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无机材料学报

无机材料学报 ›› 2021, Vol. 36 ›› Issue (10): 1083-1090.DOI: 10.15541/jim20200745

• 研究论文 • 上一篇    下一篇

生物炭-膨润土共改性及其铅离子吸附与稳定化研究

肖瑶1(), 吴中杰2, 崔美3, 苏荣欣3,4, 谢连科2, 黄仁亮4()   

  1. 1.天津大学 环境科学与工程学院, 天津300072
    2.国网山东省电力公司电力科学研究院, 济南250002
    3.天津大学 化工学院, 天津300072
    4.天津大学 海洋科学与技术学院, 天津 300072
  • 收稿日期:2020-12-30 修回日期:2021-01-25 出版日期:2021-10-20 网络出版日期:2021-03-12
  • 通讯作者: 黄仁亮, 副教授. E-mail: tjuhrl@tju.edu.cn
  • 作者简介:肖 瑶(1995-), 女, 硕士研究生. E-mail: xiaoyao950827@gmail.com
  • 基金资助:
    国家自然科学基金(21976132);国家电网公司科学技术项目(520626190015)

Co-modification of Biochar and Bentonite for Adsorption and Stabilization of Pb2+ ions

XIAO Yao1(), WU Zhongjie2, CUI Mei3, SU Rongxin3,4, XIE Lianke2, HUANG Renliang4()   

  1. 1. School of Environmental Science and Engineering, Tianjin University, Tianjin 300072, China
    2. Shandong Electric Power Research Institute of Chinese Power Company, Jinan 250002, China
    3. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
    4. School of Marine Science and Technology, Tianjin University, Tianjin 300072, China
  • Received:2020-12-30 Revised:2021-01-25 Published:2021-10-20 Online:2021-03-12
  • Contact: HUANG Renliang, associate professor. E-mail: tjuhrl@tju.edu.cn
  • About author:XIAO Yao (1995-), female, Master candidate. E-mail: xiaoyao950827@gmail.com
  • Supported by:
    National Natural Science Fund of China(21976132);Science and Technology Project of State Grid Corporation of China(520626190015)

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摘要：

重金属污染具有高毒性、持久存留和生物积累等特性, 严重危害人体健康和生态安全。本研究通过氯化钙对玉米芯残渣和膨润土混合物进行碱改性, 在无氧条件下高温煅烧制备了一种碱改性生物炭-膨润土复合物(CaO-Bent-CB)。该复合物的比表面积高, 达到441.1 m2/g, 明显高于直接煅烧制备的生物碳(132.7 m2/g)和碱改性生物炭(177.2 m2/g)。进一步评价了该复合物对水中铅离子吸附性能, 结果表明在水中铅离子浓度为120 mg/L, 膨润土与玉米芯残渣质量比为1:5, 用量为1 g/L条件下, 吸附6 h后铅离子去除率达98%, 吸附量为109.6 mg/g, 均高于生物炭(13.4 mg/g)、膨润土(72.9 mg/g)和碱改性生物炭(86.9 mg/g)。此外, 采用CaO-Bent-CB对铅离子污染土壤进行稳定化处理, 当土壤中铅离子浓度为2200 mg/kg, CaO-Bent-CB用量为土壤干重的8%时, 在pH=3.2的硫酸-硝酸浸提液中浸出12 h, 酸浸出铅离子浓度低至4.5 mg/L, 低于危险废物鉴别标准值(5 mg/L)。上述研究结果表明这种生物炭-膨润土共改性复合物在重金属污染水体和土壤修复中具有很好的应用前景。

关键词: 玉米芯残渣, 生物炭, 粘土, 重金属, 土壤修复

Abstract:

Heavy metals can seriously endanger human health and the ecological environment due to their toxicity, persistence, and bioaccumulative nature. In this study, an alkali-modified biochar-bentonite composite (CaO-Bent-CB) was prepared by alkali modification of corncob residues and bentonite mixture by calcium chloride and calcination at high temperature under anaerobic conditions. The CaO-Bent-CB composite has a specific surface area of ​​441.1 m2/g, which is significantly higher than CB (132.7 m2/g) and CaO-CB (177.2 m2/g). Meanwhile, the adsorption perfermance of CaO-Bent-CB to lead ions in water was evaluated. The results showed that the removal efficiency reached 98% after 6 h-adsorption, and the adsorption capacity was 109.6 mg/g when the concentration of lead ion was 120 mg/L, the weight ratio of bentonite to corncob residues was 1:5, and the dosage was 1 g/L. The adsorption capacity of CaO-Bent-CB was higher than that of CB (13.4 mg/g), bentonite (72.9 mg/g) and CaO-CB (86.9 mg/g). Moreover, the lead ion contaminated soil was stabilized by CaO-Bent-CB. When the concentration of lead ion in soil is 2200 mg/kg, and the loading of CaO-Bent-CB is 8% of soil, the concentration of lead ions in acid leachate (H2SO4-HNO3, pH=3.2, 12 h-soaking) is 4.5 mg/L, which is lower than the standard value of hazardous waste identification (5 mg/L). The results show that CaO-Bent-CB has a great potential in the water treatment and heavy metals removal in soil.

Key words: corncob residue, biochar, clay, heavy metal, soil remediation

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