无机材料学报 ›› 2021, Vol. 36 ›› Issue (6): 592-600.DOI: 10.15541/jim20200266
所属专题： 【能源环境】金属有机框架材料
李婷婷1,2(
), 张志明1, 韩正波2()
收稿日期:2020-05-15
修回日期:2020-07-09
出版日期:2021-06-20
网络出版日期:2020-08-28
通讯作者:
韩正波, 教授. E-mail: ceshzb@lnu.edu.cn
作者简介:李婷婷(1980-), 女, 博士. E-mail: litingting2046@163.com
基金资助:
LI Tingting1,2(), ZHANG Zhiming1, HAN Zhengbo2()
Received:2020-05-15
Revised:2020-07-09
Published:2021-06-20
Online:2020-08-28
Contact:
HAN Zhengbo, professor. E-mail: ceshzb@lnu.edu.cn
About author:LI Tingting(1980-), female, PhD. E-mail: litingting2046@163.com
Supported by:摘要：
基于静电纺丝技术的金属有机骨架纳米纤维膜材料(Metal-Organic Frameworks Nanofibrous Membranes, MOFs NFMs)综合了无机多孔材料和聚合物纳米纤维的优势, 是一类具有广阔应用前景的功能性材料。目前已经开发出不同功能的MOFs NFMs, 其应用领域也在不断扩展。本文介绍了MOFs NFMs从制备研究向应用研究的发展历程, 详述了现阶段制备MOFs NFMs的主要方法, 包括混合纺丝法、原位生长法、多步种子生长法和原子层沉积法等; 阐述了目前MOFs NFMs的主要应用领域, 如吸附分离、多相催化、传感检测等; 展望了MOFs NFMs的发展方向和趋势。
中图分类号:
李婷婷, 张志明, 韩正波. 基于静电纺丝技术的聚合物基MOFs纳米纤维膜的研究进展[J]. 无机材料学报, 2021, 36(6): 592-600.
LI Tingting, ZHANG Zhiming, HAN Zhengbo. Research Progress in Polymer-based Metal-organic Framework Nanofibrous Membranes Based on Electrospinning[J]. Journal of Inorganic Materials, 2021, 36(6): 592-600.
图1 MIL-47/PAN (a)[8]和HKUST-1 (b)[10] NFMs的SEM照片
Fig. 1 SEM images of MIL-47/PAN (a)[8] and HKUST-1 (b) NFMs[10]
图2 PI-ZIF-8 (a)[16]和PAN/MOF-808 (b)[17]的SEM照片
Fig. 2 SEM images of PI-ZIF-8 (a)[16] and PAN/MOF-808 (b) NFMs[17]
图3 (a)ZIF-8/PAN纤维的制备方法和机理[22]; (b)PAN NFM上原位生长UiO-66-NH2示意图[23]; (c)ZIF-8、MIL-88B(Fe)、HKUST-1和MIL-53(Al) NFMs的制备过程[25]
Fig. 3 (a) Preparation method and formation mechanism of the in situ ZIF-8/PAN fibers[22]; (b) Scheme of in situ growth of UiO-66-NH2 on PAN NFM[23]; (c) Fabrication process of ZIF-8, MIL-88B(Fe), HKUST-1 and MIL-53(Al) NFMs[25]
图4 自支撑的柔性HKUST-1 NFM的制备过程[6]
Fig. 4 Preparation process of self-supported and flexible HKUST-1 NFM[6]
图5 (a)PAN/ZnO/ZIF-8和PAN/Al2O3/MIL-53-NH2的SEM照片[28]; (b)ALD法制备UiO-66-NH2 NFM的示意图[29]
Fig. 5 (a) SEM images of PAN/ZnO/ZIF-8 and PAN/Al2O3/MIL-53-NH2 NFMs[28], and (b) schematic illustration of UiO-66-NH2 NFMs prepared through ALD[29]
图6 以聚多巴胺为成核中心在“惰性”聚合物NFM上沉积MOF[30]
Fig. 6 Effective deposition MOF on the ‘‘inert’’ polymer fibrous membranes by using polydopamine layer as nucleation center[30]
图7 (a)PAN/ZIF-8 NFMs对CO2的吸附等温线和CO2/N2的吸附选择率[33]; (b)Bio-MOF/PAN过滤器对阳离子染料的选择性吸附[37]; (c)ZIF-67/CA NFM对Cu(II)和Cr(VI)的吸附机理示意图[39]
Fig. 7 (a) CO2 adsorption isotherms and CO2/N2 adsorption selectivity of PAN/ZIF-8 NFMs[33], (b) selective adsorption of cationic dyes by bio-MOF/PAN filter[37], and (c) adsorption mechanism of Cu(II) and Cr(VI) on the ZIF-67/CA NFM surface[39]
图8 (a)PLA/ZIF-8@GO NFM光催化降解MB的可能机理[41]; (b)UiO-66-NH2 NFM用于处理有毒工业化学品和化学战剂的示意图[42]
Fig. 8 (a) Possible mechanism of photocatalytic degradation of MB on PLA/ZIF-8@GO fibers[41], and (b) illustration of UiO-66-NH2 NFM used for protection against toxic industrial chemicals and chemical warfare agents[42]
图9 (a)Zn-MOF/PST-1NFM的荧光照片[45]; (b)荧光试纸的可逆性实验[47]
Fig. 9 (a) Fluorescent image of Zn-MOF/PST-1 NFM[45], and (b) reversibility test of the fluorescent test paper with NB and methanol[47]
图10 (a)定向静电纺丝纤维中质子传导示意图和横截面取向纳米纤维的HRTEM照片[55]; (b)CS-PEO和CS-PEO-3% ZIF-8 NFMs对金黄色葡萄球菌的抗菌活性[56]
Fig. 10 (a) Proton conductive process of oriented electrospun nanofiber and HRTEM image of cross-sectional aligned nanofiber[55], and (b) antibacterial activities of CS-PEO and CS-PEO-3% ZIF-8 NFMs[56]
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