today, 2020, 30: 100803. DOI URL
[14]	THAKUR N, KUMAR P, SATI D C, et al. Recent advances in two-dimensional MXenes for power and smart energy systems. Journal of Energy Storage, 2022, 50: 104604. DOI URL
[15]	MENG W, LIU X, SONG H, et al. Advances and challenges in 2D MXenes: from structures to energy storage and conversions. Nano Today, 2021, 40: 101273. DOI URL
[16]	JIANG H, WANG Z, YANG Q, et al. A novel MnO₂/Ti₃C₂T_x MXene nanocomposite as high performance electrode materials for flexible supercapacitors. Electrochimica Acta, 2018, 290: 695. DOI URL
[17]	LUKATSKAYA M R, KOTA S, LIN Z, et al. Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides. Nature Energy, 2017, 2(8):17105. DOI URL
[18]	ZHANG J, KONG N, HEGH D, et al. Freezing titanium carbide aqueous dispersions for ultra-long-term storage. ACS Applied Materials & Interfaces, 2020, 12(30):34032.
[19]	MOMODU D, ZERAATI A S, PABLOS F L, et al. Hybrid energy storage using nitrogen-doped graphene and layered-MXene (Ti₃C₂) for stable high-rate supercapacitors. Electrochimica Acta, 2021, 388:138664. DOI URL
[20]	WU J, LI Q, SHUCK C E, et al. An aqueous 2.1 V pseudocapacitor with MXene and V-MnO₂ electrodes. Nano Research, 2021, 15(1):535. DOI
[21]	OKUBO M, SUGAHARA A, KAJIYAMA S, et al. MXene as a charge storage host. Accounts of Chemical Research, 2018, 51(3):591. DOI PMID
[22]	HANTANASIRISAKUL K, GOGOTSI Y. Electronic and optical properties of 2D transition metal carbides and nitrides (MXenes). Advanced Materials, 2018, 30(52):1804779. DOI URL
[23]	YING G, KOTA S, DILLON A D, et al. Conductive transparent V₂CT_x (MXene) films. Chemistry of Flat Materials, 2018, 8:25.
[24]	WANG K, ZHOU Y, XU W, et al. Fabrication and thermal stability of two-dimensional carbide Ti₃C₂ nanosheets. Ceramics International, 2016, 42(7):8419. DOI URL
[25]	HALIM J, PERSSON I, MOON E J, et al. Electronic and optical characterization of 2D Ti₂C and Nb₂C (MXene) thin films. Journal of Physics: Condensed Matter, 2019, 31(16):165301. DOI URL
[26]	ELEMIKE E E, OSAFILE O E, OMUGBE E. New perspectives 2Ds to 3Ds MXenes and graphene functionalized systems as high performance energy storage materials. Journal of Energy Storage, 2021, 42:102993. DOI URL
[27]	BORYSIUK V N, MOCHALIN V N, GOGOTSI Y. Bending rigidity of two-dimensional titanium carbide (MXene) nanoribbons: a molecular dynamics study. Computational Materials Science, 2018, 143:418. DOI URL
[28]	ZHANG N, HONG Y, YAZDANPARAST S, et al. Superior structural, elastic and electronic properties of 2D titanium nitride MXenes over carbide MXenes: a comprehensive first principles study. 2D Materials, 2018, 5(4):045004.
[29]	LI X, MA Y, YUE Y, et al. A flexible Zn-ion hybrid micro- supercapacitor based on MXene anode and V₂O₅ cathode with high capacitance. Chemical Engineering Journal, 2022, 428:130965. DOI URL
[30]	KAJIYAMA S, SZABOVA L, IINUMA H, et al. Enhanced Li-ion accessibility in MXene titanium carbide by steric chloride termination. Advanced Energy Materials, 2017, 7(9):1601873. DOI URL
[31]	KAJIYAMA S, SZABOVA L, SODEYAMA K, et al. Sodium-ion intercalation mechanism in MXene nanosheets. ACS Nano, 2016, 10(3):3334. DOI PMID
[32]	XU K, JI X, ZHANG B, et al. Charging/discharging dynamics in two-dimensional titanium carbide (MXene) slit nanopore: insights from molecular dynamic study. Electrochimica Acta, 2016, 196:75. DOI URL
[33]	YU H, WANG Y, JING Y, et al. Surface modified MXene-based nanocomposites for electrochemical energy conversion and storage. Small, 2019, 15(25):1901503. DOI URL
[34]	XIAO M X, LI M M, SONG E H, et al. Halogenated Ti₃C₂ MXene as high capacity electrode material for Li-ion batteries. Journal of Inorganic Materials, 2022, 37(6):660. DOI URL
[35]	LIU W, ZHENG Y, ZHANG Z, et al. Ultrahigh gravimetric and volumetric capacitance in Ti₃C₂T_x MXene negative electrode enabled by surface modification and in-situ intercalation. Journal of Power Sources, 2022, 521:230965. DOI URL
[36]	CHEN W, TANG J, CHENG P, et al. 3D porous MXene (Ti₃C₂T_x) prepared by alkaline-induced flocculation for supercapacitor electrodes. Materials, 2022, 15(3):925. DOI URL
[37]	CHEN J, CHEN H, CHEN M, et al. Nacre-inspired surface- engineered MXene/nanocellulose composite film for high-performance supercapacitors and zinc-ion capacitors. Chemical Engineering Journal, 2022, 428:131380. DOI URL
[38]	LI J, YUAN X, LIN C, et al. Achieving high pseudocapacitance of 2D titanium carbide (MXene) by cation intercalation and surface modification. Advanced Energy Materials, 2017, 7(15):1602725. DOI URL
[39]	CHEN X, ZHU Y, ZHANG M, et al. n-Butyllithium-treated Ti₃C₂T_x MXene with excellent pseudocapacitor performance. ACS Nano, 2019, 13(8):9449. DOI URL
[40]	KAMYSBAYEV V, FILATOV A S, HU H, et al. Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes. Science, 2020, 369(6506):979. DOI PMID
[41]	MAO K, SHI J, ZHANG Q, et al. High-capacitance MXene anode based on Zn-ion pre-intercalation strategy for degradable micro Zn-ion hybrid supercapacitors. Nano Energy, 2022, 103:107791. DOI URL
[42]	LI T, YAO L, LIU Q, et al. Fluorine-free synthesis of high-purity Ti₃C₂T_x (T=OH, O) via alkali treatment. Angewandte Chemie International Edition, 2018, 57(21):6115. DOI URL
[43]	GONG S, ZHAO F, XU H, et al. Iodine-functionalized titanium carbide MXene with ultra-stable pseudocapacitor performance. Journal of Colloid and Interface Science, 2022, 615:643. DOI PMID
[44]	NASRIN K, SUDHARSHAN V, SUBRAMANI K, et al. In-situ synergistic 2D/2D MXene/BCN heterostructure for superlative energy density supercapacitor with super-long life. Small, 2022, 18(4):2106051. DOI URL
[45]	吕通, 张恩爽, 原因, 等. 大片单层低缺陷MXene的制备及其膜材料的电磁屏蔽性能. 高等学校化学学报, 2019, 40(10): 2059. DOI
[46]	YANG F, HEGH D, SONG D, et al. Synthesis of nitrogen-sulfur co-doped Ti₃C₂T_x MXene with enhanced electrochemical properties. Materials Reports: Energy, 2022, 2(1):100079. DOI URL
[47]	WEN Y, RUFFORD T E, CHEN X, et al. Nitrogen-doped Ti₃C₂T_x MXene electrodes for high-performance supercapacitors. Nano Energy, 2017, 38:368. DOI URL
[48]	YANG F, HEGH D, SONG D, et al. A nitrogenous pre-intercalation strategy for the synthesis of nitrogen-doped Ti₃C₂T_x MXene with enhanced electrochemical capacitance. Journal of Materials Chemistry A, 2021, 9(10):6393. DOI URL
[49]	YOON Y, LEE M, KIM S K, et al. A strategy for synthesis of carbon nitride induced chemically doped 2D MXene for high- performance supercapacitor electrodes. Advanced Energy Materials, 2018, 8(15):1703173. DOI URL
[50]	LEE J B, CHOI G H, YOO P J. Oxidized-co-crumpled multiscale porous architectures of MXene for high performance supercapacitors. Journal of Alloys and Compounds, 2021, 887:161304. DOI URL
[51]	YAO M, CHEN Y, WANG Z, et al. Boosting gravimetric and volumetric energy density via engineering macroporous MXene films for supercapacitors. Chemical Engineering Journal, 2020, 395:124057. DOI URL
[52]	GUAN G, LI P, SHI X, et al. Electrode based on porous MXene nanosheets for high-performance supercapacitor. Journal of Alloys and Compounds, 2022, 924:166647. DOI URL
[53]	ZHENG X. Enhancing the ion accessibility of Ti₃C₂T_x MXene films by femtosecond laser ablation towards high-rate supercapacitors. Journal of Alloys and Compounds, 2022, 899:163275. DOI URL
[54]	WANG S, ZHAO S, GUO X, et al. 2D Material-based heterostructures for rechargeable batteries. Advanced Energy Materials, 2022, 12(4):2100864. DOI URL
[55]	DENG Y, SHANG T, WU Z, et al. Fast gelation of Ti₃C₂T_x MXene initiated by metal ions. Advanced Materials, 2019, 31(43):1902432. DOI URL
[56]	ZHU Z, WANG Z, BA Z, et al. 3D MXene-holey graphene hydrogel for supercapacitor with superior energy storage. Journal of Energy Storage, 2022, 47:103911. DOI URL
[57]	WANG Y, WANG X, LI X, et al. Engineering 3D ion transport channels for flexible MXene films with superior capacitive performance. Advanced Functional Materials, 2019, 29(14):1900326. DOI URL
[58]	GUO J, ZHAO Y, LIU A, et al. Electrostatic self-assembly of 2D delaminated MXene (Ti₃C₂) onto Ni foam with superior electrochemical performance for supercapacitor. Electrochimica Acta, 2019, 305:164. DOI URL
[59]	GUO T, ZHOU D, PANG L, et al. Sandwich-type macroporous Ti₃C₂T_x MXene frameworks for supercapacitor electrode. Scripta Materialia, 2022, 213:114590. DOI URL
[60]	MURALI G, RAWAL J, MODIGUNTA J K R, et al. A review on MXenes: new-generation 2D materials for supercapacitors. Sustainable Energy & Fuels, 2021, 5(22):5672.
[61]	LUO W, WEI Y, ZHUANG Z, et al. Fabrication of Ti₃C₂T_x MXene/polyaniline composite films with adjustable thickness for high-performance flexible all-solid-state symmetric supercapacitors. Electrochimica Acta, 2022, 406:139871. DOI URL
[62]	GUO H, ZHANG J, YANG F, et al. Sandwich-like porous MXene/ Ni₃S₄/CuS derived from MOFs as superior supercapacitor electrode. Journal of Alloys and Compounds, 2022, 906:163863. DOI URL
[63]	GUO H, ZHANG J, XU M, et al. Zeolite-imidazole framework derived nickel-cobalt hydroxide on ultrathin MXene nanosheets for long life and high performance supercapacitance. Journal of Alloys and Compounds, 2021, 888:161250. DOI URL
[64]	LIU X, LU Z, HUANG X, et al. Self-assembled S, N co-doped reduced graphene oxide/MXene aerogel for both symmetric liquid- and all-solid-state supercapacitors. Journal of Power Sources, 2021, 516:230682. DOI URL
[65]	XU J, ZHU J, GONG C, et al. Achieving high yield of Ti₃C₂T MXene few-layer flakes with enhanced pseudocapacior performance by decreasing precursor size. Chinese Chemical Letters, 2020, 31(4):1039. DOI URL
[66]	LUO S, PATOLE S, ANWER S, et al. Tensile behaviors of Ti₃C₂T_x (MXene) films. Nanotechnology, 2020, 31(39):395704. DOI URL
[67]	MALESKI K, REN C E, ZHAO M Q, et al. Size-dependent physical and electrochemical properties of two-dimensional MXene flakes. ACS Applied Materials & Interfaces, 2018, 10(29):24491.
[68]	LI X, MA Y, SHEN P, et al. Self‐healing microsupercapacitors with size-dependent 2D MXene. ChemElectroChem, 2020, 7(3):821. DOI URL
[69]	SUN J, LIU Y, HUANG J, et al. Size-refinement enhanced flexibility and electrochemical performance of MXene electrodes for flexible waterproof supercapacitors. Journal of Energy Chemistry, 2021, 63:594. DOI URL
[70]	HUANG X, HUANG J, YANG D, et al. A multi-scale structural engineering strategy for high-performance MXene hydrogel supercapacitor electrode. Advanced Science, 2021, 8(18):2101664. DOI URL
[71]	XIA Y, MATHIS T S, ZHAO M Q, et al. Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes. Nature, 2018, 557(7705):409. DOI
[72]	YU J, ZENG M, ZHOU J, et al. A one-pot synthesis of nitrogen doped porous MXene/TiO₂ heterogeneous film for high-performance flexible energy storage. Chemical Engineering Journal, 2021, 426:130765. DOI URL
[73]	TIAN Y, QUE B, LUO Y, et al. Amino-rich surface-modified MXene as anode for hybrid aqueous proton supercapacitors with superior volumetric capacity. Journal of Power Sources, 2021, 495:229790. DOI URL
[74]	WANG J, GONG J, ZHANG H, et al. Construction of hexagonal nickel-cobalt oxide nanosheets on metal-organic frameworks based on MXene interlayer ion effect for hybrid supercapacitors. Journal of Alloys and Compounds, 2021, 870:159466. DOI URL
[75]	FAN Z, WANG Y, XIE Z, et al. Modified MXene/holey graphene films for advanced supercapacitor electrodes with superior energy storage. Advanced Science, 2018, 5(10):1800750. DOI URL
[76]	YANG L, ZHENG W, ZHANG P, et al. MXene/CNTs films prepared by electrophoretic deposition for supercapacitor electrodes. Journal of Electroanalytical Chemistry, 2018, 830-831:1. DOI URL
[77]	GUO Z, LI Y, LU Z, et al. High-performance MnO₂@MXene/carbon nanotube fiber electrodes with internal and external construction for supercapacitors. Journal of Materials Science, 2022, 57(5):3613. DOI
[78]	SHEN B, LIAO X, ZHANG X, et al. Synthesis of Nb₂C MXene-based 2D layered structure electrode material for high-performance battery-type supercapacitors. Electrochimica Acta, 2022, 413:140144. DOI URL
[79]	ZHANG Y, CAO J, YUAN Z, et al. Assembling Co₃O₄ nanoparticles into MXene with enhanced electrochemical performance for advanced asymmetric supercapacitors. Journal of Colloid and Interface Science, 2021, 599:109. DOI URL
[80]	XIA Q, CAO W, XU F, et al. Assembling MnCo₂O₄ nanoparticles embedded into MXene with effectively improved electrochemical performance. Journal of Energy Storage, 2022, 47:103906. DOI URL
[81]	MAHMOOD M, CHAUDHARY K, SHAHID M, et al. Fabrication of MoO₃ nanowires/MXene@CC hybrid as highly conductive and flexible electrode for next-generation supercapacitors applications. Ceramics International, 2022, 48(13):19314. DOI URL
[82]	LIU H, HU R, QI J, et al. One‐step synthesis of nanostructured CoS₂ grown on titanium carbide MXene for high‐performance asymmetrical supercapacitors. Advanced Materials Interfaces, 2020, 7(6):1901659. DOI URL
[83]	LI H, CHEN X, ZALNEZHAD E, et al. 3D hierarchical transition-metal sulfides deposited on MXene as binder-free electrode for high-performance supercapacitors. Journal of Industrial and Engineering Chemistry, 2020, 82:309. DOI URL
[84]	XU J, YANG X, ZOU Y, et al. High density anchoring of NiMoS₄ on ultrathin Ti₃C₂ MXene assisted by dopamine for supercapacitor electrode materials. Journal of Alloys and Compounds, 2022, 891:161945. DOI URL
[85]	LIU Y, GONG J, WANG J, et al. Facile fabrication of MXene supported nickel-cobalt selenide ternary composite via one-step hydrothermal for high-performance asymmetric supercapacitors. Journal of Alloys and Compounds, 2022, 899:163354. DOI URL
[86]	KARKUZHALI R, MANOJ S, SHANMUGAPRIYA K, et al. MXene-based O/Se-rich bimetallic nanocomposites for high performance solid-state symmetric supercapacitors. Journal of Solid State Chemistry, 2022, 306:122727. DOI URL
[87]	LI C, WANG S, CUI Y, et al. Sandwich-like high-load MXene/polyaniline film electrodes with ultrahigh volumetric capacitance for flexible supercapacitors. Journal of Colloid and Interface Science, 2022, 620:35. DOI PMID
[88]	ZHANG X, YANG S, LU W, et al. MXenes induced formation of Ni-MOF microbelts for high-performance supercapacitors. Journal of Colloid and Interface Science, 2021, 592:95. DOI PMID
[89]	XIA Q X, SHINDE N M, YUN J M, et al. Bismuth oxychloride/ MXene symmetric supercapacitor with high volumetric energy density. Electrochimica Acta, 2018, 271:351. DOI URL
[90]	YAN J, REN C E, MALESKI K, et al. Flexible MXene/graphene films for ultrafast supercapacitors with outstanding volumetric capacitance. Advanced Functional Materials, 2017, 27(30):1701264. DOI URL
[91]	LIAN S, LI G, SONG F, et al. Surfactant-free self-assembled MXene/carbon nanotubes hybrids for high-rate sodium- and potassium-ion storage. Journal of Alloys and Compounds, 2022, 901:163426. DOI URL
[92]	BAI T, WANG W, XUE G, et al. Free-standing, flexible carbon@MXene films with cross-linked mesoporous structures toward supercapacitors and pressure sensors. ACS Applied Materials & Interfaces, 2021, 13(48):57576.
[93]	ZHANG D, LUO M, YANG K, et al. Porosity-adjustable MXene film with transverse and longitudinal ion channels for flexible supercapacitors. Microporous and Mesoporous Materials, 2021, 326:111389. DOI URL
[94]	ZHU M, HUANG Y, DENG Q, et al. Highly flexible, freestanding supercapacitor electrode with enhanced performance obtained by hybridizing polypyrrole chains with MXene. Advanced Energy Materials, 2016, 6(21):1600969. DOI URL
[95]	KAUSAR A. Polymer/MXene nanocomposite-a new age for advanced materials. Polymer-Plastics Technology and Materials, 2021, 60:1377.
[96]	RUAN C, ZHU D, QI J, et al. MXene-modulated CoNi₂S₄ dendrite as enhanced electrode for hybrid supercapacitors. Surfaces and Interfaces, 2021, 25:101274. DOI URL
[97]	SHI T Z, FENG Y L, PENG T, et al. Sea urchin-shaped Fe₂O₃ coupled with 2D MXene nanosheets as negative electrode for high-performance asymmetric supercapacitors. Electrochimica Acta, 2021, 381:138245. DOI URL
[98]	GENG P, ZHENG S, TANG H, et al. Transition metal sulfides based on graphene for electrochemical energy storage. Advanced Energy Materials, 2018, 8(15):1703259. DOI URL
[99]	HE Z, WANG Y, LI Y, et al. Superior pseudocapacitive performance and mechanism of self-assembled MnO₂/MXene films as positive electrodes for flexible supercapacitors. Journal of Alloys and Compounds, 2022, 899:163241. DOI URL
[100]	CHEN X, DING Z, YU H, et al. Facile fabrication of CuCo₂S₄ nanoparticles/MXene composite as anode for high-performance asymmetric supercapacitor. Materials Chemistry Frontiers, 2021, 5:7606. DOI URL
[101]	LIU Y T, ZHANG P, SUN N, et al. Self-assembly of transition metal oxide nanostructures on MXene nanosheets for fast and stable lithium storage. Advanced Materials, 2018, 30(23):1707334. DOI URL
[102]	LI H, LIU Y, LIN S, et al. Laser crystallized sandwich-like MXene/Fe₃O₄/MXene thin film electrodes for flexible supercapacitors. Journal of Power Sources, 2021, 497:229882. DOI URL
[103]	WANG X, SONG H, MA S, et al. Template ion-exchange synthesis of Co-Ni composite hydroxides nanosheets for supercapacitor with unprecedented rate capability. Chemical Engineering Journal, 2022, 432:134319. DOI URL
[104]	MAHMOOD M, ZULFIQAR S, WARSI M F, et al. Nanostructured V₂O₅ and its nanohybrid with MXene as an efficient electrode material for electrochemical capacitor applications. Ceramics International, 2022, 48(2):2345. DOI URL
[105]	FAN Z, WANG Y, XIE Z, et al. A nanoporous MXene film enables flexible supercapacitors with high energy storage. Nanoscale, 2018, 10(20):9642. DOI PMID

MXene材料的纳米工程及其作为超级电容器电极材料的研究进展

MXene: Nanoengineering and Application as Electrode Materials for Supercapacitors

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