顶部籽晶法生长大尺寸、高品质钇铁石榴石晶体

doi:10.15541/jim20220353

无机材料学报 ›› 2023, Vol. 38 ›› Issue (3): 322-328.DOI: 10.15541/jim20220353

顶部籽晶法生长大尺寸、高品质钇铁石榴石晶体

杨晓明¹(), 蓝江河²^,³(), 魏占涛³, 苏榕冰¹, 李阳³, 王祖建¹, 刘颖¹, 何超¹, 龙西法¹()

1.中国科学院福建物质结构研究所, 福州 350002
2.电子科技大学电子科学与工程学院, 成都 610054
3.西南应用磁学研究所, 绵阳 621000

收稿日期:2022-06-24 修回日期:2022-08-14 出版日期:2022-10-25 网络出版日期:2022-10-25
通讯作者: 蓝江河, 高级工程师. E-mail: lanjh418915@sina.com;
龙西法, 研究员. E-mail: lxf@fjirsm.ac.cn
作者简介:杨晓明(1990-), 男, 副研究员. E-mail: xmyang@fjirsm.ac.cn

High Quality and Large Size Yttrium Iron Garnet Crystal Grown by Top Seeded Solution Growth Technique

YANG Xiaoming¹(), LAN Jianghe²^,³(), WEI Zhantao³, SU Rongbing¹, LI Yang³, WANG Zujian¹, LIU Ying¹, HE Chao¹, LONG Xifa¹()

1. Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
2. School of Electronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu 610054, China
3. Southwest Institute of Applied Magnetics, Mianyang 621000, China

Received:2022-06-24 Revised:2022-08-14 Published:2022-10-25 Online:2022-10-25
Contact: LAN Jianghe, senior engineer. E-mail: lanjh418915@sina.com;
LONG Xifa, professor. E-mail: lxf@fjirsm.ac.cn
About author:YANG Xiaoming (1990-), male, associate professor. E-mail: xmyang@fjirsm.ac.cn
Supported by:
National Natural Science Foundation of China(51902307);National Natural Science Foundation of China(11974349);National Natural Science Foundation of China(11904362);National Natural Science Foundation of China(52172009);National Natural Science Foundation of China(52102011)

摘要/Abstract

摘要：

钇铁石榴石(Y₃Fe₅O₁₂, YIG)晶体具有优异的磁学和磁光性质, 在微波和磁光器件中有着广泛的应用。目前商用的磁光材料是采用液相外延技术在Gd₃Ga₅O₁₂(GGG)衬底上沉积的YIG单晶薄膜。本研究以无铅B₂O₃-BaF₂为复合助熔剂, 采用顶部籽晶法技术(TSSG)生长YIG单晶材料, YIG晶体尺寸和重量分别可达43 mm×46 mm×11 mm和60 g。该晶体具有较窄的铁磁共振线宽(0.679 Oe)、高透明度(75%)和法拉第旋转角(200 (°)·cm^-1@1310 nm, 160 (°)·cm^-1@1550 nm)等优异的综合性能, 是微波和磁光器件的良好候选材料。更为重要的是, 这种生长技术非常适合大尺寸YIG单晶或稀土掺杂YIG单晶, 结合定向籽晶生长和提升工艺, 可以显著降低生产成本。

关键词: 钇铁石榴石, 单晶, 顶部籽晶法, 铁磁共振线宽, 磁光效应

Abstract:

Yttrium iron garnet (Y₃Fe₅O₁₂, YIG) crystals have been widely used in microwave and magneto-optic devices due to their excellent magnetic and magneto-optical properties. Currently, the commercial material is YIG single crystal thin films, which is deposited on Gd₃Ga₅O₁₂ (GGG) substrate using liquid phase epitaxy technique. Herein, we report a new growth technology of YIG single crystal by top seeded solution growth (TSSG) technique from lead-free B₂O₃-BaF₂ flux. The maximum size and weight of the as-grown YIG crystal can be up to 43 mm× 46 mm×11 mm and 60 g, respectively. The crystals exhibit excellent comprehensive performances with narrow ferromagnetic resonance linewidth (0.679 Oe, 1 Oe=250/π A/m), high transparency (75%) and Faraday rotation angle (200 (°)·cm^-1@1310 nm and 160 (°)·cm^-1@1550 nm), indicating a good candidate in microwave and magneto-optic devices. More significantly, this growth technique is ideally suited to large size YIG or doped-YIG single crystals ascombined with the oriented seed crystal and lifting process, which can significantly decrease the manufacture cost.

Key words: yttrium iron garnet, single crystal, TSSG method, ferromagnetic resonance linewidth, magneto-optic effect

中图分类号:

TQ174

杨晓明, 蓝江河, 魏占涛, 苏榕冰, 李阳, 王祖建, 刘颖, 何超, 龙西法. 顶部籽晶法生长大尺寸、高品质钇铁石榴石晶体[J]. 无机材料学报, 2023, 38(3): 322-328.

YANG Xiaoming, LAN Jianghe, WEI Zhantao, SU Rongbing, LI Yang, WANG Zujian, LIU Ying, HE Chao, LONG Xifa. High Quality and Large Size Yttrium Iron Garnet Crystal Grown by Top Seeded Solution Growth Technique[J]. Journal of Inorganic Materials, 2023, 38(3): 322-328.

图/表 6

Fig. 1 Photo showing formation process of as-growth YIG single crystals

Fig. 2 XRD patterns and garnet structure of YIG crystal (a) XRD patterns and standard diffraction card; (b) Garnet structure; (c) Positions and sublattice structure of positive ions; (d) Oxygen coordination of positive ions

Fig. 3 Magnetic properties of YIG crystal (a) Enlarged M-H curve in the magnetic field of -1000-1000 Oe; (b) M-H curve at room temperature; (c) Temperature-dependent magnetization for an applied magnetic field of 1000 Oe (1 emu=10-3 A·m-2, 1 Oe=250/π A·m-1)

Fig. 4 Dielectric properties and FMR linewidth of YIG crystal (a, b) Temperature dependent dielectric constant (ε') and loss (tanδ) measured at the frequencies of 10 Hz-1 MHz; (c) FMR linewidth of the YIG spheres showed in the upright inset; (d) Average ΔH of the spheres (1 Oe=250/π A·m-1)Colorful figure is available on website

Fig. 5 Transmittance of YIG crystal and Faraday rotation angle at 1310 and 1550 nm

Fig. 6 X-ray photoelectron spectra and their Lorentzian-Gaussian dividing results of YIG crystal powders (a) Fe2p; (b) O1s; Colorful figure is available on website

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顶部籽晶法生长大尺寸、高品质钇铁石榴石晶体

High Quality and Large Size Yttrium Iron Garnet Crystal Grown by Top Seeded Solution Growth Technique

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