微波烧结制备ZrO2-AlN复合陶瓷的微观结构与性能研究

doi:10.15541/jim20210150

无机材料学报 ›› 2021, Vol. 36 ›› Issue (11): 1231-1236.DOI: 10.15541/jim20210150

• 研究快报 • 上一篇

微波烧结制备ZrO₂-AlN复合陶瓷的微观结构与性能研究

牟庭海¹^,²(), 许文涛²^,³, 凌军荣², 董天文², 秦梓轩², 周有福²^,³()

1.福建师范大学化学与材料学院, 福州 350007
2.中国科学院福建物质结构研究所, 光电材料化学与物理重点实验室, 福州 350002
3.福建光电信息科技创新实验室, 福州 350108

收稿日期:2021-03-11 修回日期:2021-04-12 出版日期:2021-11-20 网络出版日期:2021-05-10
通讯作者: 周有福, 研究员. E-mail: yfzhou@fjirsm.ac.cn
作者简介:牟庭海(1995-), 男, 硕士研究生. E-mail: mutinghai@fjirsm.ac.cn

Microstructure and Properties of ZrO₂-AlN Composite Ceramics by Microwave Sintering

MU Tinghai¹^,²(), XU Wentao²^,³, LING Junrong², DONG Tianwen², QIN Zixuan², ZHOU Youfu²^,³()

1. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
2. Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
3. Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

Received:2021-03-11 Revised:2021-04-12 Published:2021-11-20 Online:2021-05-10
Contact: ZHOU Youfu, professor. E-mail: yfzhou@fjirsm.ac.cn
About author:MU Tinghai (1995-), male, Master candidate. E-mail: mutinghai@fjirsm.ac.cn
Supported by:
Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20010300, XDA21010204);Adv. Energy Sci. & Technol. Guangdong Lab(Open laboratory)

摘要/Abstract

摘要：

氧化锆(ZrO₂)陶瓷具有出色的机械性能, 但其应用受到低热导率(Thermal Conductivity, TC)的限制。本研究设计并通过微波烧结制备了高热导率氧化锆-氮化铝(AlN)复合陶瓷, 优化制备条件后, 抑制了两种物质之间的反应, 获得了致密的复合陶瓷(相对密度>99%), 详细研究了该复合陶瓷的组织演变、热学性能和力学性能。研究结果表明, 随着AlN含量的增加, 复合陶瓷的室温下热导率、热扩散系数和热容增加, 分别达到41.3 W/(m·K)、15.2 mm²/s和0.6 J/(g·K)。这种具有高热导率和抗热震性的ZrO₂-AlN复合复合陶瓷在能源系统的高温热交换材料领域具有广阔的应用前景。

关键词: 氧化锆, 氮化铝, 复合陶瓷, 微波烧结, 热导率

Abstract:

Zirconia (ZrO₂) ceramics have excellent mechanical properties, but its application is limited by ZrO₂-AlN low thermal conductivity (TC). Zirconia-aluminum nitride (AlN) composite ceramics ZrO₂-AlN with high TC were designed and successfully fabricated by microwave sintering. After optimization of preparation conditions, the reaction between two substances was inhibited and the dense composite (relative density>99%) was obtained. The microstructure evolution, thermal behavior and mechanical properties were investigated in detail. The room temperature thermal conductivity, thermal diffusion coefficient and thermal capacity of ZrO₂-AlN composites increase with AlN content increasing, reaching 41.3 W/(m·K), 15.2 mm²/s and 0.6 J/(g·K), respectively. Such ZrO₂-AlN composites with high thermal conductivity and improved thermal shock resistance have broad application prospects in the field of high temperature heat exchange materials of energy systems.

Key words: zirconia, aluminum nitride, composite ceramic, microwave sintering, thermal conductivity

中图分类号:

TQ174

牟庭海, 许文涛, 凌军荣, 董天文, 秦梓轩, 周有福. 微波烧结制备ZrO₂-AlN复合陶瓷的微观结构与性能研究[J]. 无机材料学报, 2021, 36(11): 1231-1236.

MU Tinghai, XU Wentao, LING Junrong, DONG Tianwen, QIN Zixuan, ZHOU Youfu. Microstructure and Properties of ZrO₂-AlN Composite Ceramics by Microwave Sintering[J]. Journal of Inorganic Materials, 2021, 36(11): 1231-1236.

图/表 9

Table 1 Compositions of samples

Specimen	Composition
ZAN-0	100%ZrO₂
ZAN-1	95wt%ZrO₂+5wt%AlN
ZAN-2	90wt%ZrO₂+10wt%AlN
ZAN-3	85wt%ZrO₂+15wt%AlN
ZAN-4	80wt%ZrO₂+20wt%AlN

Fig. 1 Sintering process of ZrO2-AlN composite ceramic

Fig. 2 XRD pattern of raw material powder after ball milling and mixing

Fig. 3 EDS mapping images of mixed powder after ball milling

Fig. 4 XRD patterns of ZrO2-AlN composite ceramics sintered at 1350 ℃ (a) and at different temperatures (b)

Fig. 5 Relative density and mechanical behavior of different ZrO2-AlN composite ceramics (a) Relative density; (b) Vickers hardness; (c) Fracture toughness; (d) Flexural strength

Table 2 Relative density of ZAN-2 sample prepared by different CIP pressure and ball milling processes

Sample	Rotating speed/(r·min^-1)	Rotating time/h	Pressure/MPa	Relative density/%
1#	250	24	200	99.3
2#	250	12	200	98.5
3#	200	24	200	98.9
4#	250	24	100	98.1

Fig. 6 SEM images of the polished surfaces (a, b) and fracture surfaces (c, d) of ZAN-2 sample

Fig. 7 Thermal performance of ZrO2-AlN composite ceramics with different AlN contents (a) Thermal conductivity; (b) Thermal diffusion coefficient; (c) Thermal capacity

参考文献 23

[1]	LI J, PENG J, GUO S, et al. Thermodynamic calculations of t to m martenstic transformation of ZrO₂-CaO binary system. Ceramics International, 2012, 38(4):2743-2747. DOI URL
[2]	LI K, WANG D, CHEN H, et al. Normalized evaluation of thermal shock resistance for ceramic materials. Journal of Advanced Ceramics, 2014, 3(3):250-258. DOI URL
[3]	YOSHINAGA M, SASAKI T, KOBAYASHI N. Effect of microwave irradiation for crystallization behavior of yttria-stabilized zirconia system. Journal of the Ceramic Society of Japan, 2019, 127(10):767-772. DOI URL
[4]	MALYI O I, WU P, KULISH V V, et al. Formation and migration of oxygen and zirconium vacancies in cubic zirconia and zirconium oxysulfide. Solid State Ionics, 2012, 212:117-122. DOI URL
[5]	WANG L, LIANG T. Ceramics for high level radioactive waste solidification. Journal of Advanced Ceramics, 2012, 1(3):194-203. DOI URL
[6]	LI B, YANG, CHU M, et al. Ti₃SiC₂/UO₂ composite pellets with superior high-temperature thermal conductivity. Ceramics International, 2018, 44(16):19846-19850. DOI URL
[7]	HOLGATE C S, SEWARD G G E, ERICKS A R, et al. Dissolution and diffusion kinetics of yttria-stabilized zirconia into molten silicates. Journal of the European Ceramic Society, 2021, 41(3):1984-1994. DOI URL
[8]	MEBRAHITOM ASMELASH G, MAMAT O, AHMAD F, et al. Thermal shock and fatigue behavior of pressureless sintered Al₂O₃- SiO₂-ZrO₂ composites. Journal of Advanced Ceramics, 2015, 4(3):190-198. DOI URL
[9]	DONG K F, MO W Q, JIN F, et al. Effect of TiN-ZrO₂ intermediate layer on the microstructure and magnetic properties of FePt and FePt-SiO₂-C thin films. Journal of Magnetism and Magnetic Materials, 2017, 432:323-329. DOI URL
[10]	JI Y, FU R, LV J, et al. Enhanced bonding strength of Al₂O₃/AlN ceramics joined via glass frit with gradient thermal expansion coefficient. Ceramics International, 2020, 46(8):12806-12811. DOI URL
[11]	LAZAR A, KOSMAC T, ZAVASNIK J, et al. TiN-nanoparticulate- reinforced ZrO₂ for electrical discharge machining. Materials (Basel), 2019, 12(17):2788-2802. DOI URL
[12]	ESMAEILZAEI A, SAJJADI S A, MOLLAZADEH BEIDOKHTI S, et al. Rapid consolidation of Al₂O₃-TiO₂-Co nanocermets via spark plasma sintering of Co-coated ceramic particles. Journal of Alloys and Compounds, 2019, 771:79-88. DOI URL
[13]	OKAZAKI H, KOBAYASHI R, HASHIMOTO R, et al. Thermal conductivity and mechanical strength of low-temperature-sintered aluminum nitride ceramics containing aluminum nitride whiskers. Journal of the Ceramic Society of Japan, 2020, 128(11):991-994. DOI URL
[14]	YEH CT, TUAN W H. Oxidation mechanism of aluminum nitride revisited. Journal of Advanced Ceramics, 2017, 6(1):27-32. DOI URL
[15]	MIYAZAKI H, YOSHIZAWA YI. Correlation of the indentation fracture resistance measured using high-resolution optics and the fracture toughness obtained by the single edge-notched beam (SEPB) method for typical structural ceramics with various microstructures. Ceramics International, 2016, 42(6):7873-7876. DOI URL
[16]	TANAKA I. Impacts of first principles calculations in engineering ceramics. Journal of the Ceramic Society of Japan, 2016, 124(8):791-795. DOI URL
[17]	LU Y, YUAN Z, SHEN H, et al. High-temperature phase relations of ZrN-ZrO₂-Y₂O₃ ternary system. Journal of Advanced Ceramics, 2018, 7(4):388-391. DOI URL
[18]	CALLAWAY J. Model for lattice thermal conductivity at low temperatures. Physical Review, 1959, 113(4):1046-1051. DOI URL
[19]	TAO Y, LIU C, CHEN W, et al. Mean free path dependent phonon contributions to interfacial thermal conductance. Physics Letters A, 2017, 381(22):1899-1904. DOI URL
[20]	SLACK G A. Nonmetallic crystals with high thermal conductivity. J. Phys. Chem. Solids, 1972, 34:321-335. DOI URL
[21]	HONG H, KIM J, KIM T I. Effective assembly of nano-ceramic materials for high and anisotropic thermal conductivity in a polymer composite. Polymers, 2017, 9(9):413. DOI URL
[22]	CHEN H, WEI J, CHEN Y, et al. Theoretical investigation of the mechanical and thermodynamic properties of titanium pernitride under high temperature and high pressure. Journal of Alloys and Compounds, 2017, 726:1179-1185. DOI URL
[23]	NOVIKOV V V. Debye-Einstein model and anomalies of heat capacity temperature dependences of solid solutions at low temperatures. Journal of Thermal Analysis and Calorimetry, 2019, 138(1):265-272. DOI URL

微波烧结制备ZrO₂-AlN复合陶瓷的微观结构与性能研究

Microstructure and Properties of ZrO₂-AlN Composite Ceramics by Microwave Sintering

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 23

相关文章 15

编辑推荐

Metrics

本文评价

[1]	郭春霞, 陈伟东, 闫淑芳, 赵学平, 杨傲, 马文. 埃洛石纳米管负载锆氧化物吸附水中砷的研究[J]. 无机材料学报, 2023, 38(5): 529-536.
[2]	张万文, 罗建强, 刘淑娟, 马建国, 张小平, 杨松旺. 氧化锆间隔层的低温喷涂制备及其三层结构钙钛矿太阳能电池应用性能[J]. 无机材料学报, 2023, 38(2): 213-218.
[3]	付师, 杨增朝, 李宏华, 王良, 李江涛. 复合烧结助剂对Si₃N₄陶瓷力学性能和热导率的影响[J]. 无机材料学报, 2022, 37(9): 947-953.
[4]	胡佳军, 王凯, 侯鑫广, 杨婷, 夏鸿雁. 熔盐法合成高导热磷化硼及其热管理性能研究[J]. 无机材料学报, 2022, 37(9): 933-940.
[5]	王鹏将, 康慧君, 杨雄, 刘颖, 程成, 王同敏. 熵调控抑制ZrNiSn基half-Heusler热电材料的晶格热导率[J]. 无机材料学报, 2022, 37(7): 717-723.
[6]	阮景, 杨金山, 闫静怡, 游潇, 王萌萌, 胡建宝, 张翔宇, 丁玉生, 董绍明. 碳化硅纳米线增强多孔碳化硅陶瓷基复合材料的制备[J]. 无机材料学报, 2022, 37(4): 459-466.
[7]	王亚宁, 张玉琪, 宋索成, 陈若梦, 刘亚雄, 段玉岗. 氧化锆陶瓷扫描光固化成形与脱脂烧结工艺研究[J]. 无机材料学报, 2022, 37(3): 303-309.
[8]	娄许诺, 邓后权, 李爽, 张青堂, 熊文杰, 唐国栋. Ge掺杂MnTe材料的热电输运性能[J]. 无机材料学报, 2022, 37(2): 209-214.
[9]	王为得, 陈寰贝, 李世帅, 姚冬旭, 左开慧, 曾宇平. 以YbH₂-MgO体系为烧结助剂制备高热导率高强度氮化硅陶瓷[J]. 无机材料学报, 2021, 36(9): 959-966.
[10]	张维维, 陆晨, 应国兵, 张建峰, 江莞. AlN表面处理及级配填充对覆铜板绝缘层性能的影响规律与机制研究[J]. 无机材料学报, 2021, 36(8): 847-855.
[11]	桑玮玮, 张红松, 陈华辉, 温斌, 李新春. (Sm_0.2Gd_0.2Dy_0.2Y_0.2Yb_0.2)₃TaO₇高熵陶瓷的制备及热物理性能[J]. 无机材料学报, 2021, 36(4): 405-410.
[12]	张力, 杨现锋, 徐协文, 郭金玉, 周哲, 刘鹏, 谢志鹏. 熔融沉积法3D打印制备氧化锆陶瓷及其力学性能研究[J]. 无机材料学报, 2021, 36(4): 436-442.
[13]	满鑫, 吴南, 张牧, 贺红亮, 孙旭东, 李晓东. Lu₂O₃-MgO纳米粉体合成及其复相红外透明陶瓷制备[J]. 无机材料学报, 2021, 36(12): 1263-1269.
[14]	邱小小,周细应,傅赟天,孙晓萌,王连军,江莞. Ge_1-_xIn_xTe微观结构对热电性能的影响[J]. 无机材料学报, 2020, 35(8): 916-922.
[15]	张晓旭,朱东彬,梁金生. 齿科氧化锆陶瓷水热稳定性研究进展[J]. 无机材料学报, 2020, 35(7): 759-768.