无机材料学报 ›› 2023, Vol. 38 ›› Issue (2): 213-218.DOI: 10.15541/jim20220155
张万文1(), 罗建强1(), 刘淑娟1, 马建国1, 张小平1, 杨松旺2()
收稿日期:
2022-03-21
修回日期:
2022-07-21
出版日期:
2023-02-20
网络出版日期:
2022-08-04
通讯作者:
罗建强, 教授. E-mail: luojianqiang@163.com;作者简介:
张万文(1994-), 男, 硕士研究生. E-mail: 2352937300@qq.com
ZHANG Wanwen1(), LUO Jianqiang1(), LIU Shujuan1, MA Jianguo1, ZHANG Xiaoping1, YANG Songwang2()
Received:
2022-03-21
Revised:
2022-07-21
Published:
2023-02-20
Online:
2022-08-04
Contact:
LUO Jianqiang, professor. E-mail: luojianqiang@163.com;About author:
: ZHANG Wanwen (1994-), male, Master candidate. E-mail: 2352937300@qq.com
Supported by:
摘要:
氧化钛/氧化锆/碳三层结构钙钛矿太阳能电池(Perovskite solar cells, PSCs)具有原材料廉价、制备工艺易放大和稳定性好等优势, 受到了广泛关注。但三层结构PSCs的低温制备研究进展缓慢, 主要原因之一在于难以在低温条件下构建合适的氧化锆间隔层。本研究以尿素为孔隙率调节剂, 用简单的喷涂法制备多孔氧化锆间隔层用于三层结构PSCs。通过调节喷涂次数优化氧化锆层厚度为1100 nm时, 电池的性能最优, 单电池功率转换效率达到14.7%, 5块电池串联模块(5×0.9 cm×2.5 cm)达到10.8%。PSCs在恒温恒湿箱(25 ℃, 湿度40%)保存200 d, 功率转换效率保持稳定, 没有明显下降。柔性基底上的氧化锆层经50次弯曲测试后保持完整, 未见脱落。与传统的丝网印刷氧化锆间隔层制备方法相比, 本研究的喷涂方法具有方法简便、操作温度低、与柔性基底兼容性好的优点。
中图分类号:
张万文, 罗建强, 刘淑娟, 马建国, 张小平, 杨松旺. 氧化锆间隔层的低温喷涂制备及其三层结构钙钛矿太阳能电池应用性能[J]. 无机材料学报, 2023, 38(2): 213-218.
ZHANG Wanwen, LUO Jianqiang, LIU Shujuan, MA Jianguo, ZHANG Xiaoping, YANG Songwang. Zirconia Spacer: Preparation by Low Temperature Spray-coating and Application in Triple-layer Perovskite Solar Cells[J]. Journal of Inorganic Materials, 2023, 38(2): 213-218.
Fig. 2 SEM images of the zirconia film prepared by spray- coating without urea (a), with w(zirconia) : w(urea)= 2 : 1 (b) and 1 : 1 (c), cross-sectional SEM images of PSCs containing zirconia layer prepared with w(zirconia) : w(urea)= 2 : 1(d) and 1 : 1 (e) Circled areas in (d) are not completely filled
Fig. 3 J-V curves of PSCs prepared with w(zirconia) : w(urea)=2 : 1 and 1 : 1(a), and J-V curves from forward and reverse scanning of PSC prepared with w(zirconia) : w(urea)=1 : 1 (Zirconia layer thickness at ~1000 nm) (b)
Fig. 4 J-V curves of the triple-layer PSCs with spray-coated and screen-printed zirconia layer(a), IPCE spectrum and corresponding integrated current density of the PSC with 1100 nm thick zirconia layer(b), PCE distribution of 30 chips with three different thicknesses of zirconia layer(c), and stabilized power output of PSCs with optimized spray-coated zirconia layer (d)
Fig. S3 Cross-sectional SEM images of PSCs before filling perovskite with the zirconia thickness of (a, b) 750, (c, d) 1100 nm and (e, f) 1500 nm((a, c, e) before and (b, d, f) after filling perovkite)
Fig. S4 (a) J-V curves of the cell with different illumination areas with inset showing the tested cell photograph; (b) J-V curve of PSCs module with five cells connected in series with inset showing the tested cell photograph
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