无机材料学报 ›› 2023, Vol. 38 ›› Issue (3): 322-328.DOI: 10.15541/jim20220353
杨晓明1(), 蓝江河2,3(
), 魏占涛3, 苏榕冰1, 李阳3, 王祖建1, 刘颖1, 何超1, 龙西法1(
)
收稿日期:
2022-06-24
修回日期:
2022-08-14
出版日期:
2022-10-25
网络出版日期:
2022-10-25
通讯作者:
蓝江河, 高级工程师. E-mail: lanjh418915@sina.com;作者简介:
杨晓明(1990-), 男, 副研究员. E-mail: xmyang@fjirsm.ac.cn
YANG Xiaoming1(), LAN Jianghe2,3(
), WEI Zhantao3, SU Rongbing1, LI Yang3, WANG Zujian1, LIU Ying1, HE Chao1, LONG Xifa1(
)
Received:
2022-06-24
Revised:
2022-08-14
Published:
2022-10-25
Online:
2022-10-25
Contact:
LAN Jianghe, senior engineer. E-mail: lanjh418915@sina.com;About author:
YANG Xiaoming (1990-), male, associate professor. E-mail: xmyang@fjirsm.ac.cn
Supported by:
摘要:
钇铁石榴石(Y3Fe5O12, YIG)晶体具有优异的磁学和磁光性质, 在微波和磁光器件中有着广泛的应用。目前商用的磁光材料是采用液相外延技术在Gd3Ga5O12(GGG)衬底上沉积的YIG单晶薄膜。本研究以无铅B2O3-BaF2为复合助熔剂, 采用顶部籽晶法技术(TSSG)生长YIG单晶材料, YIG晶体尺寸和重量分别可达43 mm×46 mm×11 mm和60 g。该晶体具有较窄的铁磁共振线宽(0.679 Oe)、高透明度(75%)和法拉第旋转角(200 (°)·cm-1@1310 nm, 160 (°)·cm-1@1550 nm)等优异的综合性能, 是微波和磁光器件的良好候选材料。更为重要的是, 这种生长技术非常适合大尺寸YIG单晶或稀土掺杂YIG单晶, 结合定向籽晶生长和提升工艺, 可以显著降低生产成本。
中图分类号:
杨晓明, 蓝江河, 魏占涛, 苏榕冰, 李阳, 王祖建, 刘颖, 何超, 龙西法. 顶部籽晶法生长大尺寸、高品质钇铁石榴石晶体[J]. 无机材料学报, 2023, 38(3): 322-328.
YANG Xiaoming, LAN Jianghe, WEI Zhantao, SU Rongbing, LI Yang, WANG Zujian, LIU Ying, HE Chao, LONG Xifa. High Quality and Large Size Yttrium Iron Garnet Crystal Grown by Top Seeded Solution Growth Technique[J]. Journal of Inorganic Materials, 2023, 38(3): 322-328.
Fig. 2 XRD patterns and garnet structure of YIG crystal (a) XRD patterns and standard diffraction card; (b) Garnet structure; (c) Positions and sublattice structure of positive ions; (d) Oxygen coordination of positive ions
Fig. 3 Magnetic properties of YIG crystal (a) Enlarged M-H curve in the magnetic field of -1000-1000 Oe; (b) M-H curve at room temperature; (c) Temperature-dependent magnetization for an applied magnetic field of 1000 Oe (1 emu=10-3 A·m-2, 1 Oe=250/π A·m-1)
Fig. 4 Dielectric properties and FMR linewidth of YIG crystal (a, b) Temperature dependent dielectric constant (ε') and loss (tanδ) measured at the frequencies of 10 Hz-1 MHz; (c) FMR linewidth of the YIG spheres showed in the upright inset; (d) Average ΔH of the spheres (1 Oe=250/π A·m-1)Colorful figure is available on website
Fig. 6 X-ray photoelectron spectra and their Lorentzian-Gaussian dividing results of YIG crystal powders (a) Fe2p; (b) O1s; Colorful figure is available on website
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