氧化钼电致变色材料与器件

doi:10.15541/jim20200416

无机材料学报 ›› 2021, Vol. 36 ›› Issue (5): 461-470.DOI: 10.15541/jim20200416

所属专题：电致变色材料与器件；【虚拟专辑】电致变色与热致变色材料；电致变色专栏2021

• 专栏:电致变色材料与器件(特邀编辑:王金敏,刁训刚) • 上一篇下一篇

氧化钼电致变色材料与器件

王金敏¹^,²(), 后丽君¹, 马董云¹^,²

1.上海第二工业大学工学部, 环境与材料工程学院, 上海 201209
2.上海理工大学理学院, 化学系, 上海 200093

收稿日期:2020-07-24 修回日期:2020-09-17 出版日期:2021-05-20 网络出版日期:2021-04-19
作者简介:王金敏(1975-), 男, 教授. E-mail:wangjinmin@sspu.edu.cn;jmwang@usst.edu.cn
基金资助:
国家自然科学基金(61775131);国家自然科学基金(61376009);上海高校特聘教授(东方学者)岗位计划(2013-70);上海第二工业大学研究生项目基金(EGD19YJ0039)

Molybdenum Oxide Electrochromic Materials and Devices

WANG Jinmin¹^,²(), HOU Lijun¹, MA Dongyun¹^,²

1. School of Environmental and Materials Engineering, College of Engineering, Shanghai Polytechnic University, Shanghai 201209, China
2. Department of Chemistry, College of Science, University of Shanghai for Science and Technology, Shanghai 200093, China

Received:2020-07-24 Revised:2020-09-17 Published:2021-05-20 Online:2021-04-19
About author:WANG Jinmin (1975-), male, professor. E-mail:wangjinmin@sspu.edu.cn;jmwang@usst.edu.cn
Supported by:
National Natural Science Foundation of China(61775131);National Natural Science Foundation of China(61376009);Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning(2013-70);Shanghai Polytechnic University Graduate Project Fund(EGD19YJ0039)

摘要/Abstract

摘要：

电致变色材料具有可逆的颜色转变特性, 在智能窗、显示器、防眩后视镜、电子纸、军事伪装等领域应用广泛。相对于其它种类的显示器件, 电致变色显示器件具有色彩丰富、对比度高、无视盲角、断电后仍显色等优点。作为一种典型的阴极着色电致变色材料, 氧化钼具有响应时间短和着色态更接近于人眼对光线的敏感波段等优点, 使得由氧化钼组成的电致变色器件具有重要的研究价值。本文简要介绍了电致变色、电致变色材料与器件的定义及其应用, 尤其电致变色技术最近在智能手机上得到了示范应用, 表明电致变色技术未来有良好的发展前景。然后, 详细综述了氧化钼薄膜的制备、氧化钼的改性、氧化钼电致变色器件的研究进展。最后提出了氧化钼电致变色薄膜与器件当前存在的问题和解决的途径, 并对其发展前景进行了展望。

关键词: 氧化钼, 电致变色, 掺杂, 复合, 综述

Abstract:

Electrochromic materials show reversible color-changeable characteristics, which are widely used in smart windows, displays, adjustable reflective mirrors, electronic paper, military camouflage and other fields. Compared with other kinds of display devices, electrochromic display devices have advantages of multi-colors, high contrast, no blind visual angles, and maintainable color after power off. As a typical cathodic colored electrochromic material, molybdenum oxide exhibits advantages of short response time and colored state closer to the sensitive wavelength band of the human eye to light, so that the electrochromic devices composed of molybdenum oxide is important in the research. This paper briefly introduces the definitions and applications of electrochromism, electrochromic materials and devices. In particular, electrochromic technology recently realized a demonstration application in smart phones, indicating the good prospects for the future development of electrochromic technology. We summarized mainly the research progress of the preparation of molybdenum oxide films, the modification of molybdenum oxide, and the molybdenum oxide based electrochromic devices. Finally, we presented current existing problems and solutions on molybdenum oxide based electrochromic films and devices with development prospects.

Key words: molybdenum oxide, electrochromism, doping, composite

中图分类号:

TQ174

王金敏, 后丽君, 马董云. 氧化钼电致变色材料与器件[J]. 无机材料学报, 2021, 36(5): 461-470.

WANG Jinmin, HOU Lijun, MA Dongyun. Molybdenum Oxide Electrochromic Materials and Devices[J]. Journal of Inorganic Materials, 2021, 36(5): 461-470.

图/表 10

图1 MoO6八面体晶胞结构图[25]

Fig. 1 Structure diagram of MoO6 octahedral unit cell[25]

图2 电致变色器件的结构示意图[27]

Fig. 2 Schematic diagram of electrochromic device structure[27]

图3 水/溶剂热法应用领域(a),水/溶剂热法设备原理图(b)和水/溶剂热制备的一般步骤(c)[40]

Fig. 3 Application field of water/solvothermal method (a), schematic diagram of water/solvothermal method equipment (b), and general steps of water/solvothermal preparation (c)[40]

图4 两种MoO3产物在不同放大倍数下的FESEM照片[45] (a-c) Nanorods; (d-f) Nanoparticles

Fig. 4 FESEM images of two MoO3 products at different magnifications[45]

图5 施加+1.5/-1.5 V, 15/15 s后的六至十层MoO3膜的计时容量法曲线(a)和MoO3薄膜层数对其电荷密度的影响(b)[26]

Fig. 5 Chronocoulometry of six- to ten-layer MoO3 ?lm after applying +1.5/-1.5 V for 15/15 s (a) and effect of the number of MoO3 thin film layers on its charge density (b)[26] Colouful figures are available on roebsite

图6 喷雾热解系统用于制备MoO3/C复合微球的示意图[54]

Fig. 6 Schematic diagram of spray pyrolysis system applied in the preparation of MoO3/C composite microspheres[54]

图7 具有多层堆叠结构的α-MoO3晶体在不同放大倍率下的SEM显微照片(a~c), 通过煅烧市售钼酸(MoO3·H2O)获得的MoO3晶体的SEM照片(d), 以及具有44层堆积的α-MoO3的SEM显微照片(e)[57]

Fig. 7 SEM images of α-MoO3 crystals with a multi-layer stack structure at different magnifications (a-c), SEM image of MoO3 crystals obtained by calcination of commercial molybdic acid (MoO3·H2O) (d), and SEM image of α-MoO3 stacking with 44 layers (e)[57]

图8 未掺杂与掺杂Fe-Co的MoO3薄膜的透射光谱[61]

Fig. 8 Transmission spectra of undoped and Fe-Co-doped MoO3 films[61]

图9 W0.71Mo0.29O3薄膜、PEDOT:PSS薄膜和W0.71Mo0.29O3/PEDOT:PSS薄膜632.8 nm下的原位动力学特征曲线(a), 电极的着色效率曲线(b)和循环稳定性曲线(c)[66]

Fig. 9 In-situ kinetic properties measured at 632.8 nm for W0.71Mo0.29O3 film, PEDOT:PSS film and W0.71Mo0.29O3/PEDOT:PSS film (a), coloration efficiencies (b), and cycling stabilities (c) of the electrodes[66]

图10 互补型电致变色电池的示意图(a), 单活性层电致变色电池(b)和互补型电致变色电池的可见-近红外透射光谱(c), 单层器件和互补型器件的放电曲线(电流密度为0.05 mA·cm-2) (d), 以及互补型电致变色电池在-2.5 V着色后可以使LED点亮10 min以上(e)[70]

Fig. 10 Schematic diagram of a complementary electrochromic battery (a), visible-near-infrared transmission spectra of single active layer electrochromic battery (b) and complementary electrochromic batteries (c), discharge curves (current density is 0.05 mA·cm-2) of single-layer device and complementary device (d), and complementary electrochromic batteries lighting up the LED for 10 min after being colored at -2.5 V (e)[70]

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氧化钼电致变色材料与器件

Molybdenum Oxide Electrochromic Materials and Devices

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