无机材料学报 ›› 2021, Vol. 36 ›› Issue (6): 637-644.DOI: 10.15541/jim20200450
所属专题: 能源材料论文精选(2021); 【虚拟专辑】氢能材料(2020~2021)
朱云娜1(), 陈必清1(
), 程天舒2, 杜婵1, 张士民1, 赵静1
收稿日期:
2020-08-10
修回日期:
2020-10-29
出版日期:
2021-06-20
网络出版日期:
2020-11-05
通讯作者:
陈必清, 教授. E-mail: chenbq2332@163.com
作者简介:
朱云娜(1994-), 女, 硕士研究生. E-mail: zhuyunna11@163.com
基金资助:
ZHU Yunna1(), CHEN Biqing1(
), CHENG Tianshu2, DU Chan1, ZHANG Shimin1, ZHAO Jing1
Received:
2020-08-10
Revised:
2020-10-29
Published:
2021-06-20
Online:
2020-11-05
Contact:
CHEN Biqing, professor. E-mail: chenbq2332@163.com
About author:
ZHU Yunna(1994-), female, Master candidate. E-mail: zhuyunna11@163.com
Supported by:
摘要:
本研究采用简单的一步化学沉积法制备非晶纳米Nd-Ni-B/NF稀土复合电极并研究其析氢(Hydrogen evolution reaction, HER)性能。通过各种测试方法对纳米电极材料进行物相分析和形貌表征,并探索其电催化析氢性能和稳定性。结果表明, 稀土Nd可提高电极的电催化析氢性能, 当硝酸钕浓度为3 g?L-1时, 恒温35 ℃下施镀1 h, 制备的Nd-Ni-B/NF电极析氢性能最佳。Nd-Ni-B/NF(Nickel foam)电极在1.0 mol?L-1KOH 溶液中, 20 mA?cm-2电流密度下的析氢过电位仅为180 mV, Tafel斜率为117 mV?dec-1, 析氢反应由Volmer-Heyrovsky步骤控制。此外, Nd-Ni-B/NF电极具有优越的电化学稳定性, 在持续电解12 h或2000次循环伏安测试后, 催化剂的活性没有明显衰减。
中图分类号:
朱云娜, 陈必清, 程天舒, 杜婵, 张士民, 赵静. 非晶Nd-Ni-B/NF稀土复合电极材料的制备及其析氢性能[J]. 无机材料学报, 2021, 36(6): 637-644.
ZHU Yunna, CHEN Biqing, CHENG Tianshu, DU Chan, ZHANG Shimin, ZHAO Jing. Amorphous Nd-Ni-B/NF Rare Earth Composites: Preparation and HER Electrocatalytic Performance[J]. Journal of Inorganic Materials, 2021, 36(6): 637-644.
图5 (a)x-NNB/NF(x=0, 2, 3, 4, 5)和Pt/C电极的LSV曲线, (b)在20 mA?cm-2的过电位, (c)Tafel曲线(源于(a))和(d)根据Tafel曲线外推得到的交换电流密度(j0); (e)3-NNB/NF电极的CV曲线; (f)x-NNB/NF(x=0, 2, 3, 4, 5)电极的充电双电层库仑曲线
Fig. 5 (a) LSV curves, (b) overpotentials at 20 mA?cm-2, (c) Tafel curves (derived from (a)) and (d) exchange current densities (j0) derived from the Tafel curves of x-NNB/NF(x=0, 2, 3, 4, 5) and Pt/C electrodes; (e) CV curves of 3-NNB/NF electrode at different scan rates; (f) Coulomb curves of charge double-layer capacitance of x-NNB/NF(x=0, 2, 3, 4, 5) electrodes
图6 x-NNB/NF(x=0, 2, 3, 4, 5)电极的电化学阻抗图谱, 插图为等效电路图
Fig. 6 Nyquist plots of x-NNB/NF(x=0, 2, 3, 4, 5) electrodes towards HER with inset showing the corresponding equivalent circuit
图8 NNB/NF-y(y=25, 35, 45, 55)电极(a~d)在不同扫描速率下的CV曲线和(e)充电双电层库仑曲线
Fig. 8 (a-e) CV curves at different scan rates and Coulomb curves of charge double-layer capacitance for NNB/NF-y (y=25, 35, 45, 55) electrodes
图9 (a)NNB/NF-35在100 mV电位下电解12 h的电流-时间曲线; (b)2000圈循环伏安扫描前后的LSV曲线; (c)不同形状的NNB/NF-35电极的极化曲线和数码照片(插图); (d)不同非贵金属电催化材料在碱性溶液中的HER活性对比
Fig. 9 (a) I-t curve for NNB/NF-35 under 100 mV static overpotential for stability test 12 h; (b) Polarization curves of NNB/NF-35 before and after 2000 CV sweeps; (c) LSV curves and digital photos (insets) of NNB/NF-35 electrodes with different shapes; (d) Comparison of HER activities for different non-noble electrocatalytic materials in alkaline solution
Electrode | Rs/(Ω∙cm-2) | RP/(Ω∙cm-2) | Rct/(Ω∙cm-2) |
---|---|---|---|
0-NNB/NF | 0.195 | 1.573 | 1.578 |
2-NNB/NF | 0.167 | 1.294 | 1.310 |
3-NNB/NF | 0.152 | 1.261 | 1.279 |
4-NNB/NF | 0.165 | 1.438 | 1.455 |
5-NNB/NF | 0.166 | 1.536 | 1.543 |
表1 x-NNB/NF(x=0, 2, 3, 4, 5)电极的电化学交流阻抗参数
Table S1 EIS parameters of x-NNB/NF(x=0, 2, 3, 4, 5) electrodes
Electrode | Rs/(Ω∙cm-2) | RP/(Ω∙cm-2) | Rct/(Ω∙cm-2) |
---|---|---|---|
0-NNB/NF | 0.195 | 1.573 | 1.578 |
2-NNB/NF | 0.167 | 1.294 | 1.310 |
3-NNB/NF | 0.152 | 1.261 | 1.279 |
4-NNB/NF | 0.165 | 1.438 | 1.455 |
5-NNB/NF | 0.166 | 1.536 | 1.543 |
图S3 (a)3-NNB/Cu-600 ℃的SEM照片和XRD图谱及(b)3-NNB/Cu和3-NNB/Cu-600 ℃的LSV曲线
Fig. S3 (a) SEM image and XRD pattern of 3-NNB/Cu-600 ℃; (b) LSV curves of 3-NNB/Cu and 3-NNB/Cu-600 ℃
Catalyst | Current density@Overpotential | Tafel slope/(mV∙dec-1) | Ref. |
---|---|---|---|
Nd-Ni-B/NF | 20 mA∙cm-2@180 mV | 117 | This work |
Ni-Co/RuO2 | 50 mA∙cm-2@180 mV | 168.3 | [1] |
Ni-Fe-S/Ti | 50 mA∙cm-2@126 mV | 269 | [2] |
V-Ni2P NSAs/CC | 10 mA∙cm-2@85 mV | 95 | [3] |
Ni-Fe-P | 10 mA∙cm-2@174.2 mV | 142.9 | [4] |
Ni/NiS | 10 mA∙cm-2@230 mV | 123 | [5] |
FeP Nanorod | 10 mA∙cm-2@218 mV | 146 | [6] |
Ni0.5Co0.5/NC | 10 mA∙cm-2@282 mV | 189 | [7] |
FeCoP Nanoarrays | 10 mA∙cm-2@175 mV | 132 | [8] |
Ni2P-NiSe2 | 10 mA∙cm-2@66 mV | 72.6 | [9] |
Ni-Co-P/NF | 10 mA∙cm-2@85 mV | 46 | [10] |
表S2 非贵金属催化剂在1.0 mol∙L-1 KOH介质中HER催化性能的对比
Table S2 Comparison of the electrocatalytic HER activity for representative nonprecious HER catalysts in 1.0 mol∙L-1 KOH electrolyte
Catalyst | Current density@Overpotential | Tafel slope/(mV∙dec-1) | Ref. |
---|---|---|---|
Nd-Ni-B/NF | 20 mA∙cm-2@180 mV | 117 | This work |
Ni-Co/RuO2 | 50 mA∙cm-2@180 mV | 168.3 | [1] |
Ni-Fe-S/Ti | 50 mA∙cm-2@126 mV | 269 | [2] |
V-Ni2P NSAs/CC | 10 mA∙cm-2@85 mV | 95 | [3] |
Ni-Fe-P | 10 mA∙cm-2@174.2 mV | 142.9 | [4] |
Ni/NiS | 10 mA∙cm-2@230 mV | 123 | [5] |
FeP Nanorod | 10 mA∙cm-2@218 mV | 146 | [6] |
Ni0.5Co0.5/NC | 10 mA∙cm-2@282 mV | 189 | [7] |
FeCoP Nanoarrays | 10 mA∙cm-2@175 mV | 132 | [8] |
Ni2P-NiSe2 | 10 mA∙cm-2@66 mV | 72.6 | [9] |
Ni-Co-P/NF | 10 mA∙cm-2@85 mV | 46 | [10] |
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