中空有序介孔有机硅的研究进展: 制备及在肿瘤治疗中的应用

doi:10.15541/jim20220435

无机材料学报 ›› 2022, Vol. 37 ›› Issue (11): 1192-1202.DOI: 10.15541/jim20220435

所属专题：【生物材料】肿瘤治疗

中空有序介孔有机硅的研究进展: 制备及在肿瘤治疗中的应用

张文君¹(), 赵雪莹¹, 吕江维¹(), 曲有鹏²

1.哈尔滨商业大学药学院, 哈尔滨 150076
2.哈尔滨工业大学生命科学与技术学院, 哈尔滨 150080

收稿日期:2022-07-23 修回日期:2022-09-14 出版日期:2022-09-15 网络出版日期:2022-09-15
通讯作者: 吕江维, 副教授, E-mail: pp198259@163.com
作者简介:张文君(1982-), 女, 博士, 副教授. E-mail: wenjun0501@126.com
基金资助:
国家重点研发计划(MB20160087);2019年哈尔滨商业大学青年人才专项计划项目(2019CX12)

Progresses on Hollow Periodic Mesoporous Organosilicas: Preparation and Application in Tumor Therapy

ZHANG Wenjun¹(), ZHAO Xueying¹, LÜ Jiangwei¹(), QU Youpeng²

1. School of Pharmacy, Harbin University of Commerce, Harbin 150076, China
2. School of Life Science and Technology, Harbin Institute of Technology, Harbin 150080, China

Received:2022-07-23 Revised:2022-09-14 Published:2022-09-15 Online:2022-09-15
Contact: LÜ Jiangwei, associate professor. E-mail: pp198259@163.com
About author:ZHANG Wenjun (1982-), female, PhD, associate professor. E-mail: wenjun0501@126.com
Supported by:
National Key Research and Development Program(MB20160087);Special Program for Young Talents of Harbin University of Commerce 2019(2019CX12)

摘要/Abstract

摘要：

随着介孔材料和生物医学的不断发展, 中空有序介孔有机硅(HPMOs)作为一种新型介孔硅材料, 具有高比表面积、高载药量、良好的生物相容性、多功能的有机-无机杂化框架、较低的细胞毒性以及可生物降解等特点,受到广泛关注, 以HPMOs为载体的药物递送系统得到多方持续开发, 为肿瘤治疗提供了新的策略。本文综述了近年来HPMOs的合成进展, 介绍了HPMOs的种类, 对硬模板法、液界面组装法和界面重组与转化法进行了详细的阐述, 并总结了其在肿瘤治疗中的应用进展。最后对其作为药物载体所面临的挑战及未来的发展趋势作了展望, 以期为HPMOs的制备及在肿瘤治疗中的应用研究提供参考。

关键词: 中空有序介孔有机硅, 硬模板法, 液界面组装法, 界面重组与转化法, 肿瘤治疗, 综述

Abstract:

With the development of mesoporous materials and biomedicine, hollow periodic mesoporous organosilicas (HPMOs), as a new type of mesoporous silicon material, stands out among many mesoporous materials because of its high specific surface area, high drug loading, good biocompatibility, multifunctional organic-inorganic hybrid framework, low cytotoxicity and biodegradability. Drug delivery systems based on HPMOs have been continuously developed, it provides a new strategy for tumor treatment. This article summarized the synthetic progress of HPMOs in recent years, briefly introduced the types of HPMOs, mainly expounded the hard template method, liquid interface assembly method and interface recombination-transformation method, and summarized its application in tumor therapy. Finally, challenges and future development trends as a drug carrier were prospected, in order to provide reference for the preparation and application of HPMOs in tumor therapy.

Key words: hollow periodic mesoporous organosilicas, hard template method, liquid-interface assembly method, interfacial recombination-transformation method, tumor therapy, review

中图分类号:

TB34

张文君, 赵雪莹, 吕江维, 曲有鹏. 中空有序介孔有机硅的研究进展: 制备及在肿瘤治疗中的应用[J]. 无机材料学报, 2022, 37(11): 1192-1202.

ZHANG Wenjun, ZHAO Xueying, LÜ Jiangwei, QU Youpeng. Progresses on Hollow Periodic Mesoporous Organosilicas: Preparation and Application in Tumor Therapy[J]. Journal of Inorganic Materials, 2022, 37(11): 1192-1202.

图/表 10

图1 HPMOs的制备方法及在肿瘤治疗中的应用

Fig. 1 Preparation of HPMOs and their application in tumor therapy

图2 单壳、蛋黄壳和多壳HPMOs结构示意图

Fig. 2 Structures of HPMOs, yolk-shell HPMOs and multishelled HPMOs

图 3 蛋黄壳和单壳HPMOs的合成策略

Fig. 3 Synthetic processes for yolk-shell structured HPMOs and HPMOs

图4 通过HF蚀刻获得的(a)蛋黄壳HPMOs和(b)单壳HPMOs的TEM照片[34]

Fig. 4 TEM images of (a) yolk-shell HPMOs and (b) HPMOs obtained by HF etching [34]

图5 界面重组与转化法制备HPMOs的过程[35]

Fig. 5 Preparation process of HPMOs by interface recombination-transformation method [35]

表1 HPMOs制备方法的比较

Table 1 Comparison of preparation methods of HPMOs

		Hard-core templating method	Liquid-interface assembly method	Interfacial reassembly and transformation method
Synthesis strategy	Difference	①Using solid particles as template ②Etchant required	①Using droplets or micelles as templates ②No etchant required	①No sacrificial template required ②No etchant required
Synthesis strategy	Similarity	The surfactant was extracted by HCl/EtOH solution
Influence factor		①Amount and type of etchant ②Etching temperature ③SNs size and organosilicon source concentration	Stability of droplets or micelles	Hydrothermal time and temperature
Advantages		Easy to control cavity diameter	①No sacrificial template required ②No etchant required ③Simple operation	①No sacrificial template required ②No etchant required
Disadvantages		①High costs ②Cumbersome operation ③Some of etchants are toxic	①Stability of droplets or micelles should be considered	High temperature of hydrothermal process

图6 HPMOs的药物递送过程[34]

Fig. 6 Drug delivery process of HPMOs [34]

图7 光响应型药物递送系统的DOX释放过程[67]

Fig. 7 DOX release process of photoresponsive drug delivery system[67]

图8 光控制药物释放的聚合方案[71]

Fig. 8 Scheme of the polymerization within HMPDINs for photocontrolled drug release [71]

图9 还原响应型药物递送系统的CO释放过程[72]

Fig. 9 CO release process of reduction responsive drug delivery system[72]

参考文献 77

[1]	MALGRAS V, ATAEE-ESFAHANI H, WANG H, et al. Nanoarchitectures for mesoporous metals. Advanced Materials, 2016, 28(6): 993-1010. DOI URL
[2]	LI W, LIU J, ZHAO D. Mesoporous materials for energy conversion and storage devices. Nature Reviews Materials, 2016, 1(6): 16023-17. DOI URL
[3]	LINARES N, SILVESTRE-ALBERO A M, SERRANO E, et al. Mesoporous materials for clean energy technologies. Chemical Society Reviews, 2014, 43(22): 7681-7717. DOI PMID
[4]	YANG X, QIU P, YANG J, et al. Mesoporous materials-based electrochemical biosensors from enzymatic to nonenzymatic. Small, 2021, 17(9): 1904022-16. DOI URL
[5]	MANZANO M, VALLET-REGÍ M. Mesoporous silica nanoparticles for drug delivery. Advanced Functional Materials, 2020, 30(2): 1902634-13. DOI URL
[6]	ZHOU Y, QUAN G, WU Q, et al. Mesoporous silica nanoparticles for drug and gene delivery. Acta Pharmaceutica Sinica B, 2018, 8(2): 165-177. DOI PMID
[7]	THI H, NGUYEN Q, HOANG T, et al. Functionalized mesoporous silica nanoparticles and biomedical applications. Materials Science and Engineering: C, 2019, 99: 631-656.
[8]	GNANAMOORTHY P, ANANDHAN S, PRABU V A. Natural nanoporous silica frustules from marine diatom as a biocarrier for drug delivery. Journal of Porous Materials, 2014, 21(5): 789-796. DOI URL
[9]	SZCZĘŚNIAK B, CHOMA J, JARONIEC M. Major advances in the development of ordered mesoporous materials. Chemical Communications, 2020, 56(57): 7836-7848. DOI URL
[10]	PANG L B, WANG D P. Drug carrier based on mesoporous borosilicate glass microspheres: preparation and performance. Journal of Inorganic Materials, 2022, 37(7): 780-786. DOI
[11]	MA H, TAO J H, WANG Y N, et al. Gold nanoparticles supported on silica & titania hybrid mesoporous spheres and their catalytic performance regulation. Journal of Inorganic Materials, 2022, 37(4): 404-412. DOI URL
[12]	PAN S, LI Y S, SHI J L. Facile synthesis of dendritic mesoporous silica nanoparticles for Co-loading of doxorubicin and hemoglobin. Journal of Inorganic Materials, 2018, 33(10): 1097-1102. DOI
[13]	ZEA C, ALCÁNTARA J, BARRANCO-GARCÍA R, et al. Synthesis and characterization of hollow mesoporous silica nanoparticles for smart corrosion protection. Nanomaterials, 2018, 8(7): 478. DOI URL
[14]	BAO Y, WANG T. Recent advances in fabrication and sustained/ controlled-release application of hollow silica microspheres. Journal of Inorganic Materials, 2016, 31(12): 1269-1278. DOI URL
[15]	MOGHADDAM S P H, YAZDIMAMAGHANI M, GHANDEHARI H. Glutathione-sensitive hollow mesoporous silica nanoparticles for controlled drug delivery. Journal of Controlled Release, 2018, 282: 62-75.
[16]	GAO Y, ZHANG Y, HE S, et al. Fabrication of a hollow mesoporous silica hybrid to improve the targeting of a pesticide. Chemical Engineering Journal, 2019, 364: 361-369.
[17]	TIAN M, LONG Y, XU D, et al. Hollow mesoporous silica nanotubes modified with palladium nanoparticles for environmental catalytic applications. Journal of Colloid and Interface Science, 2018, 521: 132-140.
[18]	ZHAO D Y, WAN Y, ZHOU W Z, et al. Ordered mesoporous molecular sieve materials, 2013. Beijing: Higher education press, 2013: 397-426.
[19]	LIN F, MENG X, WU L, et al. Inorganic salt assisted self-assembly of periodic mesoporous organosilicas with various structures under alkaline conditions. European Journal of Inorganic Chemistry, 2019, 2019(38): 4063-4069. DOI URL
[20]	GOTO Y, MIZOSHITA N, WAKI M, et al. Synthesis and applications of periodic mesoporous organosilicas//Abderrazzak D, Masakazu A. Chemistry of Silica and Zeolite-Based Materials. Elsevier, 2019: 1-25.
[21]	CROISSANT J G, CATTOËN X, MAN M W C, et al. Syntheses and applications of periodic mesoporous organosilica nanoparticles. Nanoscale, 2015, 7(48): 20318-20334. DOI PMID
[22]	PARK S S, MOORTHY M S, HA C S. Periodic mesoporous organosilica (PMO) for catalytic applications. Korean Journal of Chemical Engineering, 2014, 31(10): 1707-1719. DOI URL
[23]	WANG W, LOFGREEN J E, OZIN G A. Why PMO? Towards functionality and utility of periodic mesoporous organosilicas. Small, 2010, 6(23): 2634-2642. DOI PMID
[24]	YANG Q H, LIU J, ZHONG H, et al. Progress in the periodic mesoporous organosilicas. Journal of Inorganic Materials, 2009, 24(4): 641-649. DOI URL
[25]	ZENG Y L, CHEN J J, TIAN Z F, et al. Preparation of mesoporous organosilica-based nanosystem for in vitro synergistic chemo- and photothermal therapy. Journal of Inorganic Materials, 2020, 35(12): 1365-1372. DOI URL
[26]	WU M, CHEN Y, ZHANG L, et al. A salt-assisted acid etching strategy for hollow mesoporous silica/organosilica for pH-responsive drug and gene co-delivery. Journal of Materials Chemistry B, 2015, 3(5): 766-775. DOI PMID
[27]	TENG Z, LI W, TANG Y, et al. Mesoporous organosilica hollow nanoparticles: synthesis and applications. Advanced Materials, 2019, 31(38): 1707612-24. DOI URL
[28]	CHEN J, YANG Y, LIN B, et al. Hollow mesoporous organosilica nanotheranostics incorporating formimidoyltransferase cyclodeaminase (FTCD) plasmids for magnetic resonance imaging and tetrahydrofolate metabolism fission on hepatocellular carcinoma. International Journal of Pharmaceutics, 2022, 612: 121281-11.
[29]	CHUNLING L, XIYU Z, MENG C, et al. Application of hollow mesoporous organosilica nanoparticles as pH and redox double stimuli-responsive nanocontainer in the controlled release of corrosion inhibitor molecules. Progress in Organic Coatings, 2021, 159: 106437-12.
[30]	QIU P, MA B, HUNG C T, et al. Spherical mesoporous materials from single to multilevel architectures. Accounts of Chemical Research, 2019, 52(10): 2928-2938. DOI PMID
[31]	SHAO Y, SONG J, LI X, et al. Synthesis of noble metal M@YSiO₂yolk-shell nanoparticles with thin organic/inorganic hybrid outer shells via an aqueous medium phase. Langmuir, 2021, 37(23): 7237-7245. DOI URL
[32]	WU J, LIU Y, TANG Y, et al. Synergistic chemo-photothermal therapy of breast cancer by mesenchymal stem cell-encapsulated yolk-shell GNR@HPMOs-PTX nanospheres. Applied Materials & Interfaces, 2016, 8(28): 17927-17935.
[33]	YU L, PAN P, ZHANG Y, et al. Nonsacrificial self-template synthesis of colloidal magnetic yolk-shell mesoporous organosilicas for efficient oil/water interface catalysis. Small, 2019, 15(14): 1805465-9. DOI URL
[34]	CHEN Y, XU P, CHEN H, et al. Colloidal HPMO nanoparticles: silica-etching chemistry tailoring, topological transformation, and nano-biomedical applications. Advanced Materials, 2013, 25(22): 3100-3105. DOI URL
[35]	TENG Z, SU X, ZHENG Y, et al. A facile multi-interface transformation approach to monodisperse multiple-shelled periodic mesoporous organosilica hollow spheres. Journal of the American Chemical Society, 2015, 137(24): 7935-7944. DOI PMID
[36]	WANG C, SANG G, RONG Y, et al. Unexpected phenomenon in a conventional system: synthesis of raspberry-like hollow periodic mesoporous organosilica with controlled structure in one continuous step. New Journal of Chemistry, 2021, 45(15): 6651-6660. DOI URL
[37]	TENG Z, WANG C, TANG Y, et al. Deformable hollow periodic mesoporous organosilica nanocapsules for significantly improved cellular uptake. Journal of the American Chemical Society, 2018, 140(4): 1385-1393. DOI PMID
[38]	BAO Y, SHI C, WANG T, et al. Recent progress in hollow silica: template synthesis, morphologies and applications. Microporous and Mesoporous Materials, 2016, 227: 121-136.
[39]	BAO Y, SHI C H, MA J Z. Fabrication of hollow silica spheres and their effect on water vapor permeability of waterborne polyurethane film. Journal of the Chinese Ceramic Society, 2015, 43(1): 35-41.
[40]	LIU X, JIAO Z, SONG T, et al. Surfactant-assisted selective etching strategy for generation of rattle-like mesoporous silica nanoparticles. Journal of Colloid and Interface Science, 2017, 490: 497-504.
[41]	CHO Y S. Fabrication of hollow or macroporous silica particles by spray drying of colloidal dispersion. Journal of Dispersion Science and Technology, 2016, 37(1): 23-33. DOI URL
[42]	ZHANG W J, LIANG X L, LYU J W, et al. Synthesis and biomedicine application progress of periodic mesoporous organosilicas. Fine Chemicals, 2022, 39(02): 236-246.
[43]	KARIMI B, GANJI N, POURSHIANI O, et al. Periodic mesoporous organosilicas (PMOs): from synthesis strategies to applications. Progress in Materials Science, 2021,125: 100896-90.
[44]	HUANG X, LI W, WANG M, et al. A facile template route to periodic mesoporous organosilicas nanospheres with tubular structure by using compressed CO₂. Scientific Reports, 2017, 7(1): 45055-11. DOI PMID
[45]	GUO W, WANG J, LEE S J, et al. A general pH-responsive supramolecular nanovalve based on mesoporous organosilica hollow nanospheres. Chemistry-a European Journal, 2010, 16(29): 8641-8646. DOI PMID
[46]	YANG L, GUO H, WANG L, et al. A facile “polystyrene- dissolving” strategy to hollow periodic mesoporous organosilica with flexible structure-tailorability. Microporous and Mesoporous Materials, 2017, 239: 173-179.
[47]	KOIKE N, CHAIKITTISILP W, SHIMOJIMA A, et al. Surfactant- free synthesis of hollow mesoporous organosilica nanoparticles with controllable particle sizes and diversified organic moieties. Royal Society of Chemistry Advances, 2016, 6: 90435-90445.
[48]	WANG Y, WANG P, CHEN L, et al. Organosilane-assisted selective etching strategy for fabrication of hollow/rattle-type mesoporous organosilica nanospheres. Journal of Solid State Chemistry, 2018, 266: 279-285.
[49]	LI C L, ZHAO X, MENG C, et al. Application of hollow mesoporous organosilica nanoparticles as pH and redox double stimuli- responsive nanocontainer in the controlled release of corrosion inhibitor molecules. Progress in Organic Coatings, 2021, 159: 106437.
[50]	HUANG L, FENG J, FAN W, et al. Intelligent pore switch of hollow mesoporous organosilica nanoparticles for high contrast magnetic resonance imaging and tumor-specific chemotherapy. Nano-Micro Letters, 2021, 21(22): 9551-9559.
[51]	DJOJOPUTRO H, ZHOU X F, QIAO S Z, et al. Periodic mesoporous organosilica hollow spheres with tunable wall thickness. Journal of the American Chemical Society, 2006, 128(19): 6320-6321. PMID
[52]	MA X, ZHANG J, DANG M, et al. Hollow periodic mesoporous organosilica nanospheres by a facile emulsion approach. Journal of Colloid and Interface Science, 2016, 475: 66-71.
[53]	MA N, DENG Y, LIU W, et al. A one-step synthesis of hollow periodic mesoporous organosilica spheres with radially oriented mesochannels. Chemical Communications, 2016, 52(17): 3544-3547. DOI URL
[54]	TENG Z, LI W, TANG Y, et al. Mesoporous organosilica hollow nanoparticles: synthesis and applications. Advanced Materials, 2019, 31(38): 170762.
[55]	TENG Z, SU X, LEE B, et al. Yolk-shell structured mesoporous nanoparticles with thioether-bridged organosilica frameworks. Chemistry of Materials, 2014, 26(20): 5980-5987. DOI URL
[56]	TENG Z, WANG S, SU X, et al. Facile synthesis of yolk-shell structured inorganic-organic hybrid spheres with ordered radial mesochannels. Advanced Materials, 2014, 26(22): 3741-3747. DOI URL
[57]	TENG Z, ZHANG J, LI W, et al. Facile synthesis of yolk- shell-structured triple-hybridized periodic mesoporous organosilica nanoparticles for biomedicine. Small, 2016, 12(26): 3550-3558. DOI URL
[58]	ZHANG J, WENG L, SU X, et al. Cisplatin and doxorubicin high- loaded nanodrug based on biocompatible thioether-and ethane- bridged hollow mesoporous organosilica nanoparticles. Journal of Colloid and Interface Science, 2018, 513: 214-221.
[59]	YU R, TAO J, SHAO L, et al. Facile synthesis of hybridized triple-shelled hollow mesoporous organosilica nanoparticles. Journal of the Taiwan Institute of Chemical Engineers, 2022, 131: 104122-7.
[60]	GUAN L, CHEN J, TIAN Z, et al. Mesoporous organosilica nanoparticles: degradation strategies and application in tumor therapy. View, 2021, 2(5): 20200117-22. DOI URL
[61]	ZHOU Y, XU Q, LI C, et al. Hollow mesoporous silica nanoparticles as nanocarriers employed in cancer therapy: a review. Frontiers of Materials Science, 2020, 14(4): 373-386. DOI
[62]	ANIS T, KHURSHID A, FAKHAR-E-ALAM M, et al. Hollow multicomponent capsules for biomedical applications: a comprehensive review. Journal of Cluster Science, 2022: https://doi.org/10.1007/s10876-022-02272-z.
[63]	JIN M Z, JIN W L. The updated landscape of tumor microenvironment and drug repurposing. Signal Transduction and Targeted Therapy, 2020, 5(1): 1052-1067.
[64]	LI Y, WANG Z, WEI Q, et al. Non-covalent interactions in controlling pH-responsive behaviors of self-assembled nanosystems. Polymer chemistry, 2016, 7(38): 5949-5956. DOI PMID
[65]	MOLLAZADEH S, MACKIEWICZ M, YAZDIMAMAGHANI M. Recent advances in the redox-responsive drug delivery nanoplatforms: a chemical structure and physical property perspective. Materials Science and Engineering: C, 2021, 118: 111536-13.
[66]	WU J, MENG Z, EXNER A, et al. Biodegradable cascade nanocatalysts enable tumor-microenvironment remodeling for controllable CO release and targeted/synergistic cancer nanotheapy. Biomaterials, 2021, 276: 121001-13.
[67]	FAN J, ZHANG Z, WANG Y, et al. Photo-responsive degradable hollow mesoporous organosilica nanoplatforms for drug delivery. Journal of Nanobiotechnology, 2020, 18: 91-14.
[68]	LIU X, SU H, SHI W, et al. Functionalized poly (pyrrole-3- carboxylic acid) nanoneedles for dual-imaging guided PDT/PTT combination therapy. Biomaterials, 2018, 167: 177-190.
[69]	BARKAT A, BEG S, PANDA S K, et al. Functionalized mesoporous silica nanoparticles in anticancer therapeutics. Seminars in Cancer Biology, 2021, 69: 365-375.
[70]	ZHANG H, SONG F, DONG C, et al. Co-delivery of nanoparticle and molecular drug by hollow mesoporous organosilica for tumor- activated and photothermal-augmented chemotherapy of breast cancer. Journal of Nanobiotechnology, 2021, 19: 290-13.
[71]	YANG Z, FAN W, ZOU J, et al. Precision cancer theranostic platform by in situ polymerization in perylene diimide-hybridized hollow mesoporous organosilica nanoparticles. Journal of the American Chemical Society, 2019, 141(37): 14687-14698. DOI URL
[72]	TANG W, FAN W, WANG Z, et al. Acidity/reducibility dual-responsive hollow mesoporous organosilica nanoplatforms for tumor-specific self-assembly and synergistic therapy. Nano Materials, 2018, 12(12): 12269-12283.
[73]	LI L, LIN H, LI D, et al. Ultrasound activated nanosensitizers for sonodynamic therapy and theranostics. Biomedical Materials, 2021, 16(2): 022008-17. DOI URL
[74]	ZHU P, CHEN Y, SHI J. Nanoenzyme-augmented cancer sonodynamic therapy by catalytic tumor oxygenation. Nano, 2018, 12(4): 3780-3795.
[75]	ZOU W, HAO J, WU J, et al. Biodegradable reduce expenditure bioreactor for augmented sonodynamic therapy via regulating tumor hypoxia and inducing pro-death autophagy. Journal of Nanobiotechnology, 2021, 19(1): 418-15. DOI URL
[76]	FAN W, LU N, SHEN Z, et al. Generic synthesis of small-sized hollow mesoporous organosilica nanoparticles for oxygen-independent X-ray-activated synergistic therapy. Nature Communications, 2019, 10: 1241-14.
[77]	LU N, FAN W, YI X, et al. Biodegradable hollow mesoporous organosilica nanotheranostics for mild hyperthermia-induced bubble-enhanced oxygen-sensitized radiotherapy. Nano, 2018, 12(2): 1580-1591.

中空有序介孔有机硅的研究进展: 制备及在肿瘤治疗中的应用

Progresses on Hollow Periodic Mesoporous Organosilicas: Preparation and Application in Tumor Therapy

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